20 results on '"Siegrist, Hansruedi"'
Search Results
2. (NH)SO recovery from liquid side streams.
- Author
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Boehler, Marc, Heisele, Alexander, Seyfried, Alexander, Grömping, Markus, and Siegrist, Hansruedi
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NITROGEN in water ,SEWAGE disposal plants ,WASTEWATER treatment ,AMMONIA ,ARTIFICIAL membranes - Abstract
Two methods of recovering nitrogen from liquid side streams are presented in this paper. The first method was demonstrated at an ammonia stripping plant treating 5-7 m/h sludge water at the wastewater treatment plant (WWTP) Kloten-Opfikon (CH). In addition to the usual stripping and scrubbing columns, a third column had been added in order strip CO, thus reducing the NaOH-demand of the subsequent ammonia stripping. At first, just the stripping plant was put into operation and optimized without any pre-treatment of the supernatant. Next, the CO-stripper column was activated and optimized by gas measurements to minimize free ammonia losses, heat losses, and energy consumption. Key operational aspects of the plant were evaluated. Finally, up to 1.4 m/h source-separated urine was successfully fed into the stripping facility. The second ammonia removal method using hydrophobic hollow fiber membranes was tested in two small pilot systems by different manufacturers in 2012 and 2013 at WWTP Neugut. In this technology, free ammonia gas in the sludge liquid diffuses at pH >9.3 from the sludge liquid through the air-filled pores of the microporous hydrophobic membrane into concentrated sulfuric acid flowing through the hollow fibers, forming ammonium sulfate. The small pore size and the hydrophobic nature of the membrane prevent the liquid phase from entering into the pores due to the surface tension effect. Practical experience regarding operational parameters like wastewater flow rate, pH, temperature, ammonia concentration, fouling and precipitations processes, optimal flow schemes, and process configurations was collected. [ABSTRACT FROM AUTHOR]
- Published
- 2015
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3. Hospital Wastewater Treatment by Membrane Bioreactor: Performance and Efficiency for Organic Micropollutant Elimination.
- Author
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Kovalova, Lubomira, Siegrist, Hansruedi, Singer, Heinz, Wittmer, Anita, and McArdell, Christa S.
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PILOT projects , *WASTEWATER treatment , *PERFORMANCE of bioreactors , *MEMBRANE reactors , *HOSPITAL waste disposal , *MICROPOLLUTANTS - Abstract
A pilot-scale membrane bioreactor (MBR) was installed and operated for one year at a Swiss hospital. It was fed an influent directly from the hospital's sanitary collection system. To study the efficiency of micropollutant elimination in raw hospital wastewater that comprises a complex matrix with micropollutant concentrations ranging from low ng/L to low mg/L, an automated online SPE-HPLC-MS/MS analytical method was developed. Among the 68 target analytes were the following: 56 pharmaceuticals (antibiotics, antimycotics, antivirals, iodinated X-ray contrast media, antiinflamatory, cytostatics, diuretics, beta blockers, anesthetics, analgesics, antiepileptics, antidepressants, and others), 10 metabolites, and 2 corrosion inhibitors. The MBR influent contained the majority of those target analytes. The micropollutant elimination efficiency was assessed through continuous flow-proportional sampling of the MBR influent and continuous time-proportional sampling of the MBR effluent. An overall load elimination of all pharmaceuticals and metabolites in the MBR was 22%, as over 80% of the load was due to persistent iodinated contrast media. No inhibition by antibacterial agents or disinfectants from the hospital was observed in the MBR. The hospital wastewater was found to be a dynamic system in which conjugates of pharmaceuticals deconjugate and biological transformation products are formed, which in some cases are pharmaceuticals themselves. [ABSTRACT FROM AUTHOR]
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- 2012
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4. Assessing wastewater dilution in small rivers with high resolution conductivity probes.
- Author
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Ort, Christoph and Siegrist, Hansruedi
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DILUTION , *INDUSTRIAL wastes , *RIVERS , *HYDRODYNAMICS , *WASTEWATER treatment , *SEWAGE purification , *ELECTRIC conductivity , *WATER temperature , *HYDROLOGY - Abstract
Installation and maintenance of flow gauging stations to assess wastewater dilution in small creeks is expensive. The method outlined in this paper provides a flexible and cheap alternative for situations with dilution factors smaller than 10 and unambiguous flow direction. It is shown that conductivity profiles from three sampling locations enable accurate identification of the dilution factor with an uncertainty of ±10-30%. Furthermore, much insight can be gained on the temporal behavior of both, the receiving water and the wastewater treatment system by combined analysis of conductivity and temperature data. In this case study the data also enabled identification and tracking down of illegal polluters. [ABSTRACT FROM AUTHOR]
- Published
- 2009
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5. Modelling nitrite in wastewater treatment systems: a discussion of different modelling concepts.
- Author
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Sin, Gürkan, Kaelin, David, Kampschreur, Marlies J., Takács, Imre, Wett, Bernhard, Gernaey, Krist V., Rieger, Leiv, Siegrist, Hansruedi, and van Loosdrecht, Mark C. M.
- Subjects
NITRIFICATION ,WASTEWATER treatment ,NITRITES ,SEWAGE purification ,SEWAGE disposal plants ,WATER purification ,DENITRIFICATION ,OXIDATION ,WATER quality management ,INDUSTRIAL wastes - Abstract
Originally presented at the 1st IWA/WEF Wastewater Treatment Modelling Seminar (WWTmod 2008), this contribution has been updated to also include the valuable feedback that was received during the Modelling Seminar. This paper addresses a number of basic issues concerning the modelling of nitrite in key processes involved in biological wastewater water treatment. To this end, we review different model concepts (together with model structures and corresponding parameter sets) proposed for processes such as two-step nitrification/denitrification, anaerobic ammonium oxidation and phosphorus uptake processes. After critically discussing these models with respect to their assumptions and parameter sets, common points of agreement as well as disagreement were elucidated. From this discussion a general picture of the state-of-the-art in the modelling of nitrite is provided. Taking this into account, a number of recommendations are provided to focus further research and development on nitrite modelling in biological wastewater treatment. [ABSTRACT FROM AUTHOR]
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- 2008
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6. Biological nutrient removal in a small-scale MBR treating household wastewater
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Abegglen, Christian, Ospelt, Mario, and Siegrist, Hansruedi
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WASTEWATER treatment , *ACTIVATED sludge process , *BIOREACTORS , *PHOSPHORUS in water , *NITROGEN in water , *SLUDGE management , *INDUSTRIAL wastes , *PHOSPHORUS , *MEMBRANE reactors - Abstract
The biological nutrient-removal potential of an on-site Membrane bioreactor (MBR) located in the basement of a four-person house treating domestic wastewater was investigated. The reactor consists of two tanks in series. This treatment plant differs from other conventional MBRs by a highly fluctuating influent water flow and a lack of pretreatment. During the first period, the first reactor was operated as a primary clarifier, resulting in nitrogen and phosphorus removals of 50% and 25%, respectively. Primary sludge production and bad odors in the basement were further disadvantages. When using the first reactor as an anaerobic/anoxic reactor by recycling activated sludge and mixing the first reactor, nitrogen and phosphorus removals of over 90% and 70% were achieved, respectively. By applying a dynamic model of the plant, the return sludge ratio was identified as the most important parameter. With a return sludge ratio of about 1.2, optimal PAO growth and phosphorous removal up to 90% was reached. Since only activated sludge is produced with this operational mode, on-site sludge dewatering is possible. During vacation periods without loading, the Bio-P activity is kept constant if the aeration is reduced to 5–20mind−1. [Copyright &y& Elsevier]
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- 2008
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7. Decay processes of nitrifying bacteria in biological wastewater treatment systems
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Manser, Reto, Gujer, Willi, and Siegrist, Hansruedi
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NITRIFYING bacteria , *WASTEWATER treatment , *AMMONIA , *NITROGEN compounds - Abstract
Abstract: A knowledge of the decay rates of autotrophic bacteria is important for reliably modeling nitrification in activated sludge plants. The introduction of nitrite to activated sludge models also requires the separate determination of the kinetics of ammonia- and nitrite-oxidizing bacteria. Batch experiments were carried out in order to study the effects of different oxidiation–reduction potential conditions and membrane separation on the separate decay of these bacteria. It was found that decay is negligible in both cases under anoxic conditions. No significant differences were detected between the membrane and conventional activated sludge. The aerobic decay of these two types of bacteria did not diverge significantly either. However, the measured loss of autotrophic activity was only partly explained by the endogenous respiration concept as incorporated in activated sludge model no. 3 (ASM3). In contrast to nitrite-oxidizing bacteria, ammonia-oxidizing bacteria needed 1–2h after substrate addition to reach their maximum growth rate measured as a maximum OUR. This pattern could be successfully modeled using the ASM3 extended by enzyme kinetics. The significance of these findings on wastewater treatment is discussed on the basis of the extended ASM3. [Copyright &y& Elsevier]
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- 2006
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8. Evaluation of a full-scale wastewater treatment plant upgraded with ozonation and biological post-treatments: Abatement of micropollutants, formation of transformation products and oxidation by-products.
- Author
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Bourgin, Marc, Beck, Birgit, Boehler, Marc, Borowska, Ewa, Fleiner, Julian, Salhi, Elisabeth, Teichler, Rebekka, von Gunten, Urs, Siegrist, Hansruedi, and McArdell, Christa S.
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SEWAGE disposal plants , *OZONIZATION , *MICROPOLLUTANTS , *WASTE products , *DRINKING water analysis - Abstract
To protect the ecosystem and drinking water resources in Switzerland and in the countries of the downstream catchments, a new Swiss water protection act entered into force in 2016 aiming to reduce the discharge of micropollutants from wastewater treatment plants (WWTPs). As a consequence, selected WWTPs must be upgraded by an advanced treatment for micropollutant abatement with suitable and economic options such as (powdered) activated carbon treatment or ozonation. WWTP Neugut (105′000 people equivalent) was the first WWTP in Switzerland to implement a long-term full-scale ozonation. Differing specific ozone doses in the range of 0.35–0.97 g O 3 /g DOC were applied to determine the adequate ozone dose to fulfill the requirements of the Swiss water protection act. Based on this assessment, a specific ozone dose of 0.55 g O 3 /g DOC is recommended at this plant to ensure an average abatement of the twelve selected indicator substances by ≥80% over the whole treatment. A monitoring of 550 substances confirmed that this dose was very efficient to abate a broad range of micropollutants by >79% on average. After ozonation, an additional biological post-treatment is required to eliminate possible negative ecotoxicological effects generated during ozonation caused by biodegradable ozonation transformation products (OTPs) and oxidation by-products (OBPs). Three biological treatments (sand filtration, moving bed, fixed bed) and granular activated carbon (GAC, fresh and pre-loaded) filtration were evaluated as post-treatments after ozonation. In parallel, a fresh GAC filter directly connected to the effluent of the secondary clarifier was assessed. Among the three purely biological post-treatments, the sand filtration performed best in terms of removal of dissolved organic carbon (DOC), assimilable organic carbon (AOC) and total suspended solids (TSS). The fresh activated carbon filtration ensured a significant additional micropollutants abatement after ozonation due to sorption. The relative abatement of the indicator substances ranged between 20 and 89% after 27′000 bed volumes (BV) and was still substantial at 50′000 BV. In an identical GAC filter running in parallel and being fed with the effluent of the secondary clarifier, the elimination was less efficient. Seven primary OTPs (chlorothiazide and six N -oxides) formed during ozonation could be quantified thanks to available reference standards. Their concentration decreased with increasing specific ozone doses with the concomitant formation of other OTPs. The seven OTPs were found to be stable compounds and were not abated in the biological post-treatments. They were sorbed in the fresh GAC filter, but less efficiently than the corresponding parent compounds. Two OBPs, bromate (BrO 3 − ) and N -nitrosodimethylamine (NDMA), were formed during ozonation but did not exceeded 5 μg/L for bromate and 30 ng/L for NDMA at the recommended specific ozone dose of 0.55 g O 3 /g DOC. NDMA was well abated in all post-treatments (minimum 41% during fixed bed filtration, maximum 83% during fresh GAC filtration), while bromate was very stable as expected. [ABSTRACT FROM AUTHOR]
- Published
- 2018
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9. Nitrous oxide emissions from the oxidation tank of a pilot activated sludge plant
- Author
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Lotito, Adriana Maria, Wunderlin, Pascal, Joss, Adriano, Kipf, Marco, and Siegrist, Hansruedi
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NITROUS oxide , *EMISSIONS (Air pollution) , *SEWAGE sludge , *WASTEWATER treatment , *GREENHOUSE effect , *DISSOLVED oxygen in water , *AMMONIA , *NITRITES , *SEWAGE disposal plants - Abstract
Abstract: This study discusses the results of the continuous monitoring of nitrous oxide emissions from the oxidation tank of a pilot conventional wastewater treatment plant. Nitrous oxide emissions from biological processes for nitrogen removal in wastewater treatment plants have drawn great attention over the last years, due to the high greenhouse effect. However, even if several studies have been carried out to quantify nitrous oxide emission rates from different types of treatment, quite wide ranges have been reported. Only grab samples or continuous measurements over limited periods were considered in previous studies, which can account for the wide variability of the obtained results. Through continuous monitoring over several months, our work tries to fill this gap of knowledge and get a deeper insight into nitrous oxide daily and weekly emission dynamics. Moreover, the influence of some operating conditions (sludge age, dissolved oxygen concentration in the oxidation tank, nitrogen load) was studied to determine good practices for wastewater treatment plant operation aiming at the reduction of nitrous oxide emissions. The dissolved oxygen set-point is shown to play a major role in nitrous oxide emissions. Low sludge ages and high nitrogen loads are responsible for higher emissions as well. An interesting pattern has been observed, with quite negligible emissions during most of the day and a peak with a bell-like shape in the morning in the hours of maximum nitrogen load in the plant, correlated to the ammonia and nitrite peaks in the tank. [Copyright &y& Elsevier]
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- 2012
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10. Mechanisms of N2O production in biological wastewater treatment under nitrifying and denitrifying conditions
- Author
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Wunderlin, Pascal, Mohn, Joachim, Joss, Adriano, Emmenegger, Lukas, and Siegrist, Hansruedi
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NITROUS oxide , *WASTEWATER treatment , *BIOGAS , *DENITRIFICATION , *HYDROXYLAMINE oxidase , *BIOCONCENTRATION , *AMMONIA-oxidizing bacteria , *AQUATIC microbiology - Abstract
Abstract: Nitrous oxide (N2O) is an important greenhouse gas and a major sink for stratospheric ozone. In biological wastewater treatment, microbial processes such as autotrophic nitrification and heterotrophic denitrification have been identified as major sources; however, the underlying pathways remain unclear. In this study, the mechanisms of N2O production were investigated in a laboratory batch-scale system with activated sludge for treating municipal wastewater. This relatively complex mixed population system is well representative for full-scale activated sludge treatment under nitrifying and denitrifying conditions. Under aerobic conditions, the addition of nitrite resulted in strongly nitrite-dependent N2O production, mainly by nitrifier denitrification of ammonia-oxidizing bacteria (AOB). Furthermore, N2O is produced via hydroxylamine oxidation, as has been shown by the addition of hydroxylamine. In both sets of experiments, N2O production was highest at the beginning of the experiment, then decreased continuously and ceased when the substrate (nitrite, hydroxylamine) had been completely consumed. In ammonia oxidation experiments, N2O peaked at the beginning of the experiment when the nitrite concentration was lowest. This indicates that N2O production via hydroxylamine oxidation is favored at high ammonia and low nitrite concentrations, and in combination with a high metabolic activity of ammonia-oxidizing bacteria (at 2 to 3 mgO2/l); the contribution of nitrifier denitrification by AOB increased at higher nitrite and lower ammonia concentrations towards the end of the experiment. Under anoxic conditions, nitrate reducing experiments confirmed that N2O emission is low under optimal growth conditions for heterotrophic denitrifiers (e.g. no oxygen input and no limitation of readily biodegradable organic carbon). However, N2O and nitric oxide (NO) production rates increased significantly in the presence of nitrite or low dissolved oxygen concentrations. [Copyright &y& Elsevier]
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- 2012
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11. Combined Nitritation -- Anammox: Advances in Understanding Process Stability.
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Joss, Adriano, Derlon, Nicolas, Cyprien, Clementine, Burger, Sabine, Szivak, Ilona, Traber, Jacqueline, Siegrist, Hansruedi, and Morgenroth, Eberhard
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NITROGEN removal (Sewage purification) , *SEQUENCING batch reactor process , *WASTEWATER treatment , *EFFICIENCY of sewage disposal plants , *DENITRIFYING bacteria , *AMMONIA , *MICROBIAL biotechnology - Abstract
Efficient nitrogen removal from wastewater containing high concentrations of ammonium but little organic substrate has recently been demonstrated by several full-scale applications of the combined nitritation-anammox process. While the process efficiency is in most cases very good, process instabilities have been observed to result in temporary process failures. In the current study, conditions resulting in instability and strategies to regain efficient operation were evaluated. First, data from full-scale operation is presented, showing a sudden partial loss of activity followed by recovery within less than 1 month. Results from laboratory-scale experiments indicate that these dynamics observed in full scale can be caused by partial inhibition of the ammonia oxidizing bacteria (AOB), while anammox inhibition is a secondary effect due to temporarily reduced O2 depletion. Complete anammox inhibition is observed at 0.2 mg O2∙L-1, resulting in NO2- accumulation. However, this inhibition of anammox is reversible within minutes after O2 depletion. Thus, variable AOB activity was identified as the key to reactor stability. With appropriate interpretation of the online NH4+ signal, accumulation of NO2- can be detected indirectly and used to signal an imbalance of O2 supply and AOB activity (no suitable online NO2- electrode is currently available). Second, increased abundance of nitrite-oxidizing bacteria (NOB; competing with anammox for NO2-) is known as another cause of instability. Based on a comparison of parallel full-scale reactors, it is suggested that an infrequent and short-term increased O2 supply (e.g., for maintenance of aerators) that exceeds prompt depletion of oxygen by AOB may have caused increased NOB abundance. The volumetric air supply as a proxy for O2 supply thus needs to be linked to AOB activity. Further, NOB can be washed out of the system during regular operation if the system is operated at a sludge age in the range of 45 days and by controlling the air supply according to the NO3- concentration in the treated effluent. Early detection of growing NOB abundance while the population is still low can help guide process operation and it is suggested that molecular methods of quantifying NOB abundance should be tested. [ABSTRACT FROM AUTHOR]
- Published
- 2011
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12. Kinetic assessment and modeling of an ozonation step for full-scale municipal wastewater treatment: Micropollutant oxidation, by-product formation and disinfection
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Zimmermann, Saskia G., Wittenwiler, Mathias, Hollender, Juliane, Krauss, Martin, Ort, Christoph, Siegrist, Hansruedi, and von Gunten, Urs
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OZONIZATION of water , *WASTEWATER treatment , *MICROPOLLUTANTS , *OXIDATION in water purification , *WATER disinfection , *WASTE products , *HYDROXYL group , *MONTE Carlo method , *WATER pollution - Abstract
Abstract: The kinetics of oxidation and disinfection processes during ozonation in a full-scale reactor treating secondary wastewater effluent were investigated for seven ozone doses ranging from 0.21 to 1.24 g O3 g−1 dissolved organic carbon (DOC). Substances reacting fast with ozone, such as diclofenac or carbamazepine ( > 104 M−1 s−1), were eliminated within the gas bubble column, except for the lowest ozone dose of 0.21 g O3 g−1 DOC. For this low dose, this could be attributed to short-circuiting within the reactor. Substances with lower ozone reactivity ( < 104 M−1 s−1) were only fully eliminated for higher ozone doses. The predictions of micropollutant oxidation based on coupling reactor hydraulics with ozone chemistry and reaction kinetics were up to a factor of 2.5 higher than full-scale measurements. Monte Carlo simulations showed that the observed differences were higher than model uncertainties. The overestimation of micropollutant oxidation was attributed to a protection of micropollutants from ozone attack by the interaction with aquatic colloids. Laboratory-scale batch experiments using wastewater from the same full-scale treatment plant could predict the oxidation of slowly-reacting micropollutants on the full-scale level within a factor of 1.5. The Rct value, the experimentally determined ratio of the concentrations of hydroxyl radicals and ozone, was identified as a major contribution to this difference. An increase in the formation of bromate, a potential human carcinogen, was observed with increasing ozone doses. The final concentration for the highest ozone dose of 1.24 g O3 g−1 DOC was 7.5 μg L−1, which is below the drinking water standard of 10 μg L−1. N-Nitrosodimethylamine (NDMA) formation of up to 15 ng L−1 was observed in the first compartment of the reactor, followed by a slight elimination during sand filtration. Assimilable organic carbon (AOC) increased up to 740 μg AOC L−1, with no clear trend when correlated to the ozone dose, and decreased by up to 50% during post-sand filtration. The disinfection capacity of the ozone reactor was assessed to be 1–4.5 log units in terms of total cell counts (TCC) and 0.5 to 2.5 log units for Escherichia coli (E. coli). Regrowth of up to 2.5 log units during sand filtration was observed for TCC while no regrowth occurred for E. coli. E. coli inactivation could not be accurately predicted by the model approach, most likely due to shielding of E. coli by flocs. [Copyright &y& Elsevier]
- Published
- 2011
- Full Text
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13. Full-Scale Nitrogen Removal from Digester Liquid with Partial Nitritation and Anammox in One SBR.
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JOSS, ADRIANO, SALZGEBER, DAVID, EUGSTER, JACK, KONIG, ROGER, ROTTERMANN, KARIN, BURGER, SABINE, PABIJAN, PETER, LEUMANN, SUSANNE, MOHN, JOACHIM, and SIEGRIST, HANSRUEDI
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SEQUENCING batch reactor process , *WASTEWATER treatment , *SEWAGE purification processes , *NITROGEN removal (Sewage purification) , *NEW business enterprises , *GREENHOUSE gases - Abstract
Full-scale application of partial nitritation and anammox in a single suspended-growth sequencing batch (SBR) reactor presented here confirm the process suitable for removing nitrogen from ammonium-rich wastewater with low concentrations of BOD and suspended solids: details of simple and robust process control based on online ammonium or conductivity signals are discussed by describing the full-scale startup at three municipal plants (five reactors in total). Ammonium oxidation rates of up to 500 gN m-3d-1 with conversion to N2 of over 90% are achieved in a full-scale plant, but pilot results indicate that significantly higher rates are feasible. With continuous aeration at dissolved oxygen concentrations <1 mgO2·L-1, the nitrite oxidation and the anammox reaction occur simultaneously, allowing increased overall performance and simplified process control compared to separate aerobic and anaerobic phases (segregated either temporally or in different reactors). Sedimentation of the sludge requires special attention only during startup. Although the observed N2O emissions were slightly higher than in conventional nitrogen removal, the overall greenhouse gas emissions were lower, mainly due to energy-saving. [ABSTRACT FROM AUTHOR]
- Published
- 2009
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14. Mass Flows of X-ray Contrast Media and Cytostatics in Hospital Wastewater.
- Author
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WEISSBRODT, DAVID, KOVALOVA, LUBOMIRA, ORT, CHRISTOPH, PAZHEPURACKEL, VINITHA, MOSER, RUEDI, HOLLENDER, JULIANE, SIEGRIST, HANSRUEDI, and MCARDELL, CHRISTA S.
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HOSPITALS , *EMISSIONS (Air pollution) , *MICROPOLLUTANTS , *WATER pollution measurement , *HOSPITAL waste disposal , *WASTEWATER treatment , *EFFLUENT quality testing , *PHARMACOKINETICS , *TOXICOLOGY of water pollution , *RADIOGRAPHIC contrast media ,ENVIRONMENTAL aspects - Abstract
Little is known about the significance of hospitals as point sources for emission of organic micropollutants into the aquatic environment. A mass flow analysis of pharmaceuticals and diagnostics used in hospitals was performed on the site of a representative Swiss cantonal hospital. Specifically, we analyzed the consumption of iodinated X-ray contrast media (ICM) and cytostatics in their corresponding medical applications of radiology and oncology, respectively, and their discharge into hospital wastewater and eventually into the wastewater of the municipal wastewater treatment plant. Emission levels within one day and over several days were found to correlate with the pharmacokinetic excretion pattern and the consumed amounts in the hospital during these days. ICM total emissions vary substantially from day to day from 255 to 1259 g/d, with a maximum on the day when the highest radiology treatment occurred. Parent cytostatic compounds reach maximal emissions of 8-10 mg/d. A total of 1.1%, 1.4%, and 3.7% of the excreted amounts of the cytostatico 5-fluorouracil, gemcitabine, and 2',2'-difluorodeoxyuridine (main metabolite of gemcitabine), respectively, were found in the hospital wastewater, whereas 49% of the total ICM was detected, showing a high variability among the compounds. These recoveries can essentially be explained by the high amount administered to out-patients (70% for cytostatics and 50% for ICM); therefore, only part of this dose is expected to be excreted on-site. In addition, this study emphasizes critical issues to consider when sampling in hospital sewer systems. Flow proportional sampling over a longer period is crucial to compute robust hospital mass flows. [ABSTRACT FROM AUTHOR]
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- 2009
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15. The fate of selected micropollutants in a single-house MBR
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Abegglen, Christian, Joss, Adriano, McArdell, Christa S., Fink, Guido, Schlüsener, Michael P., Ternes, Thomas A., and Siegrist, Hansruedi
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WASTEWATER treatment , *SEWAGE purification , *ARTIFICIAL membranes , *MEMBRANE separation , *SEPARATION (Technology) , *ANTIBIOTICS - Abstract
Abstract: Membrane bioreactor (MBR) technology is an interesting option for single-house wastewater treatment or small communities. Because typically a very high effluent quality is achieved with respect to pathogens, suspended solids, organics and nitrogen, the permeate is well suited for reuse. Little is known about the fate of micropollutants in such small systems. The differences between centralized and decentralized biological wastewater treatment with respect to micropollutants are manifold: besides the operational parameters like hydraulic and sludge retention time, the main difference is in the load variation. While the influent load is expected to be more or less constant in large catchments, it varies strongly in small MBRs due to irregular consumption (e.g. of medication by individuals). Concentrations of micropollutants are higher by a factor 50–1000 than in centralized treatment. It is also unknown how reliable degradation of micropollutants is in case of irregular exposure. In this study, two experiments were conducted in a small MBR treating the wastewater of a three-person household. During normal operation of the treatment plant, 25 pharmaceuticals (antibiotics, antiphlogistics, lipid regulators, iodinated contrast media and hormones) that had not been used by members of the household were added in concentrations typical for municipal wastewater. The removal of most substances was in the same range as for centralized wastewater treatment. It was shown that biological transformation was the main elimination process while adsorption to the activated sludge was negligible for most substances due to the low sludge production at high sludge retention time. No appreciable lag for inducing biological degradation was observed. The high hydraulic and sludge residence time had a positive effect on the elimination of slowly degradable substances, but this was partly compensated by the lower biological activity. An experiment with antibiotics concentrations typical for decentralized treatment (between 500 and 1000μgl−1; sulfamethoxazole, sulfapyridine, trimethoprim, clarithromycin, roxithromycin) did not show an inhibitory effect on either nitrification or denitrification. [Copyright &y& Elsevier]
- Published
- 2009
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16. Fate of beta blockers and psycho-active drugs in conventional wastewater treatment
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Wick, Arne, Fink, Guido, Joss, Adriano, Siegrist, Hansruedi, and Ternes, Thomas A.
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ADRENERGIC beta blockers , *PSYCHIATRIC drugs , *DRUGS & the environment , *WASTEWATER treatment , *ACTIVATED sludge process , *ALKALOIDS , *CODEINE , *MORPHINE - Abstract
The removal of beta blockers and psycho-active drugs was investigated in a representative conventional German WWTP by long-term measurement campaigns along different biological treatment processes. The activated sludge treatment with an elevated SRT of 18 d was the only process which led to a significant removal of certain beta blockers and psycho-active drugs. The removal efficiency was below 60% for all compounds except for the natural opium alkaloids codeine and morphine being removed by more than 80%. Primary biological transformation and sorption onto sludge as the main removal mechanisms were examined in lab-scale batch experiments. Sorption onto activated sludge was found to be negligible (<3%). The biological transformation could be described by pseudo-first order kinetics and the transformation constants k biol were used to predict the removal of beta blockers and psycho-active drugs in an activated sludge unit with a model. For most compounds the removal efficiencies measured on the full-scale WWTP were within the 95% confidence intervals predicted by the model. The results from full-scale measurements and modeling indicate that biological transformation in the nitrification tank together with parameters such as the sludge retention time and the temperature is crucial regarding the biological transformation of beta blockers and psycho-active drugs in conventional WWTPs. [Copyright &y& Elsevier]
- Published
- 2009
- Full Text
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17. How to avoid pharmaceuticals in the aquatic environment
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Larsen, Tove A., Lienert, Judit, Joss, Adriano, and Siegrist, Hansruedi
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MICROPOLLUTANTS , *SEWAGE purification , *WATER quality management , *DRUGS - Abstract
Pharmaceuticals and other micropollutants in wastewater pose a new challenge to wastewater professionals as well as to the pharmaceutical industry. Although there is a great deal of uncertainty concerning the possible detrimental effects on the aquatic ecosystems, the precautionary principle – or possibly new scientific evidence – may give rise to more stringent demands on wastewater treatment in the future. In conventional wastewater treatment plants, a combination of biological treatment with high sludge residence times and ozonation of the effluent seems to be the most promising technology. Ozonation, however, is an energy-intensive technology. Moreover, in conventional end-of-pipe systems a large part of the pollutants will always be lost to the environment due to leaking, primarily during rain. In the long term, source separation offers the more sustainable solution to the entire wastewater problem, including organic micropollutants. Urine source separation is an elegant solution to the problems of nutrients and pharmaceuticals alike and losses of untreated pollutants to the environment can be minimized. Although few technologies for the separate treatment of urine have been developed to date, the 100–500 times higher concentrations of micropollutants promise more efficient conditions for all removal technologies known from conventional wastewater treatment. [Copyright &y& Elsevier]
- Published
- 2004
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18. Removal of Estrogens in Municipal Wastewater Treatment under Aerobic and Anaerobic Conditions: Consequences for Plant Optimization.
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Joss, Adriano, Andersen, Henrik, Ternes, Thomas, Richle, Philip R., and Siegrist, Hansruedi
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SEX hormones , *ESTROGEN , *STEROID hormones , *WASTEWATER treatment , *INDUSTRIAL wastes , *LAMINAR boundary layer - Abstract
The removal of estrogens (estrone E1, estradiol E2, and ethinylestradiol EE2) was studied in various municipal wastewater treatment processes equipped for nutrient removal. A biological degradation model is formulated, am kinetic parameters are evaluated with batch experiments under various redox conditions. The resulting model calculations are then compared with sampling campaigns performed on different types of full-scale plant: conventional activated-sludge treatment, a membrane bioreactor, and a fixed-bed reactor. The results show a >90% removal of all estrogens in the activated sludge processes. (Due to the analytical quantification limit and low influent concentrations, however, this removal efficiency represents only an observable minimum.) The removal efficiencies of 77% and ≥90% for E1 and E2. respectively, in the fixed-bed reactor represent a good performance in view of the short hydraulic retention time of 35 min. The first-order removal- rate constant in batch experiments observed for E2 varied from 150 to 950 d-1 for a 1 gSS L-1 sludge suspension. The removal efficiency of E1 and EE2 clearly depends on the redox conditions, the maximum removal rate occurring under aerobic conditions when E1 was reduced to E2. Sampling campaigns on full-scale plants indicate that the kinetic values identified in batch experiments (without substrate addition) for the natural estrogens may overestimate the actual removal rates. Although this paper does not give direct experimental evidence, it seems that the substrate present in the raw influent competitively inhibits the degradation of E1 and E2. These compounds are therefore removed mainly in activated sludge compartments with low substrate loading. [ABSTRACT FROM AUTHOR]
- Published
- 2004
- Full Text
- View/download PDF
19. Biological treatment of ammonium-rich wastewater by partial nitritation and subsequent anaerobic ammonium oxidation (anammox) in a pilot plant
- Author
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Fux, Christian, Boehler, Marc, Huber, Philipp, Brunner, Irene, and Siegrist, Hansruedi
- Subjects
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OXIDATION , *WASTEWATER treatment , *AMMONIUM , *NITRITES - Abstract
In wastewater treatment plants with anaerobic sludge digestion, 15–20% of the nitrogen load is recirculated to the main stream with the return liquors from dewatering. Separate treatment of this ammonium-rich digester supernatant would significantly reduce the nitrogen load of the activated sludge system. Some years ago, a novel biological process was discovered in which ammonium is converted to nitrogen gas under anoxic conditions with nitrite as the electron acceptor (anaerobic ammonium oxidation, anammox). Compared to conventional nitrification and denitrification, the aeration and carbon-source demand is reduced by over 50 and 100%, respectively. The combination of partial nitritation to produce nitrite in a first step and subsequent anaerobic ammonium oxidation in a second reactor was successfully tested on a pilot scale (3.6 m3) for over half a year. This report focuses on the feasibility of nitrogen removal from digester effluents from two different wastewater treatment plants (WWTPs) with the combined partial nitritation/anammox process. Nitritation was performed in a continuously stirred tank reactor (V=2.0 m3) without sludge retention. Some 58% of the ammonium in the supernatant was converted to nitrite. At 30 °C the maximum dilution rate Dx was 0.85 d−1, resulting in nitrite production of 0.35 kg NO2–N m−3reactor d−1. The nitrate production was marginal. The anaerobic ammonium oxidation was carried out in a sequencing batch reactor (SBR, V=1.6 m3) with a nitrogen elimination rate of 2.4 kg N m−3reactor d−1 during the nitrite-containing periods of the SBR cycle. Over 90% of the inlet nitrogen load to the anammox reactor was removed and the sludge production was negligible. The nitritation efficiency of the first reactor limited the overall maximum rate of nitrogen elimination. [Copyright &y& Elsevier]
- Published
- 2002
- Full Text
- View/download PDF
20. N2O emission in full-scale wastewater treatment: Proposing a refined monitoring strategy.
- Author
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Gruber, Wenzel, Villez, Kris, Kipf, Marco, Wunderlin, Pascal, Siegrist, Hansruedi, Vogt, Liliane, and Joss, Adriano
- Abstract
• Long-term N 2 O emission data set of three different activated sludge systems. • Significant spatial and temporal emission variation on all three treatment plants. • Guiding principles for monitoring on wastewater treatment plants with open tanks. • Separate reject water treatment can reduce overall N 2 O emissions. Nitrous oxide (N 2 O) emissions from wastewater treatment contribute significantly to greenhouse gas emissions. They have been shown to exhibit a strong seasonal and daily profile in previously conducted monitoring campaigns. However, only two year-long online monitoring campaigns have been published to date. Based on three monitoring campaigns on three full-scale wastewater treatment plants (WWTPs) with different activated sludge configurations, each of which lasted at least one year, we propose a refined monitoring strategy for long-term emission monitoring with multiple flux chambers on open tanks. Our monitoring campaigns confirm that the N 2 O emissions exhibited a strong seasonal profile and were substantial on all three plants (1–2.4% of the total nitrogen load). These results confirm that N 2 O is the most important greenhouse gas emission from wastewater treatment. The temporal variation was more distinct than the spatial variation within aeration tanks. Nevertheless, multiple monitoring spots along a single lane are crucial to assess representative emission factors in flow-through systems. Sequencing batch reactor systems were shown to exhibit comparable emissions within one reactor but significant variation between parallel reactors. The results indicate that considerable emission differences between lanes are to be expected in cases of inhomogeneous loading and discontinuous feeding. For example, N 2 O emission could be shown to depend on the amount of treated reject water: lanes without emitted <1% of the influent load, while parallel lanes emitted around 3%. In case of inhomogeneous loading, monitoring of multiple lanes is required. Our study enables robust planning of monitoring campaigns on WWTPs with open tanks. Extensive full-scale emission monitoring campaigns are important as a basis for reliable decisions about reducing the climate impact of wastewater treatment. More specifically, such data sets help us to define general emission factors for wastewater treatment plants and to construct and critically evaluate N 2 O emission models. [ABSTRACT FROM AUTHOR]
- Published
- 2020
- Full Text
- View/download PDF
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