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Tree cores (Pinus nigra ssp. laricio) and leaves (Castanea sativa) from the flanks of Mount Etna, Sicily were analysed by ICP-MS to investigate whether volcanogenic cations within plant material provide an archive of a volcano's temporal and spatial depositional influence. There is significant compositional variability both within and between trees, but no systematic dendrochemical correlation with periods of effusive, explosive or increased degassing activity. Dendrochemistry does not provide a record of persistent but fluctuating volcanic activity. Foliar levels of bioaccumulated cations correspond to modelled plume transport patterns, and map short-term volcanic fumigation. Around the flanks of the volcano foliar variation is greater for volatile cations (Cs, Cd, Pb) than for lithophilic cations (Ba, Sr), consistent with trace-metal supply from volcanic aerosol during quiescent periods.

We report CO2 emission rates and plume δ13C during the July 2023 eruption at Litli Hrútur in the Fagradalsfjall region of the Reykjanes Peninsula. The CO2 emission rates were measured by UAV utilizing a new method of data extrapolation that enables obtaining rapid flux results of dynamic eruption plumes. The δ13C values are consistent with degassing-induced isotopic fractionation of the magma during and after the eruption. Our results show that rapid, real-time CO2 flux measurements coupled with isotopic values of samples collected at the same time provide key insights into the dynamics of volcanic eruptions and have the potential of forecasting the termination of activity. [ABSTRACT FROM AUTHOR]

Open conduit volcanoes erupt with the highest frequency on Earth. Their activity is characterized by an outgassing flux that largely exceeds the gas that could be released by the erupted magma; and by frequent small explosions intercalated by larger events that pose a significant risk to locals, tourists, and scientists. Thus, identifying the signs of an impending larger explosion is of utmost importance for the mitigation of volcanic hazard. Larger explosive events have been associated with the sudden ascent of volatile rich magmas, however, where and why magma accumulates within the plumbing system remains unclear. Here we show that the interaction between CO2‐rich fluids and magma spontaneously leads to the accumulation of volatile‐rich, low density and gravitationally unstable magma at depth, without the requirement of permeability barriers. CO2‐flushing forces the exsolution of water and the increase of magma viscosity, which proceeds from the bottom of the magma column upward. This rheological configuration unavoidably leads to the progressive thickening of a gas‐rich and low density (i.e., gravitationally unstable) layer at the bottom of the feeding system. Our calculations account for observations, gas monitoring and petrological data; moreover, they provide a basis to trace the approach to deeply triggered large or paroxysmal eruptions and estimate their size from monitoring data. Our model is finally applied to Stromboli volcano, an emblematic example of open conduit volcano, but can be applied to any other open conduit volcano globally and offers a framework to anticipate the occurrence of unexpectedly large eruptions. Plain Language Summary: Open conduit volcanoes erupt with the highest frequency on Earth and release significantly more gas than magma. Their activity is characterized by almost continuous and small explosions that are intercalated by significantly larger explosive events. The relatively continuous explosive activity makes these volcanoes attractive both for scientific research and tourism, however, unexpectedly large explosions pose a significant risk to scientists and tourists. The excess gas these volcanoes release is CO2‐rich and its interaction with magma leads to the accumulation of gas‐rich and low‐density magma at depth, below higher density magma. We suggest that the gravitational destabilization of this deep and gas rich magma is ultimately responsible for the large explosions that punctuate the activity of open conduit volcanoes. The approach to this larger events can be traced with continuous gas monitoring, which therefore provides a unique opportunity to anticipate this otherwise unexpected explosions. Key Points: Continuous CO2 flushing can prime basaltic volcanic systems toward more energetic eruptionsAccumulation of gas‐rich and low‐density magma at depth results from CO2 flushing alone and no ad‐hoc physical barrier is requiredBuild‐up to larger explosions can be monitored through continuous gas monitoring at the surface [ABSTRACT FROM AUTHOR]

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HBr emissions from volcanoes lead rapidly to the formation of BrO within volcanic plumes and have an impact on tropospheric chemistry, at least at the local and regional scales. The motivation of this paper is to prepare a framework for further 3D modelling of volcanic halogen emissions in order to determine their fate within the volcanic plume and then in the atmosphere at the regional and global scales. The main aim is to evaluate the ability of the model to produce a realistic partitioning of bromine species within a grid box size typical of MOCAGE (Model Of atmospheric Chemistry At larGE scale) 3D (0.5 ∘ × 0.5 ∘). This work is based on a 1D single-column configuration of the global chemistry-transport model MOCAGE that has low enough computational cost to allow us to perform a large set of sensitivity simulations. This paper uses the emissions from the Mount Etna eruption on 10 May 2008. Several reactions are added to MOCAGE to represent the volcanic plume halogen chemistry. A simple plume parameterisation is also implemented and tested. The use of this parameterisation tends to only slightly limit the efficiency of BrO net production. Both simulations with and without the parameterisation give results for the partitioning of the bromine species, of ozone depletion and of the BrO/SO2 ratio that are consistent with previous studies. A series of test experiments were performed to evaluate the sensitivity of the results to the composition of the emissions (primary sulfate aerosols, Br radical and NO) and to the effective radius assumed for the volcanic sulfate aerosols. Simulations show that the plume chemistry is sensitive to all these parameters. We also find that the maximum altitude of the eruption changes the BrO production, which is linked to the vertical variability of the concentrations of oxidants in the background air. These sensitivity tests display changes in the bromine chemistry cycles that are generally at least as important as the plume parameterisation. Overall, the version of the MOCAGE chemistry developed for this study is suitable to produce the expected halogen chemistry in volcanic plumes during daytime and night-time. [ABSTRACT FROM AUTHOR]

Featured Application: Authors are encouraged to provide a concise description of the specific application or a potential application of the work. This section is not mandatory. Volcanologists have demonstrated that carbon dioxide (CO2) fluxes are precursors of volcanic eruptions. Controlling volcanic gases and, in particular, the CO2 flux, is technically challenging, but we can retrieve useful information from magmatic/geological process studies for the mitigation of volcanic hazards including air traffic security. Existing techniques used to probe volcanic gas fluxes have severe limitations such as the requirement of near-vent in situ measurements, which is unsafe for operators and deleterious for equipment. In order to overcome these limitations, a novel range-resolved DIAL-Lidar (Differential Absorption Light Detection and Ranging) has been developed as part of the ERC (European Research Council) Project "BRIDGE", for sensitive, remote, and safe real-time CO2 observations. Here, we report on data collection, processing techniques, and the most significant findings of the experimental campaigns carried out at the most hazardous volcanic areas in Italy: Pozzuoli Solfatara (Phlegraen Fields), Stromboli, and Mt. Etna. The BrIdge voLcanic LIdar—BILLI has successfully obtained accurate measurements of in-plume CO2 concentration and flux. In addition, wind velocity has also been retrieved. It has been shown that the measurements of CO2 concentration performed by BILLI are comparable to those carried out by volcanologists with other standard techniques, heralding a new era in the observation of long-term volcanic gases. [ABSTRACT FROM AUTHOR]

Located on Halmahera island, Dukono is among the least known volcanoes in Indonesia. A compilation of the rare available reports indicates that this remote and hardly accessible volcano has been regularly in eruption since 1933, and has undergone nearly continuous eruptive manifestation over the last decade. The first study of its gas emissions, presented in this work, highlights a huge magmatic volatile contribution into the atmosphere, with an estimated annual output of about 290 kt of SO, 5000 kt of HO, 88 kt of CO, 5 kt of HS and 7 kt of H. Assuming these figures are representative of the long-term continuous eruptive activity, then Dukono is the current most prominent volcanic gas discharge point in Indonesia and ranks among the top-ten volcanic SO sources on earth. Combining our findings with other recent volcanic SO flux results, obtained during periodic campaigns at a number of volcanoes with DOAS and UV-Cameras, the SO emission budget for Indonesia is estimated at 540 kt year, representing 2-3% of the global volcanic SO contribution into the atmosphere. This figure should be considered as minimum as gas emissions from numerous other active volcanoes in Indonesia are yet to be evaluated. This voluminous degassing output from Dukono is sustained by a depleted Indian-MORB (I-MORB) mantle source. This latter is currently undergoing lateral pressure from the steepening of the subducted slab, the downward force from the Philippine Sea plate and the westward motion of a continental fragments along the Sorong fault, leading to high fluid fluxes to the surface. Over the course of Dukono eruptive activity, the magma reservoir has changed from a less differentiated source that fed the past voluminous lava flows to a more evolved melt that sustained the current ongoing explosive activity. [ABSTRACT FROM AUTHOR]

The 2014-2015 Bárðarbunga fissure eruption at Holuhraun in central Iceland was distinguished by the high emission of gases, in total 9.6 Mt SO2, with almost no tephra. This work collates all ground-based measurements of this extraordinary eruption cloud made under particularly challenging conditions: remote location, optically dense cloud with high SO2 column amounts, low UV intensity, frequent clouds and precipitation, an extensive and hot lava field, developing ramparts, and high-latitude winter conditions. Semi-continuous measurements of SO2 flux with three scanning DOAS instruments were augmented by car traverses along the ring-road and along the lava. The ratios of other gases/SO2 were measured by OP-FTIR, MultiGAS, and filter packs. Ratios of SO2/HCl = 30-110 and SO2/HF = 30-130 show a halogen-poor eruption cloud. Scientists on-site reported extremely minor tephra production during the eruption. OPC and filter packs showed low particle concentrations similar to non-eruption cloud conditions. Three weather radars detected a droplet-rich eruption cloud. Top of eruption cloud heights of 0.3-5.5 km agl were measured with ground- and aircraft-based visual observations, web camera and NicAIR II infrared images, triangulation of scanning DOAS instruments, and the location of SO2 peaks measured by DOAS traverses. Cloud height and emission rate measurements were critical for initializing gas dispersal simulations for hazard forecasting. [ABSTRACT FROM AUTHOR]

Volcanic eruptions are often preceded by precursory increases in the volcanic carbon dioxide (CO2) flux. Unfortunately, the traditional techniques used to measure volcanic CO2 require near-vent, in situ plume measurements that are potentially hazardous for operators and expose instruments to extreme conditions. To overcome these limitations, the project BRIDGE (BRIDging the gap between Gas Emissions and geophysical observations at active volcanoes) received funding from the European Research Council, with the objective to develop a new generation of volcanic gas sensing instruments, including a novel DIAL-Lidar (Differential Absorption Light Detection and Ranging) for remote (e.g., distal) CO2 observations. Here we report on the results of a field campaign carried out at Mt. Etna from 28 July 2016 to 1 August 2016, during which we used this novel DIAL-Lidar to retrieve spatially and temporally resolved profiles of excess CO2 concentrations inside the volcanic plume. By vertically scanning the volcanic plume at different elevation angles and distances, an excess CO2 concentration of tens of ppm (up to 30% above the atmospheric background of 400 ppm) was resolved from up to a 4 km distance from the plume itself. From this, the first remotely sensed volcanic CO2 flux estimation from Etna's northeast crater was derived at ≈2850-3900 tons/day. This Lidar-based CO2 flux is in fair agreement with that (≈2750 tons/day) obtained using conventional techniques requiring the in situ measurement of volcanic gas composition. [ABSTRACT FROM AUTHOR]

Volcanic gases give information on magmatic processes. In particular, anomalous releases of carbon dioxide precede volcanic eruptions. Up to now, this gas has been measured in volcanic plumes with conventional measurements that imply the severe risks of local sampling and can last many hours. For these reasons and for the great advantages of laser sensing, the thorough development of volcanic lidars has been undertaken at ENEA (Italian National Agency for New Technologies, Energy and Sustainable Economic Development). In fact, lidar profiling allows one to scan remotely volcanic plumes in a fast and continuous way, and with high spatial and temporal resolution. A differential absorption lidar instrument will be presented in this paper: BILLI (BrIdge voLcanic LIdar). It is based on injection-seeded Nd:YAG laser, double-grating dye laser, difference frequency mixing and optical parametric amplifier. BILLI is funded by the ERC (European Research Council) project BRIDGE (BRIDging the gap between Gas Emissions and geophysical observations at active volcanos). It scanned the gas emitted by Pozzuoli Solfatara (Naples, Italy) and Stromboli Volcano (Sicily, Italy) during field campaigns carried out from October 13 to 17, 2014, and from June 24 to 29, 2015, respectively. Carbon dioxide concentration maps were retrieved remotely in few minutes in the crater areas. To our knowledge, it is the first time that carbon dioxide in a volcanic plume is retrieved by lidar. This result represents the first direct measurement of this kind ever performed on active volcanos and shows the high potential of laser remote sensing in early detection of volcanic hazard. [ABSTRACT FROM AUTHOR]

Abstract: The recent eruption of Stromboli in February–April 2007 offered a unique chance to test our current understanding of processes driving the transition from ordinary (persistent Strombolian) to effusive activity, and the ability of instrumental geophysical and geochemical networks to interpret and predict these events. Here, we report on the results of two years of in-situ sensing of the CO2/SO2 ratio in Stromboli''s volcanic gas plume, in the attempt to put constraints on the trigger mechanisms and dynamics of the eruption. We show that large variations of the plume CO2/SO2 ratio (range, 0.9–26) preceded the onset of the eruption (since December 2007), interrupting a period of relatively-steady and low ratios (time-averaged ratio, 4.3) lasting from at least May to November 2006. By contrasting our observations with numerical simulations of volcanic degassing at Stromboli, derived by use of an equilibrium saturation model, we suggest that the pre-eruptive increase of the ratio reflected an enhanced supply of deeply-derived CO2-rich gas bubbles to the shallow-plumbing system. This larger-than-normal ascent of gas bubbles was likely sourced by a 1–3 km deep gas–melt separation region (probably a magma storage zone), and caused faster convective overturning of magmas in the shallow conduit; an increase in the explosive rate and in seismic tremor, and finally the collapse of the la Sciara del Fuoco sector triggering the effusive phase. The high CO2/SO2 ratios (up to 21) observed during the effusive phase, and particularly in the days and hours before a paroxysmal explosion on March 15, 2007, indicate the persistence of the same gas source; and suggest that de-pressurization of the same 1–3 km deep magma storage zone could have been the trigger mechanism for the paroxysm itself. [Copyright &y& Elsevier]

It is generally accepted, but not experimentally proven, that a quantitative prediction of volcanic eruptions is possible from the evaluation of volcanic gas data. By discussing the results of two years of real-time observation of H2O, CO2, and SO2 in volcanic gases from Mount Etna volcano, we unambiguously demonstrate that increasing CO2/SO2 ratios can allow detection of the pre-eruptive degassing of rising magmas. Quantitative modeling by the use of a saturation model allows us to relate the pre-eruptive increases of the CO2/SO2 ratio to the refilling of Etna's shallow conduits with CO2-rich deep-reservoir magmas, leading to pressurization and triggering of eruption. The advent of real-time observations of H2O, CO2, and SO2, combined with well-constrained models of degassing, represents a step forward in eruption forecasting. [ABSTRACT FROM AUTHOR]

We used a one-year long SO2 flux record, which was obtained using a novel algorithm for real-time automatic processing of ultraviolet (UV) camera data, to characterize changes in degassing dynamics at the Mt. Etna volcano in 2016. These SO2 flux records, when combined with independent thermal and seismic evidence, allowed for capturing switches in activity from paroxysmal explosive eruptions to quiescent degassing. We found SO2 fluxes 1.5–2 times higher than the 2016 average (1588 tons/day) during the Etna's May 16–25 eruptive paroxysmal activity, and mild but detectable SO2 flux increases more than one month before its onset. The SO2 flux typically peaked during a lava fountain. Here, the average SO2 degassing rate was ~158 kg/s, the peak emission was ~260 kg/s, and the total released SO2 mass was ~1700 tons (in 3 h on 18 May, 2016). Comparison between our data and prior (2014–2015) results revealed systematic SO2 emission patterns prior to, during, and after an Etna's paroxysmal phases, which allows us to tentatively identify thresholds between pre-eruptive, syn-eruptive, and post-eruptive degassing regimes. [ABSTRACT FROM AUTHOR]

There have been substantial advances in the ability to monitor the activity of hazardous volcanoes in recent decades. However, obtaining early warning of eruptions remains challenging, because the patterns and consequences of volcanic unrests are both complex and nonlinear. Measuring volcanic gases has long been a key aspect of volcano monitoring since these mobile fluids should reach the surface long before the magma. There has been considerable progress in methods for remote and in-situ gas sensing, but measuring the flux of volcanic CO2-the most reliable gas precursor to an eruption-has remained a challenge. Here we report on the first direct quantitative measurements of the volcanic CO2 flux using a newly designed differential absorption lidar (DIAL), which were performed at the restless Campi Flegrei volcano. We show that DIAL makes it possible to remotely obtain volcanic CO2 flux time series with a high temporal resolution (tens of minutes) and accuracy (<30%). The ability of this lidar to remotely sense volcanic CO2 represents a major step forward in volcano monitoring, and will contribute improved volcanic CO2 flux inventories. Our results also demonstrate the unusually strong degassing behavior of Campi Flegrei fumaroles in the current ongoing state of unrest. [ABSTRACT FROM AUTHOR]

Identifying the onset of volcano unrest and providing an unequivocal identification of volcano reawakening remain challenging problems in volcanology. At Piton de la Fournaise, renewal of eruptive activity in 2014–2015, after 41 months of quiescence and deflation, was associated with long-term continuous edifice inflation measured by GNSS. Inflation started on June 9, 2014, and its rate progressively increased through 2015. Inflation onset was rapidly followed by an eruption on June 20–21, 2014, showing that volcano reactivation can be extremely fast, even after long non-eruptive phases. This short-lived eruption involved a shallow source (1.3–1.9 km depth below the summit). The inflation that followed, and eruptions in 2015, involved a larger depth range of fluid accumulation, constrained by inverse modeling at ca. 3.9 to 1.2–1.7 km depth. This time evolution reveals that volcano reawakening was associated with continuous pressurization of the shallowest parts of its plumbing system, triggered by progressive upwards transfer of magma from greater depth. A deep magma pulse occurred in mid-April 2015 and was associated with deep seismicity (3 to 9.5 km depth) and CO 2 enrichment in fluids emitted by summit fumaroles. From this date, ground deformation accelerated and the output rates of eruptions increased, culminating in the long-lasting, large-volume, August–October eruption (~ 36 Mm 3 ). This evolution suggests that deep magma/fluid transfer through an open conduit system first provoked the expulsion of the top of the plumbing system in June 2014, and then induced the progressive vertical transfer of the entire plumbing system down to 9 km (four eruptions in 2015). The new sustained feeding of the volcano was also at the origin of the hydrothermal system perturbation and the acceleration of the eastern flank motion, which favor lateral dike propagation and the occurrence of frequent and increasingly large eruptions. Our results highlight the fast and progressive way in which basaltic magmatic systems can wake up. [ABSTRACT FROM AUTHOR]

Open-vent volcanic activity is typically sustained by ascent and degassing of shallow magma, in which the rate of magma supply to the upper feeding system largely exceeds the rate of magma eruption. Such unbalance between supplied (input) and erupted (output) magma rates is thought to result from steady, degassing-driven, convective magma overturning in a shallow conduit/feeding dyke. Here, we characterize shallow magma circulation at Stromboli volcano by combining independent observations of heat (Volcanic Radiative Power; via satellite images) and gas (SO 2 , via UV camera) output in a temporal interval (from August 1, 2018 to April 30, 2020) encompassing the summer 2019 effusive eruption and two paroxysmal explosions (on July 3 and August 28, 2019). We show that, during the phase of ordinary strombolian explosive activity that preceded the 2019 effusive eruption, the average magma input rate (0.1-0.2 m3/s) exceeds the magma eruption rate (0.001-0.01 m3/s) by ∼2 orders of magnitude. Conversely, magma input and output rates converge to an average of ∼0.4 m3/s during the summer 2019 summit effusion, implying an overall suppression of magma recycling back into the feeding system, and hence of excess degassing. We find that, during the effusive eruption, the peak in SO 2 emissions lags behind the thermal emission peak by ∼27 days, suggesting that magma output, feeding the lava flow field, initially dominates over magma input in the conduit. We propose that this conduit mass unloading, produced by this initial phase of the effusive eruption, leads to an overall decompression (of up to 30 Pa/s) of the shallow plumbing system, ultimately causing ascent of less-dense, volatile-rich magma batch(es) from depth, enhanced explosive activity, and elevated SO 2 fluxes culminating into a paroxysmal explosion on August 28. Our results demonstrate that combined analysis of thermal and SO 2 flux time-series paves the way to improved understanding of shallow magmatic system dynamics at open-vent volcanoes, and of the transition from explosive to effusive activity regimes. • Open-vent volcanoes are explained from combined thermal and gas flux observations. • Distinct volcano regimes resolvable from changes in the magma input vs. output rate. • Magma convective overturning stops at the strombolian to effusive transition. • Effusive eruptions involve magma recharge/discharge cycles in the feeding system. [ABSTRACT FROM AUTHOR]

Abstract: We report results from an observational and modeling study of reactive chemistry in the tropospheric plume emitted by Redoubt Volcano, Alaska. Our measurements include the first observations of Br and I degassing from an Alaskan volcano, the first study of O3 evolution in a volcanic plume, as well as the first detection of BrO in the plume of a passively degassing Alaskan volcano. This study also represents the first detailed spatially-resolved comparison of measured and modeled O3 depletion in a volcanic plume. The composition of the plume was measured on June 20, 2010 using base-treated filter packs (for F, Cl, Br, I, and S) at the crater rim and by an instrumented fixed-wing aircraft on June 21 and August 19, 2010. The aircraft was used to track the chemical evolution of the plume up to ~30km downwind (2h plume travel time) from the volcano and was equipped to make in situ observations of O3, water vapor, CO2, SO2, and H2S during both flights plus remote spectroscopic observations of SO2 and BrO on the August 19th flight. The airborne data from June 21 reveal rapid chemical O3 destruction in the plume as well as the strong influence chemical heterogeneity in background air had on plume composition. Spectroscopic retrievals from airborne traverses made under the plume on August 19 show that BrO was present ~6km downwind (20min plume travel time) and in situ measurements revealed several ppbv of O3 loss near the center of the plume at a similar location downwind. Simulations with the PlumeChem model reproduce the timing and magnitude of the observed O3 deficits and suggest that autocatalytic release of reactive bromine and in-plume formation of BrO were primarily responsible for the observed O3 destruction in the plume. The measurements are therefore in general agreement with recent model studies of reactive halogen formation in volcanic plumes, but also show that field studies must pay close attention to variations in the composition of ambient air entrained into volcanic plumes in order to unambiguously attribute observed O3 anomalies to specific chemical or dynamic processes. Our results suggest that volcanic eruptions in Alaska are sources of reactive halogen species to the subarctic troposphere. [Copyright &y& Elsevier]

The first gas and thermal measurements at the summit of the Gamalama volcano indicate that the system is dominated by hydrothermal processes. This is highlighted by the prevalence of H 2 S over SO 2 (H 2 S/SO 2 = 2–8), a high CO 2 /SO 2 ratio (76–201), and a low heat transfer (3.0 MW) to the surface. A relative variation in gas composition is observed along the degassing fracture zone, possibly due to partial S scrubbing. Despite this surface hydrothermal signature, the system exhibits high gas equilibrium temperatures (425–480 °C), indicating that fluids are not exclusively derived from a boiling hydrothermal aquifer, but also sourced by cooling and crystallizing basaltic magma at deep that continues to inject magmatic fluids into the system. This hydrothermally dominated activity on Gamalama possibly persisted over the last two decades, during which a high number of eruptive events were witnessed. The period coincides with the opening of large fractures at the summit that subsequently shifted the volcanic activity from the crater center to the peripheral fractures zones. These fractures that possibly developed in response to the regional geodynamics, have weakened the hydrothermal seal, allowing the pressure developed by the hydrothermal-magmatic system and promoted by the high annual rainfall, to rapidly exceeds the tensile strength of the seal leading to the numerous phreatic eruptions. • Gamalama a frequently erupting volcano but poorly studied. • A volcanic system dominated by hydrothermal manifestation. • A remarkable shift of volcanic activity from the crater center to the peripheral fractures zones. • Fractures have weakened the hydrothermal seal leading to recurrent phreatic eruptions. [ABSTRACT FROM AUTHOR]

Open vent basaltic volcanoes account for a substantial portion of the global atmospheric outgassing flux, largely through passive degassing and mild explosive activity. We present volcanic gas flux and composition data from Yasur Volcano, Vanuatu collected in July 2018. The average volcanic plume chemistry is characterised by a mean molar CO 2 /SO 2 ratio of 2.14, H 2 O/SO 2 of 148 and SO 2 /HCl of 1.02. The measured mean SO 2 flux in the period of 6th to 9th July is 4.9 kg s−1. Therefore, the mean fluxes of the other species are 7.5 kg∙s−1 CO 2 , 208 kg∙s−1 H 2 O and 4.8 kg∙s−1 HCl. The degassing regime at Yasur volcano ranges from 'passive' to 'active' styles, with the latter including Strombolian activity and spattering. Gases emitted during active degassing are enriched in SO 2 over HCl and CO 2 over SO 2 relative to passive degassing, with CO 2 /SO 2 ratios of 2.85 ± 0.17, SO 2 /HCl of 1.6 ± 0.22, and H 2 O/SO 2 of 315 ± 78.8. Gases emitted during passive degassing have CO 2 /SO 2 ratios of 1.96 ± 0.12, SO 2 /HCl of 0.50 ± 0.07 and H 2 O/SO 2 of 174 ± 43.5. We use a model of volatile degassing derived from melt inclusion studies (Metrich et al., 2011), combined with our observations of chemical variations in the outgassing bubbles to propose a mechanism for magma degassing in the conduit at Yasur. We envisage a shallow conduit filled with crystal-rich magma, forming a viscous and mobile plug that develops an effective yield strength from the surface to a depth of at least 2000 m, in which bubbles are trapped, grow, ascend towards the surface and burst in a typical Strombolian eruption. Deeper bubbles released during active degassing are enriched in CO 2 and SO 2 compared to bubbles released during 'passive degassing', which are sourced from close to the surface, and are, consequently, HCl-rich. • FTIR and Multi-GAS measurements at Yasur Volcano constrain volcanic gas compositions • The cyclic variation in gas geochemistry at Yasur is explained by therupture and reforming of a crystal-rich plug. • High fluxes of volcanic gases have persisted at Yasur Volcano for decades [ABSTRACT FROM AUTHOR]

Basaltic volcanoes are characterized by low-level explosions and lava fountaining, but are capable of violent subplinian to plinian eruptions. Stromboli Volcano has been observed with seismometers and tiltmeters to deform prior to explosion [Genco and Ripepe, 2010]. Quantitatively linking this precursory deformation, often interpreted as inflation due to an influx of magma and gas, with the volume of subsequent erupted material (gas and tephra) will be helpful for understanding eruption dynamics and in hazard mitigation, as we can better constrain expected volatile output from monitored volume input. To these aims, we temporarily deployed 7 seismometers, 7 infrasonic microphones, an FTIR, FLIR, gravimeter, and MultiGAS at Stromboli Volcano, Italy in May 2018. We use these data in combination with data from permanently installed seismometers, infrasound sensors, tiltmeters, and a UV camera to examine the volatile budget of Stromboli by comparing shallow volume input derived from broadband, tilt-affected seismic and tilt data with volume output from infrasound and gas data. First, we characterize and locate the seismically-derived tilt source using a nonlinear moment tensor inversion method [Tape and Tape, 2012; Waite and Lanza, 2016] and use the result to quantify the volatile volume input. Initial inversion results place the tilt-affected source ~300 m below the active craters. We will attempt to characterize the input volume density using gravity data. Independently, we characterize and locate the infrasonic explosion source and quantify the output volume using an infrasonic waveform inversion technique that accounts for the influence of topography by computing numerical Green's functions by way of a 3-D finite difference time domain method [Kim et al., 2015]. The seismically estimated volume input and infrasonically estimated volume output will then be validated with volume output estimated from gas observations. This quantitative examination of tilt, infrasound and gas data aims to advance our ability to determine the size of eruption prior to its occurrence. [ABSTRACT FROM AUTHOR]