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We study superconducting properties of NbN thin film samples with different thicknesses and an ultra-thin NbTiN meander nanowire sample. For the ultra-thin samples, we found that the temperature dependence of upper critical field (Hc2) in parallel to surface orientation shows bending curvature close to critical temperature Tc, suggesting a two-dimensional (2D) nature of the samples. The 2D behavior is further supported by the angular dependence measurements of Hc2 for the thinnest samples. The temperature dependence of parallel upper critical field for the thick films could be described by a model based on the anisotropic Ginzburg–Landau theory. Interestingly, the results measured in the field perpendicular to the film surface orientation show a similar bending curvature but in a much narrow temperature region close to Tc for the ultra-thin samples. We suggest that this feature could be due to suppression of pair-breaking caused by local in-homogeneity. We further propose the temperature dependence of perpendicular Hc2 as a measure of uniformity of superconducting ultra-thin films. For the thick samples, we find that Hc2 shows maxima for both parallel and perpendicular orientations. The Hc2 peak for the perpendicular orientation is believed to be due to the columnar structure formed during the growth of the thick films. The presence of columnar structure is confirmed by transmission electron microscopy (TEM). In addition, we have measured the angular dependence of magneto-resistance, and the results are consistent with the Hc2 data. [ABSTRACT FROM AUTHOR]

Highly uniform dispersed bimetallic Pt3Zn alloy nanocrystals (NCs) with unique geometries are obtained via a facile one‐pot synthesis process by regulating different reductants. To investigate the morphology and composition of the prepared catalysts, the transmission electron microscopy, X‐ray diffraction and X‐ray photoelectron spectroscopy are utilized. Electrochemical measurements reveal that the Pt3Zn NCs significantly exhibited larger electrochemically active surface areas and excellent catalytic activity towards electro‐oxidation of methanol and ethanol in comparison to the commercial Pt/C. The optimized Pt3Zn (AA) NCs exhibit excellent mass activities in both methanol oxidation reaction (1251.4 mA mgPt−1) and ethanol oxidation reaction (975.7 mA mgPt−1) in acidic media, which are respectively 4.28 times and 3.02 times higher than those of commercial Pt/C. Moreover, the Pt3Zn NCs show a higher stability and better resistance to the COads poisoning. The activity enhancements are attributed to electronic effects and a bifunctional mechanism. [ABSTRACT FROM AUTHOR]