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A method for obtaining non-isocyanate polyurethane (NIPU) foams from cyclic carbonate (CC) based on soybean oil was developed. For this purpose, cyclic carbonate was synthesized from epoxidized soybean oil and CO2 using various ionic liquids (ILs) as catalysts. Among the tested ILs, the highest selectivity (100%) and CC yield (98%) were achieved for 1-ethyl-3-methylimidazolium ([emim]Br). Without any purification, the resulting cyclic carbonate was reacted directly with diethylenetriamine as a model crosslinking agent to produce NIPU foams. It was found that the soybean oil-based CC synthesized with bromide imidazolium ionic liquids exhibited significantly shorter gelling times (8 min 50 s for [emim]Br and 9 min 35 s for [bmim]Br) compared to those obtained with the conventional TBAB catalyst (26 min 15 s). A shorter gelling time is a crucial parameter for the crosslinking process in foams. The obtained foams were subjected to mechanical tests and a morphology analysis. [ABSTRACT FROM AUTHOR]

The paper presents a technology for producing base oil by oxidizing organosulfur compounds, contained in petroleum distillates and deasphaltisates, with hydrogen peroxide in the presence of vegetable (rapeseed and castor) oils, followed by extraction of oxidates and dewaxing of raffinates. Extraction of the resulting oxidized mixture (oxidate) was carried out with N-methylpyrrolidone. The content of rapeseed oil contained in the raffinate and extract was determined. The extract solution from a medium-viscosity oil distillate was cooled to obtain a secondary raffinate represented by a sulfoxide concentrate. The secondary raffinate was used as a base oil for producing a lubricant with high tribological properties for use in heavily loaded friction units. The rapeseed oil remained in the raffinate improves its viscosity index and lubricating properties. The raw materials and obtained raffinates were analyzed to assess their physicochemical and tribological properties. [ABSTRACT FROM AUTHOR]

Emollients are valued ingredients of many cosmetic products and medical devices used to support the treatment and prevention of many skin diseases. Despite the fact that they are one of the oldest cosmetic ingredients, raw materials as well as new recipe solutions are constantly being sought, the main goal of which is to obtain products with the most favorable physicochemical properties while improving the hydration of the stratum corneum and softening and smoothing the skin. It should be noted that there are few scientific articles on the effect of emollients on the physicochemical and usable properties of emollient preparations of the body-oils type. The obtained formulations were subjected to physicochemical tests (dynamic viscosity, surface tension, contact angle, and color evaluation), and the degree of skin hydration and lubrication after application of the developed cosmetic oils was evaluated. Cosmetic oils based on natural emollients were characterized by weaker spreading abilities, which was confirmed by their higher viscosity, surface tension, and contact-angle results relative to those obtained for cosmetic oils based on synthetic emollients. In addition, it was found that the use of both groups of cosmetic oils based on natural and synthetic emollients leads to an increase in the degree of hydration of the skin and an increase in its oiliness. However, a higher increase in the degree of hydration and a lower decrease in the level of skin lubrication are observed after the application of body oils based on natural emollients. [ABSTRACT FROM AUTHOR]

Vegetable oils are a highly promising alternative to produce various lubricants, owing to their biodegradability and eco-friendliness. In comparison to mineral oil, these oils possess a higher flash point and viscosity index, along with superior lubricating properties. Additionally, most of the vegetable oils are easily accessible in local markets in India. However, their industrial application is limited by poor thermal and oxidative stability, which can be addressed through chemical modification, the addition of appropriate additives, or by blending these oils. Greases, characterized by their semi-solid consistency, are widely used lubricants. Most of the grease production is based on mineral oils as base oil and lithium soap as a thickener. These materials are not only non-biodegradable but also scarce and have health implications. Consequently, biodegradable grease represents an eco-friendly and healthy alternative. Grease made using vegetable oils with the required properties has the potential to bring about revolutionary changes. The present work focuses on the feasibility of using chemically modified blended rice bran oil (RBO) and Calophyllum inophyllum oil (CIO) as a bio-lubricant. The oils undergo a two-step modification process, involving a transesterification reaction followed by epoxidation. Significant improvements have been observed in the chemical properties (acid, peroxide, and iodine values) of transesterified epoxidized rice bran oil Calophyllum inophyllum oil mixture–50:50 (ETRCIO) when compared with Unmodified Rice bran oil Calophyllum inophyllum oil mixture–50:50 (RCIO). The acid value, peroxide value, and iodine value improved by 91.66%, 87.08%, and 15.78% respectively. The rheological, tribological, and chemical properties of the blended samples have been evaluated and compared to pure oils using American Society for Testing and Materials (ASTM) and Indian Standards (IS). Additionally, ETRCIO was used to develop a bio-grease, and its tribological properties were extensively analyzed. The mean coefficient of friction (COF) and wear scar diameter (WSD) of the ETRCIO grease sample improved by 10.20% and 29.32% respectively when compared with that of commercially available grease. These findings indicate that the ETRCIO bio-grease exhibits superior tribological properties in comparison to commercially available grease. Research highlights: • The study explores the potential of vegetable oils as a biodegradable and environmentally friendly alternative for producing lubricants, specifically focusing on rice bran oil and Calophyllum inophyllum oil. • The oils undergo a two-step chemical modification process (transesterification followed by epoxidation) to improve their thermal and oxidative stability, making them suitable for industrial use. • The chemically modified and blended oils showed significantly improved chemical properties. • The rheological, tribological, and chemical properties of the blended samples were evaluated according to ASTM, and IS standards and compared with those of pure oils. • A bio-grease was formulated using these chemically modified oils, exhibiting better tribological properties than commercially available grease, indicating its potential as an eco-friendly and health-conscious alternative to traditional mineral oil-based greases. [ABSTRACT FROM AUTHOR]

Attention to greenhouse gases is carried out by reducing CO2 emissions. Emission reduction is achieved using mixed fuels, primarily derived from plant oils. The pertasol-diethyl ether and tamanu oil (PDETO) fuel mixture were tested using a spark ignition engine. The research objective is to obtain fuel specifications and test engine performance using the resulting fuel. Mixed fuels were created from various compositions with codes ranging from BE0 to BE10. Performance testing was conducted using a 110-cc gasoline engine with specific specifications using mixed fuels and compared to commercial gasoline. The research results indicate that engine torque, power, and MeP are higher when using mixed fuels BE0 - BE10 than retail gasoline. The maximum torque that can be achieved is 8.51 NM at 5000 rpm using BE10 mixed fuel, higher than the maximum torque of commercial gasoline, which is 6.81 NM. The highest full power is generated by BE10 fuel, at 7.75 HP at an engine speed of 7000 rpm. The minimum capacity is produced by BE0 fuel, with a power of 6.78 HP at an engine speed of 7000 rpm. Optimal SFC occurs in the BE0 fuel mixture at 7000 rpm engine speed at 0.25 kg/Hp·h. BE10 thermal efficiency reached 31.8%, which is better than commercial gasoline. [ABSTRACT FROM AUTHOR]

The development of thermo-responsive shape-memory polymers has attracted attention due to their ability to undergo reversible deformations based on temperature changes. Vegetable oils are confirmed to be an excellent biorenewable source of starting materials for the synthesis of polymers. Therefore, the objective of this research was to synthesize thermo-responsive shape-memory polymers based on vegetable oils by using the dual-curing technique and obtaining polymers with tailorable properties. Acrylated epoxidized soybean oil and two epoxidized vegetable oils, linseed oil and camelina oil, were chosen for dual curing with m-xylylenediamine. Rheological tests were used to analyze the curing kinetics of systems undergoing radical photopolymerization, thermal cationic polymerization, and dual-curing processes. The rheological, mechanical, and thermal characteristics of the polymers were enhanced by the second curing stage. Dual-cured vegetable oil-based polymers had shape-memory properties with a recovery ratio of 100%, making them suitable for a variety of applications, including electronics, biomedical devices, and robotics. [ABSTRACT FROM AUTHOR]

Phosphonation and nitrogenation of methyl epoxyoleate (MEO) were done to prepare phosphonitrogenated methyl epoxyoleate (PNMEO). The structural characteristics of PNMEO were characterized. The tribological properties of PNMEO and MEO as additives in a paraffin oil and a rapeseed oil were evaluated, and the morphologies, element compositions and tribochemical species of worn surfaces were analyzed. Results showed that PNMEO was more efficient in enhancing tribological properties of oils than MEO. Results also showed that PNMEO and MEO were more powerful in paraffin oil than in rapeseed oil in improving load-carrying, friction-reducing and anti-wear performances, but in rapeseed oil than in paraffin oil in improving extreme pressure property. The tribological mechanisms of PNMEO in reducing friction and wear were attributed to PNMEO-involved tribo-adsorptions and tribo-reactions to produce a composite boundary lubrication film which consisted of a matrix of PNMEO with inclusions of iron oxide, polyphosphates, aminic compounds, and the base oil molecules. [ABSTRACT FROM AUTHOR]

MoS2 lithium-based grease is suitable for lubrication protection between bearings at high temperatures and loads due to its excellent tribological properties. However, there is little research on the influence of different addition methods of MoS2 additive on its tribology and corrosion properties. In this work, eco-friendly vegetable oil was selected as the base oil, with MoS2 powder as the additive to synthesize lithium-based grease. The effects of different adding modes of MoS2 on the tribology and corrosion properties of the grease were studied. The experimental results showed that adding 0.01 wt% MoS2 before thickening (Method D) was more conducive to improving the tribological properties of lithium grease. The average friction coefficient was reduced by 26.1%, and the average wear scar diameter was reduced by 0.16 mm. After grinding and adding (Method B) 0.01 wt% MoS2, the corrosion inhibition efficiency of the steel sheet was as high as 96.97%. The reason was that the tribochemical reaction of MoS2 evenly distributed throughout the grease during friction, forming a thin friction film, reducing friction and wear. The protective film formed by MoS2 and GCr15-bearing steel improved the corrosion inhibition performance of the grease. [ABSTRACT FROM AUTHOR]

Molybdenum disulfide (MoS2) and Tungsten disulfide (WS2) nanoparticles addition to castor oil produce nano lubricants of novel properties. These nanomaterial additives are dispersed thoroughly in the liquid phase and are intended to boost the base fluid's thermo-physical, rheological, and tribological properties. All these properties have been studied by varying concentrations of nanoparticles from 0.05 to 2.5%. The size of both nanoparticles are in the range of <20nm. The density of nano lubricants was found to change with respect to nanoparticle concentration and temperature. The density increases from 0.06 to 0.6% with respect to the increase in concentration and decreases by 4%, for increasing temperature from 25 to 100 o C. A significant (15 %) increase in thermal conductivity with MoS2 nanoparticles in lubricants could be observed while with WS2 nanoparticles only 8 % enhancement was observed. The rheological study suggests that nano lubricants have better dynamic viscosity and shear stress than neat castor oil. A tribology study showed improved lubrication properties of the nanolubricants as compared with base castor oil. The addition of MoS2 and WS2 nanoparticles in castor oil decreased the friction coefficient by 53 % and 42 %, respectively, and reduced the wear scar diameter by 24% and 20 %, respectively, as compared to base castor oil. This study was done to develop nonedible vegetable oil based nanolubricants exploring their potential as emerging lubricants. [ABSTRACT FROM AUTHOR]

The use of biolubricants as an alternative to petroleum-based products has played an important role in the last decade. Due to the encouragement of global policies, which mainly support green chemistry and circular economy, there has been an increasing interest in bio-based products, including biolubricants, from scientific and industrial points of view. Their raw materials, production, and characteristics might vary, as biolubricants present different applications for a wide range of practical uses, making this field a continuously changing subject of study by researchers. The aim of this work was to study biolubricant production from vegetable oil crops from a bio-refinery perspective, paying attention to the main raw materials used, the corresponding production methods (with a special focus on double transesterification), the role of catalysts and some techno-economic studies. Thus, the main factors affecting quality parameters such as viscosity or oxidative stability have been covered, including catalyst addition, reaction temperature, or the use of raw materials, reagents, or additives were also analyzed. In conclusion, the search for suitable raw materials, the use of heterogeneous catalysts to improve the effectiveness and efficiency of the process, and the optimization of chemical conditions seem to be the most interesting research lines according to the literature. [ABSTRACT FROM AUTHOR]

Purpose: This study aims to investigate the behavior of vegetable oil with two additives. Base oil's tribological qualities can be improved with the help of several additions. In the present investigation, soybean oil is served as the foundational oil due to its eco-friendliness and status as a vegetable oil with two additives, named polytetrafluoroethylene (PTFE) and molybdenum disulfide (MoS2). Design/methodology/approach: As additives, PTFE and MoS2 are used; PTFE is renowned for its anti-friction (AF) properties, while MoS2 is a solid lubricant with anti-wear (AW) properties. This investigation examines the synergistic impact of AF and AW additions in vegetable oil. The lubricity of the base oil is measured by using a four-ball tester, and the wear properties of the oil at different additive amounts are determined by using a universal tribometer. Findings: PTFE (at 5 Wt.%) and MoS2 (at 1 Wt.%) were found to improve the tribological performance of the base oil. The weld load is significantly increased when 5 Wt.% of PTFE + MoS2 is added to the base oil. Originality/value: A better tribological characteristic can be achieved by combining additives that amount to less than 1% of the base oil. In experiments with highly concentrated MoS2, the adequate pressure improved dramatically, but the lubricant's tribological characteristics did not. Peer review: The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-11-2022-0321/ [ABSTRACT FROM AUTHOR]

Enzymatic interesterification (EIE) of beef tallow (BT) blended with soybean oil (SO), peanut oil (PO) and canola oil (CO) in different proportions were analyzed in terms of the fatty acid compositions, thermal properties (melting and crystallization behaviors), rheological properties, hardness, crystal, and microstructure to achieve their sufficient utilization. The content of saturated fatty acids in all interesterified oils (IOs) decreased gradually with the increase of plant oil content in base stock. The higher the proportion of plant oil in the base stock, the lower the enthalpy of IOs. All IOs were in the solid-like state, and the hardness of all IOs met the requirements of traditional plastic oil. All IOs were mainly in α and β′ crystal forms and can be used as basic stock for special oils. [ABSTRACT FROM AUTHOR]

Vegetable oils or fats are one of the most important renewable resources and mainly consist of triglyceride esters with different fatty acid chains. These components contain a number of highly functional sites in the form of unsaturated -C = C- bonds, triglyceride ester groups, and allylic reactive positions. Therefore, they present a possibility for multiple ranges of chemical transformations and also produce new and novel bio-based monomers for the synthesis of polymers with considerable bio-degradability. Vegetable oils and the chemicals derived thereof come from non-exhaustible and renewable resource. They are eco-friendly and emerging as sustainable alternates to the chemicals or monomers derived from limitedly available petroleum source, which are also known for their toxicity and environmental pollution. The present review discusses and analyses the possible application areas and summarise the diverse chemical modifications namely, hydrogenation, trans-esterification, epoxidation, along with various polymerization processes that have been reported in the literature. The case of very less explored non-edible oil derived from Cassia fistula (Indian laburnum), as a futuristic precursor especially in the polymer synthesis has been highlighted. We believe that the commercial potential and opportunities for such sustainable materials in general and bio-degradable polymers or plastics in particular will emerge on the global market in the near future. [ABSTRACT FROM AUTHOR]

Vegetable oils have been used as metalworking fluids (MWFs) for many years, particularly in small-scale metalworking operations and in industries where environmental regulations are strict. Before the development of modern MWFs, vegetable oils were one of the most common lubricants used for metalworking tools. The use of vegetable oils can be traced back to ancient civilizations such as Egypt, Greece, and Rome, where olive oil was commonly used to lubricate metal tools and weapons. Today, vegetable oils are used as MWFs in a variety of applications. They are often combined with additives or nanoparticles to enhance their performance, such as improving the lubricity, cooling properties, and stability of the oil, as well as reducing friction and wear on the cutting tool. Additives, such as antioxidants, anti-wear agents, and extreme pressure (EP) additives, can be used to improve the performance of vegetable oils as cutting fluids. Compared to standard MWFs, vegetable oils are generally more biodegradable and environmentally friendly, and can be more cost-effective. However, MWFs may offer superior performance in certain areas, such as lubrication and cooling. Ultimately, the choice of MWFs will depend on the specific requirements of the metalworking operation and the balance between performance, cost, and environmental considerations. As the demand for sustainability and environmental responsibility continues, the use of vegetable oils as MWFs is likely to become even more popular in the future. Overall, vegetable oils offer a viable and potentially attractive alternative to standard MWFs in certain applications. This review highlights both conventional and most recent advances in vegetal oils frequently used as lubricant fluids in manufacturing processes. [ABSTRACT FROM AUTHOR]

Background: Emulsions have been widely used as immunological adjuvants. But the use of materials derived from plants such as cottonseed oil, alpha-tocopherol, or minerals such as zinc, as well as their use at the nanometric scale has been little explored. In this study, we develop a new miniemulsion and evaluated its antioxidant and phagocytic capacity, as well as parameters related to immune response stimulation by cytokine expression and antibodies production in a mice model. Methods: Formulated CN (cottonseed oil miniemulsion) and CNZ (cottonseed oil miniemulsion whit zinc oxide nanoparticles) miniemulsions were characterized by scanning electronic microscopy SEM, DLS and FT-IR. In murine macrophages, splenocytes and thymocytes primary cultures safety and cytotoxicity were determined by MTT. In macrophages the antioxidant and phagocytic capacity was evaluated. In BALB/c mice, the stimulation of the immune system was determined by the expression of cytokines and the production of antibodies. Results: The CN and CNZ presented stability for 90 days. Immediately after preparation, the CN presented a higher particle size (543.1 nm) than CNZ (320 nm). FT-IR demonstrated the correct nanoparticle synthesis by the absence of sulfate groups. CN and CNZ (1.25 to 10 µL/mL) had no toxic effect on macrophages (p = 0.108), splenocytes (p = 0.413), and thymocytes (p = 0.923). All CN and CNZ doses tested induced nitric oxide and antioxidants production in dose dependent manner when compared with control. CN-ovalbumin and CNZ-ovalbumin treatments in femoral subcutaneous tissue area showed inflammation with higher leukocyte infiltration compared with FCA. The intraperitoneal administration with CN, CNZ, and FCA showed a higher total intraperitoneal cells recruitment (CD14+ ) after 24 h of inoculation than control (p = 0.0001). CN and CNZ increased the phagocyte capacity with respect to untreated macrophages in the Candida albicansphagocytosis assay. The evaluation of residual CFU indicated that only CNsignificantly decreased (p = 0.004) this value at 3 h. By other side, only CN increased (p = 0.002) the nitric oxide production. CNZ stimulated a major INFγ secretion compared with FCA at day 7. A major IL-2 secretion was observed at days 7 and 14, stimulated with CN and CNZ. Both miniemulsions did not affect the antibody isotypes production (IgG1, IgG2a, IgG3, IgA and IgM) at days 7, 14, 28, and 42. CN induced a significant IgG production against OVA, but lesser than FCA. Conclusions: The two new miniemulsions with adjuvant and antioxidant capacity, were capable of generating leukocyte infiltration and increased cytokines and antibodies production. [ABSTRACT FROM AUTHOR]

The paper’s research focuses on the development of novel hydrophobizing agents and the demonstration of their efficiency on a concrete surface. The starting materials are based on natural oils, water‒soluble silanes and siloxanes, and/or tap water. Aqueous preparations have qualities that limit the influence of volatile organic compounds (VOCs) on the environment since they solely include biodegradable components. According to research, the higher fatty acids obtained from vegetable oils and derived from the glycerin phase can be employed as a component of concrete hydrophobizing agents while matching the standard requirements for such agents. Analysis of the usage of vegetable oil as a basis ingredient in the manufacturing of industrial substances shows that it is biodegradable with at least 95% certainty. The reference concrete after the frost resistance test showed a weight loss of 1.8%. In the case of hydrophobization, the weight loss was 33.3 to 72% less than the reference samples. In the case of concrete hydrophobized with the glycerin agents, the salt crystallization occurred inside the structure of the material without causing any damage, with the reference concrete showing a weight loss of 0.8%. [ABSTRACT FROM AUTHOR]

Lubricants are essential to machinery life, as they play a crucial role in controlling and diminishing the friction and wear between moving parts when operated under extreme conditions. To this end, due to tight environmental conditions, manufacturers are looking for alternative solid lubricants to be dispersed in base liquid lubricants. MoS2 and graphene are solid lubricants that provide low frictional properties and high thermal stability in both oxidizing and non-oxidizing environments. This research offers a new lubricant with improved thermal conductivity that combines the synergistic effect of graphene and MoS2 in a blend of vegetable oil (peanut) and naphthenic oil. The ratio of peanut oil and naphthenic oil varies from 1:3–3:1. A fixed composition of 4.34 wt.% palm oil methyl ester (POME) is added to enhance the anti-wear property further. Graphene and MoS2 concentrations varied between 1:2–5:2, respectively. This nanoparticle additive oil blend is physically mixed using a water bath sonication for 4 h. The stability of the blend lubricant dispersed with MoS2 and graphene is studied using a UV-Vis spectrophotometer for 25 days. The effect of various concentrations of graphene, MoS2, peanut oil, and naphthenic oil on the thermal conductivity of the nanolubricant is also studied as a function of temperature (25 °C–55 °C). Artificial neural network models were used for the parametric investigation of the nanolubricant. It is found that the stability of the formulated nanolubricant increased with peanut oil composition above 25 wt.%. The results show that the 3:1 blend ratio showed higher stability for hybrid MoS2-based lubricants. Similarly, the highest thermal conductivity is observed for 100 wt.% naphthenic oil with a 1:2 ratio of graphene–MoS2 at 55 °C. [ABSTRACT FROM AUTHOR]

Argan oil (AO), extracted from the argan tree's fruits, is principally composed of mono-unsaturated fatty acids, polyphenols, tocopherols, and sterols. This unique chemical composition is likely to be responsible for its beneficial effects. The argan tree (Argania spinosa) grows endemically in the southwest of Morocco. This study aimed to evaluate the chemical composition of three types of argan oil from three geographical locations: argan oil extracted from argan nuts collected from a plantation (Casablanca, AOC) and two forest stands of argan trees growing naturally in their native environment of the south-west of Morocco ((regions of Essaouira (AOE) and Taroudant (AOT)). The composition of the three oils corresponds to the known composition of argan oil in terms of fatty acids and unsaponifiable fraction. The chemical analyses revealed that the argan oil extracted from the plantations (AOC) is significantly richer in linoleic acid, linolenic acid, and tocopherols compared to the oil from the two natural stands (AOE and AOT) of argan trees. These results suggest that it is possible to facilitate an assisted migration of the argan tree outside its natural area into sites exposed to sea spray without affecting the quality of its argan oil. [ABSTRACT FROM AUTHOR]

Background: The present study was conducted to evaluate the efficacy of some eco-friendly management modules based on plant oils and Metarhizium anisopliae against a biennial white grub species, Lepidiota mansueta Burmeister (Coleoptera: Scarabaeidae) infesting potato crop in the farmer's field at Majuli river island, Assam, India. Results: Amongst all the modules evaluated against L. mansueta grubs, the pooled analysis of two years of data (2019–2020 and 2020–2021) revealed that Module-VI [presowing treatment of mustard oil cake @ 150 kg/ha + wood ash @ 150 kg/ha + panchagavya @ 3% plus the application of Metarhizium anisopliae @ 10 g/sq.m after 1st & 2nd earthing up (25 & 60 Days after Sowing (DAS))] and Module-III [presowing treatment plus soil drenching with jatropha oil @ 5 ml/lit after 1st & 2nd earthing up (25 & 60 DAS)] were significantly superior and statistically at par over the rest of the modules in recording high yield (122.71 and 121.50 q/ha, respectively), minimum per cent tuber damage on weight basis (11.32 and 11.82%, respectively) and number basis (14.07 and 14.78%, respectively). The maximum benefit cost ratio was recorded in Module-VI, followed by Module-III and Module- II. Conclusion: All the management modules were effective, however, Module-VI and Module-III were found to be significantly superior and registered the least tuber damage on weight and number basis and the highest tuber yield compared to other modules. [ABSTRACT FROM AUTHOR]

Currently, the lubricating greases on the market are products based on mineral oil, which are finally discarded, generating great pollution in the environment; on the other hand, the vegetable oil used in cooking is almost always disposed of through a sink, a landfill or a sewer, without prior treatment, causing environmental problems as a consequence. The objective of this research was to obtain a lubricating bio-fat by reusing vegetable oil used in kitchens in frying processes. To carry out this research, sodium hydroxide was used to obtain the soap and recycled oil to carry out the saponification process and as a base oil to obtain the fat. In this investigation, eight different formulations were made, with variations in the amounts of NaOH and antifoam, finally a formulation was obtained, whose soap was formed by 40 ml of used oil plus 40 ml of sodium hydroxide and its base was 80%. of the same used oil, presented physicalchemical characteristics similar to commercial fats on the market. In conclusion, the obtained lubricating grease is a grade 2 grease, according to the National Institute of Lubricating Greases, it is a soft grease suitable for use in bearings, bearings and valves, which can be subjected to temperatures not exceeding 160 °C, where the presence of water is minimal, it can also be used in structures exposed to the air. [ABSTRACT FROM AUTHOR]

Microbial transformation of hydrophobic phytosterols into the pharmaceutical steroid precursors AD (androst-4-ene-3, 17-dione) and ADD (androst-4-diene-3, 17-dione) in a water–plant oil two-phase system by Mycolicibacterium neoaurum is a paradigm of interfacial biocatalysis in Pickering emulsions stabilized by bacterial cells. In the present work, phase inversion of Pickering emulsions—i.e., Pickering emulsions turning from water-in-oil (W/O) emulsions into oil-in-water (O/W) ones—was observed during microbial transformation in the presence of high concentrations of crystal phytosterols. It was found that there is a correlation relationship between the phase behaviors of Pickering emulsions and the biocatalytic activity of utilizing M. neoaurum as a whole-cell catalyst. Efficient microbial transformation under the high crystal phytosterol loadings was achieved due to the formation of O/W emulsions where interfacial biocatalysis took place. Under the optimal conditions (volume ratio of soybean oil to water: 15:35 mL, phytosterols concentration in the soybean oil: 80 g/L, glucose as co-substrate in the aqueous culture medium: 10 g/L), the concentrations of AD and ADD reached 4.8 g/L based on the whole broth (16 g/L based on the oil phase) after microbial transformation for 9 days. [ABSTRACT FROM AUTHOR]

For obtaining a spatial map of the distribution of nitrogen nutrients from oil palm plantations, a quite complex Leaf Sampling Unit (LSU) is required. In addition, sample analysis in the laboratory is time consuming and quite expensive, especially for large plantation areas. Monitoring the nutrition of oil palm plants can be achieved using remote-sensing technology. The main obstacles of using passive sensors in multispectral imagery are cloud cover and shadow noise. This research used C-SAR Sentinel equipped with active sensors that can overcome cloud barriers. A model to estimate leaf nitrogen nutrient status was constructed using random forest regression (RFR) based on multiple polarization (VV-VH) and local incidence angle (LIA) data on Sentinel-1A imagery. A sample of 1116 LSU data from different islands (i.e., Sumatra, Java, and Kalimantan) was used to develop the proposed estimation model. The performance evaluation of the model obtained the averaged MAPE, correctness, and MSE of 9.68%, 90.32% and 11.03%, respectively. Spatial maps of the distribution of nitrogen values in certain oil palm areas can be produced and visualized on the web so that they can be accessed easily and quickly for various purposes of oil palm management such as fertilization planning, recommendations, and monitoring. [ABSTRACT FROM AUTHOR]

Palm oil is a major global commodity that is vital for the well-being of many communities. Despite its significant contribution to the attainment of the 2030 Sustainable Development Goals, such as zero hunger, decent work and economic growth, palm oil has been criticised for its negative impact on the environment due to deforestation and its cultivation processes. The palm oil sustainability contribution is imbalanced and not coherent with the three pillars of sustainability, namely profit, economics, and the environment, which casts doubt on the palm oil status quo. Increasing Environmental Kuznets curve (EKC)-based studies on the linear impact of agriculture on carbon dioxide (CO2) offer some insights; however, the nonlinear relationships (the asymmetric effects of positive and negative shocks) between the palm oil industry and CO2 are rarely examined, and the postulating literature is incomplete. Thus, this study aims to analyse the symmetric and asymmetric impacts of palm oil production on CO2 emissions based on time series data for Malaysia from 1978 to 2018. The novelty of this research lies in the asymmetric nonlinear autoregressive distributed lag model, which reveals that rising palm oil production reduces CO2 in the long run, while reducing palm oil production increases emissions. The research also found significant effects of renewable energy consumption, oil demand, and trade openness on CO2 emissions. Considering the future perspective, this study discusses and offers evidence that supports the EKC hypothesis through linear and nonlinear analyses, which verifies the relevance of studies on the symmetric and asymmetric EKC. Furthermore, this study provides an in-depth discussion of the implications for policymaking, with the expansion of palm oil production representing a solution to environmental degradation. [ABSTRACT FROM AUTHOR]

[Display omitted] Oxide-stabilized emulsions generally require a surface functionalization step to tune the oxide wettability, often involving hazardous hydrophobizing agents. Here, we propose the in situ functionalization of ZnO in vegetable oils without the addition of any modifier, resulting in the one-step formation of highly stable Pickering emulsions. The role of ZnO surface features was studied by modifying the particles' wettability through surface functionalization and by comparing different oil phases. The emulsion stability was assessed through aging tests, multiple hot-and-cold cycles, centrifugation, and addition of multiple electrolytes. While the wetting features of the functionalized oxide play a crucial role when the oil phase is methyl octanoate, emulsions based on vegetable oils form also using hydrophilic ZnO. During the emulsification, an in situ functionalization of bare ZnO particles takes place due to the fatty acids present in vegetable oil. These in situ -generated systems lead to stable emulsions showing < 2 μm-diameter oil droplets. The resulting emulsions display excellent stability over time (over seven months) and against temperature variations, mechanical stress and increased ionic strength. Finally, we demonstrate that this approach can be extended to a variety of vegetable oils and oxides with different morphologies. [ABSTRACT FROM AUTHOR]

Field trials were conducted at Anbil Dharmalingam Agricultural College and Research Institute, Tiruchirappalli district, Tamil Nadu, to evaluate the bioefficacy of insecticides and plant-based oils against red spider mite, Tetranychus urticae (Koch) in okra during rabi 2021 and summer 2022. The results revealed that the highest per cent reduction over control of the red spider mite population was recorded in spiromesifen 25 EC @ 0.8 ml/l (73.28% and 67.78%), followed by propargite 57 EC @ 3ml/l (70.82% and 65.51%) in both the seasons, respectively. Among the plant-based oils, karanj oil was most effective against red spider mites, with a per cent reduction over control of 58.7% and 47.98% in rabi, 2021 and summer 2022, respectively. Mahua oil (54.02% and 41.72%) and camphor oil (51.62% and 38.74%) moderately control the red spider mite in okra. Based on moderate to high efficacy and safer natural enemies and environment, spiromesifen 25 EC @ 0.8 ml/l, propargite 57 EC @ 3ml/l and karanj oil 2ml/l would be used as an effective component in the IPM module for okra red spider mite. [ABSTRACT FROM AUTHOR]

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A potential, sustainable, and economical eco-friendly alternative to harmful petroleum-based lubricants is a big challenge for the 21st-century lubricant industry. The present study explores, for the very first time, polysaccharide gums like gum acacia (GA) and guar gum (GG) as additives (0.5–10 %w/w) to enhance the extreme-pressure (EP) performance of greases (based on vegetable oil and organoclay). The greases are evaluated on a four-ball tester for the standard EP test (ASTM D2596). Adding GA or GG to greases enhances EP performance significantly. The performance ameliorates with the gum's concentration showing impressive results at higher concentrations (up to ≈ 60% better than a commercial grease). The superior performance is attributed to an in-situ formed polymer-layered silicate nanocomposite tribofilm at the interface via chemisorption (for GA) or physisorption (for GG). The formulated greases are a possible replacement for existing mineral oil-based commercial greases. [Display omitted] [ABSTRACT FROM AUTHOR]

Mites cause significant damage to various crops, often requiring synthetic acaricides for their control. However, the frequent use of these products, resistance problems and severe problems with contamination occur. Therefore, one of the promising solutions is plant acaricides, which can be developed based on essential oils. Thus, the objective of this work was the extraction and characterization of the essential oil from the leaves of Kermani lemongrass, Dracocephalum polychaetum, and acaricidal evaluation of the oil and its major compound using the application by fumigation on female adults of Tetranychus urticae. The composition of the essential oil was analysed by GC-MS. The major components in the oil were 1-octen-3-ol (11.27%), 6-methyl-5-hepten-2-one (11.06%), linalool (9.89), and nonanal (9.64%), respectively. The impact of essential oil of this plant on fumigant toxicity, LT50, oviposition deterrent activity, and repellency against T. urticae was studied at different concentrations. The results stated that D. polychaetum oil had high toxicity on eggs and adults of two-spotted spider mite (LC50 was 60.30 and 50.87 µL L−1 for eggs and adults, respectively) with LT50 of 8.02 h. In addition, all tested concentrations had oviposition deterrent activity and repellency in adults of this mite. [ABSTRACT FROM AUTHOR]

Copyright of Packaging & Food Machinery is the property of Packaging & Food Machinery Magazine and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Drugs are chemical substances that come from either natural occurrence or synthetic sources. These compounds are designed to have some pharmacological effects, give some benefits to society, and remain through time. Their bioaccumulation or their interactions with other chemicals has been considered as a health risk because they can cause adverse effects on ecosystems and human health. The Emulsion Liquid Membranes (ELM) technique is proposed as a useful and simple methodology in the drug elimination from sewage water. In recent years, some green methods integrated by vegetable oils have been reported; nevertheless, toxic carriers continue to be used. Soybean oil has been reported in stability studies and formulation improvement of cosmetic, food and pharmaceutical emulsions, but not in emulsions for drugs recovery. Thus, a methodology totally environmentally friendly was developed in this work, without carriers and using only soybean oil. The ELM was integrated by soybean oil + Abil EM 90® 0.25 wt% as organic phase; NaHCO 3 0.1 mol⋅L−1 as internal aqueous phase and all these emulsified at 19000 rpm for 10 minutes and a V IAP /V OP ratio equal to 1:1 respectively. It was able to extract 81% of naproxen and subsequent 67% recovery in 5 minutes of stirring. It can be inferred that soybean oil is an effective and green option because it can act as a carrier and as a diluent in ELMs for drugs recovery. [Display omitted] • A green emulsion liquid membrane based on soybean oil was developed. • A methodology for environmentally friendly NPX recovery has been developed. • The system composed by soybean oil, Abil EM90® and NaHCO 3 proved to be efficient. • The presence of the carrier was not necessary in this system. • Soybean oil acted as both diluent and carrier at the same time. [ABSTRACT FROM AUTHOR]

Rapid, cost-efficient, and eco-friendly methods are desired today for routine analysis of the Fusarium mycotoxin zearalenone (ZEN) in edible vegetable oils. Liquid chromatography with fluorescence detection (HPLC-FLD) is commonly used to reliably control the specified ZEN maximum levels, which requires efficient sample clean-up to avoid matrix interferences. Therefore, a highly selective extraction and clean-up method based on reversible covalent hydrazine chemistry (RCHC) using hydrazine-functionalized silica was developed. This efficient solid-phase extraction (SPE) involves reversible hydrazone formation of ZEN with the hydrazine moiety covalently bound to a solid phase. Optimal conditions were achieved with 1 mL SPE cartridges filled with 400 mg of hydrazine-functionalized silica. The developed RCHC-SPE method was validated in an interlaboratory comparison study (ILC) with twelve participants analyzing six edible vegetable oils with a focus on maize oils. The derived method parameters (ZEN recovery 83%, repeatability 7.0%, and reproducibility 18%) meet the performance criteria of Commission Regulation (EC) No 401/2006. The developed RCHC-SPE-based HPLC-FLD method allows the reliable quantification of ZEN in the range of 47–494 µg/kg for different types of edible vegetable oils, also for matrix-reach native oils. Due to the high efficiency, the significantly reduced matrix load helps to extend the lifetime of analytical equipment. Furthermore, the re-useability of the RCHC-SPE cartridges contributes to an eco-friendly approach and reduced analysis costs. To our knowledge, this is the first report on ZEN quantification in edible vegetable oils based on manual RCHC-SPE cartridges. Due to its high performance, the developed RCHC-SPE method is a promising alternative to the current European standard method EN 16924:2017 (HPLC-FLD part). [ABSTRACT FROM AUTHOR]

Vegetable oils, whose hydrocarbon structure is very similar to that of petroleum products, are ideal renewable and sustainable alternatives to petroleum lubricants. Bio-lubricants are commonly synthesized by modifying the chemical structure of vegetable oils. In this study, microwave irradiation was applied to intensify the mass-transfer-limited transesterification reaction to produce trimethylolpropane triester (bio-lubricant) from camelina oil as a promising local energy crop. A rotatable RSM-BBD method was applied to find the optimal levels of experimental factors, namely reaction time (67.8 min), the catalyst concentration (1.4 wt%) and the molar ratio (3.5). In these optimal levels, the reaction yield of 94.3% was obtained with desirability of 0.975. The quadratic statistical model with a determination coefficient of 97.97%, a standard deviation of 0.91 and a variation coefficient of 1% was suggested as the most appropriate model by Design-Expert software. Finally, the physicochemical properties of the purified product were in accordance with the requirements of the ISO-VG22 base oil standard. [ABSTRACT FROM AUTHOR]

It is imperative to emphasize the wear-reducing and load-sustaining abilities of the lubricating oils, as they are an essential part of their operation. In this study, the anti-wear and extreme pressure (EP) performance of Jatropha oil was explored. The investigation was executed on a 4-ball tester machine according to ASTM-D-4172 and D-2783 standards. Nano-sized Molybdenum disulfide and graphene were added to the base oil, whose addition reduced the wear on the test balls but failed to improve the EP properties. However, the addition of Garlic oil elevated the EP properties of the base oil. The Last Non-seizure load and weld point of the jatropha oil was elevated by up to 3 levels, while the Load Wear index was increased by 91.88%. The Flash Temperature Parameter of jatropha oil was increased by 658% and 250% at 100kgf and 126kgf load, respectively, after the addition of 5% garlic oil. Further, the wear scars were examined under an optical microscope and FESEM, which proved that the addition of nano-additives reduced the wear of the balls during anti-wear tests at lower loads, and garlic oil reduced the wear in EP conditions and produced smoother surfaces. These improvements were attributed to the formation of tribo-films on the surfaces as characterized by the EDS analysis. It was concluded that Garlic oil could be a substantial EP additive to vegetable oils (especially jatropha oil) to lift their load-carrying capacity without hampering their environmentally friendly nature. [ABSTRACT FROM AUTHOR]

As the slow-release fertilizer, oil-coated fertilizer can not only slow down the nutrients loss, but also have outstanding advantages in controlling the nutrients release. Based on a large number of literature, this paper systematically investigated the composition, classification, properties and preparation of oil-coated fertilizers, summarizes the challenges faced by the oil-coated fertilizers and offers a few suggestions for the future research. Through literature research, some important conclusions were found: (1) Oil-coated fertilizers are generally composed of core fertilizers and coated oil layers, and some have active interlayers. (2) Vegetable oils has the characteristics of easy degradation, water resistance and impact resistance, and the nutrient release curves of vegetable oil coated fertilizer in soil and still water are "S" type. (3) The modified polyurethane exhibits good compatibility with urea, and can control the release of N in a long period of time, which is 30 days longer than the N release life of ordinary polyurethane-coated fertilizers. (4) Oil-coated fertilizers can reduce the loss of N by slowing down the hydrolysis rate of urea and the nitrification from NH 4 + to NO 3 −, which reduces the N 2 O release by 70–80% compared to the uncoated fertilizers. Moreover, the paper also proposes a new preparation method of oil-coated material. [Display omitted] • The nutrient release of oil-coated fertilizer presents the "diffusion" mechanism. • Production costs and environmental risks are challenges for oil-coated fertilizers. • Temperature is the most important external factor affecting the nutrients release. • Bio-based polyurethane materials can replace petroleum-based polymers. [ABSTRACT FROM AUTHOR]

This paper uses extreme value theory and exponential generalised autoregressive score models to estimate the tail extremes of financial return series. The peak-over-threshold method based on the generalised pareto distribution is combined with the EGAS models and the nonparametric quantile method is used to determine the thresholds in the POT method, which is used to calculate the value-at-risk of financial markets and to perform backtesting. The empirical analysis was conducted on the soybean oil, rapeseed oil, and palm oil futures indices in the Chinese futures market. The study demonstrated that the EGAS-POT models based on nonparametric quantile thresholds can effectively characterise tail risk and provide a feasible measure of risk for investors. [ABSTRACT FROM AUTHOR]

The greener additives synthesized from bio-sources with low-cost and multifunctional applications have attracted considerable attention in the field of lubricant industry. In this study, the synthesis of novel multifunctional green additives of stearyl methacrylate-co-triglyceride polymeric architectures MGA-1 and MGA-2 has been reported by incorporating the stearyl methacrylate on the sunflower oil and soybean oil, respectively. Direct polymerization through the double bonds of the fatty acid chain in the presence of a free radical initiator leads to the formation of ecofriendly copolymeric additive. The synthesized copolymers have been characterized by routine spectroscopic analysis, and the molecular weight and thermal decomposition of copolymers were determined by gel permeation chromatography and thermogravimetric analysis, respectively. The rheological behavior and performance evaluation of the formulated base oil were examined in different concentrations of additive viz. 1%, 1.5%, and 2% (w/v). Both MGA-1 and MGA-2 additives act as pour point depressant, viscosity modifier, viscosity index (VI) improver, and rheology modifier to the base oil. However, MGA-1 additive acts as an excellent viscosity modifier and VI improvers, whereas MGA-2 copolymer acts as better pour point depressant (PPD). The rheological study established the shear-thickening behavior for both the additive. The significance of this study lies in the fact that the increment in viscosity occurs with shear rate which make the formulated lubricant feasible at extreme conditions. Along with this, these vegetable oils derived additives MGA-1 and MGA-2 can be considered as good alternative to conventional synthetic homo- and copolymeric lubricant additives for environmentally benign lubricant formulations. [ABSTRACT FROM AUTHOR]

Chia oil (CO) has gained popularity given its α‐linolenic acid content (around 60%). Nonetheless, the susceptibility of polyunsaturated fatty acids toward oxidation represents a challenge for incorporating CO in different products, which justifies the need for exploring stabilization methods. To the best of the authors' knowledge, no reports about powders based on chia oil blends are published. Therefore, the objective of this research is to evaluate the stability at room temperature of microencapsulated CO blends [with virgin sesame (VSO) and wheat germ (WGO) oils] and microencapsulated CO with the addition of tert‐butylhydroquinone (TBHQ). Spray‐drying yielded powders with a better encapsulation efficiency, flowability, and stability, compared with freeze‐drying. After a storage test performed during 3 months, the highest hydroperoxide content (>100 meq.O2 kg−1 oil) is observed for the microencapsulated CO/WGO 80/20 blend, despite its α and β‐tocopherol contents and its antioxidant activity (>90% inhibition of DPPH radical). Notwithstanding, bulk and microencapsulated CO‐TBHQ, CO/VSO 80/20, and 20/80 showed hydroperoxide contents <8 meq.O2 kg−1 oil. By the end of the test, the highest induction period is observed for the microencapsulated CO/VSO 20/80 blend (19.85 ± 0.18 h). Finally, the drying method and the core formulation greatly affect the stability of microcapsules. Practical Applications: Addition of antioxidants, oil blending and microencapsulation are technological solutions for the preservation of omega‐3‐rich oils, which are popular among healthy food consumers. This research studies and compares the microencapsulation processes by spray or freeze‐drying in order to preserve chia oil blends (with virgin sesame and wheat germ oils) and chia oil with the addition of antioxidants, thereby taking the advantages of the three technological solutions mentioned above. Stable omega‐3‐rich powders, with a higher oxidative stability than pure chia oil, can be obtained as ingredients for the food industry. This ultimately allows the incorporation of the oil into different food products developed to satisfy specific market tendencies. [ABSTRACT FROM AUTHOR]

Graphene oxide is one of the latest in- trend nanomaterials in the field of nanotechnology which is being studied in various engineering fields. Yet, its effects on the transformer solid insulation remain unexplored. In this research, the transformer pressboard and Kraft paper are impregnated with nonconductive graphene oxide dispersed vegetable ester-based insulating nanofluid and the behavior of impregnated solid insulation is studied under different thermal aging conditions. The results show that after 60 days of aging, the crystallinity of nanofluid impregnated pressboard is 24.9% more than that of the base oil-blend (OB) impregnated pressboard whereas the crystallinity of nanofluid impregnated Kraft paper is 3.8% more than that of the base OB impregnated Kraft paper. In terms of dielectric properties, the ac breakdown voltage (BDV) of nanofluid impregnated pressboard and Kraft paper is 29.5% and 41% more than the OB impregnated pressboard and Kraft paper, respectively. The dielectric stress is more uniform in nanofluid-based insulation system as compared to the base OB-based insulation system leading to a better design clearance. Therefore, graphene oxide dispersed ester oil (EO)-based nanofluid impregnated solid insulation has better mechanical and dielectric properties, thus leading to an increased lifespan of the transformer. [ABSTRACT FROM AUTHOR]

Biolubricants generated from biomass and other wastes can reduce the carbon footprint of manufacturing processes and power generation. In this paper, the properties and uses of biolubricants have been compared thoroughly with conventional mineral-based lubricants. The biolubricants, which are currently based on vegetable oils, are discussed in terms of their physicochemical and thermophysical properties, stability, and biodegradability. This mini-review points out the main features of the existing biolubricants, and puts forward the case of using sustainable biolubricants, which can be generated from agro-residues via thermochemical processes. The properties, applications, and limitations of non-edible oils and waste-derived oils, such as bio-oil from pyrolysis and bio-crude from hydrothermal liquefaction, are discussed in the context of biolubricants. While the existing studies on biolubricants have mostly focused on the use of vegetable oils and some non-edible oils, there is a need to shift to waste-derived oils, which is highlighted in this paper. This perspective compares the key properties of conventional oils with different oils derived from renewable resources and wastes. In the authors' opinion, the use of waste-derived oils is a potential future option to address the problem of the waste management and supply of biolubricant for various applications including machining, milling applications, biological applications, engine oils, and compressor oils. In order to achieve this, significant research needs to be conducted to evaluate salient properties such as viscosity, flash point, biodegradability, thermo-oxidative and storage stability of the oils, technoeconomics, and sustainability, which are highlighted in this review. [ABSTRACT FROM AUTHOR]