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Due to the growing interest in environmental concerns, synthetic and natural esters have become the key focus of the picture in the last two decades as insulating fluids for high-voltage equipment. This is because, unlike mineral oil, ester liquids are biodegradable, nontoxic, and safe for the environment and human health. These fluids are derived from renewable sources and have high fire resistance. However, synthetic and natural ester fluids are still used in a rather limited number of electrical equipment for several reasons (high cost, high viscosity and density, increased tendency toward electrostatic charge, faster propagation of streamers in an inhomogeneous electric field, etc.). Besides, a huge amount of equipment is filled with mineral oils. The massive replacement of oil-filled equipment with natural or synthetic esters may be extremely expensive to utilities and transformer owners. In addition, in the event of partial or complete retrofilling of mineral oil with an ester fluid, the equipment may evidently contain a mixture of two insulating fluids, and therefore, demanding the scope for research on mixed insulating liquids. The intent of this article is to present a comprehensive review of the literature on the blend of mineral oil and other alternative dielectric fluids. The critical research progresses, highlights, and challenges related to mixed liquids along with significant tutorial elements as well as some analyses are discussed. This review should be useful for researchers, utilities, and transformer owners concerned with ester liquids and retrofilling aspects. [ABSTRACT FROM AUTHOR]

Application of low pour point esters in transformers insulation serving in cold climatic regions is still a challenge. To address this concern, the pre-breakdown and breakdown analyses of thermally aged low pour point ester fluids are investigated. The breakdown measurements are performed at different aging conditions under AC stress. Needle-plane electrode geometry (with varying radii of the tip) is employed since this configuration is necessary for any practical diagnostic based on partial discharge (PD). This allows studying the effect of the chemical impurities (aging by-products) as assessed by some physicochemical properties (acidity, particles count, turbidity, and dissolved decay products) on the partial discharge and breakdown characteristics. The complete analysis is carried out for liquids having the pour points less than -50 °C, including a mineral oil (MO) and two synthetic ester liquids (SE1 and SE2). Changes in the streamer properties, such as partial discharge inception voltage (PDIV), breakdown-streamer inception voltage, and breakdown voltage are reported as a function of the needle tip radius and aging condition. It is observed that the breakdown properties of SE1 are better than that of SE2 and are comparable to MO. To understand the influence of aging on the PD, correlations between decay products, acidity, BSIV, and PDIV are reported. It is observed that the acidity and concentration of decay products directly impact the PD characteristics. [ABSTRACT FROM AUTHOR]

The intent of this work is to evaluate the influence of cellulose insulation paper on gassing tendency of transformer oil under electrical discharge conditions. For comprehensive enumeration, insulation oil was thermally stressed at 115°C as per ASTM D 1934 with a controlled thermal aging history. The thermally aged oils were considered for gassing tendency evaluation as per ASTM D 6180 (5 hours, 10 kV AC) in the presence of cellulose. Different cellulose Kraft paper proportions including 0, 10, 20, and 30% of aged oil were introduced in to discharge cell. Different cellulose proportions and aging conditions were considered to understand the impact of cellulose while understanding the decomposition aspects of insulation. Diagnostic measurements with those including dissolved gas analysis, moisture, interfacial tension, turbidity, dissolved decay contents, acidity, and dissipation factor were performed before and after gassing tendency evaluation. It was found that, cellulose paper aids significantly in increasing dissolved gases and moisture in oil during electrical discharge. Importantly, diagnostic measurements have shown the ability of paper to absorb certain decomposition products during the discharge process. [ABSTRACT FROM AUTHOR]

Transformers are one of the most strategic components in balancing the voltage levels and hence a high priority is given to their performance [1]. It is established that, insulation technology plays a critical role in judging the performance and service life in oil filled apparatus [2]. Performance of the insulation system depends mainly on the deterioration behavior of insulation oil and paper. The mechanisms that are responsible for premature aging of oil/paper insulation are almost the same in all the oil filled apparatus. Yet, there will be a significant difference in the intensity of the aging mechanisms in different apparatus. This intensity is attributable to rating, design, and duration of operation for different machines. The detailed discussions on these mechanisms are presented in the subsequent sections of this paper. However, aging of service insulants is unavoidable and is to be maintained at a lower rate or arrested to the greatest possible extent, such that, catastrophic failures and unscheduled outages may be mitigated [3]. Normally, utilities follow scheduled condition monitoring activities to avoid the consequences of premature aging. Hence, knowledge on these in-service condition monitoring activities will be helpful in understanding the exact deterioration rate of the insulation system. Real time in-service experience of several transformer fleets that belong to United Kingdom utilities are reported in [4]. An early degradation of insulation is noticed through increase in acidity and furan concentration in oil for several transformers in the fleet. Authors investigated this early degradation in different perspectives including loading conditions, manufacturers, and oil chemistry changes. It is inferred that changes in oil chemistry is an important attribute for early degradation and hence utilities are advised to adopt different asset management strategies for affected and unaffected transformers in a fleet. Recently, failure rate data of service aged transformer fleets of an Australian utility were analyzed to establish the relationship between aging and different failure types [5]. It is noticed that degradation of the insulation system will be rapid after 20 years of service aging thus entailing the frequent condition monitoring activities after 20 years to identify premature aging failures. [ABSTRACT FROM AUTHOR]

In this paper, magnetite (Fe3O4) nanoparticles based nanofluid has been synthesized and characterized for application in oil filled transformers. The intent of this work is to check the feasibility of magnetite based nanofluid through appropriate characterizations. Magnetite nanoparticles have been synthesized by chemical co-precipitation method and the corresponding nanoparticles have been characterized by Raman spectroscopy, X-Ray diffraction, UV-Vis spectroscopy and Scanning Electron Microscopy. Further, ferrofluid has been characterized at different concentrations of nanoparticles those including 10%, 20%, 30%, and 40% w/v % to report optimal concentration for improved dielectric and thermal performance of the nanofluid. Electrical measurements such as resistivity, permittivity and loss tangent at different concentrations of magnetite are reported. It is inferred that 20% concentration of magnetite is an optimal concentration with an improvement of 34% of BDV. Importantly, with the application of magnetite nanoparticles overall thermal and dielectric behavior of the insulation fluid will be improved while reducing the size and weight of the transformers. [ABSTRACT FROM AUTHOR]

Transformers are generally considered to be the costliest assets in a power network. The lifetime of a transformer is mainly attributable to the condition of its solid insulation, which in turn is measured and described according to the degree of polymerization (DP) of the cellulose. Since the determination of the DP index is complex and time-consuming and requires the transformer to be taken out of service, utilities prefer indirect and non-invasive methods of determining the DP based on the byproduct of cellulose aging. This paper analyzes solid insulation degradation by measuring the furan concentration, recently introduced methanol, and dissolved gases like carbon oxides and hydrogen, in the insulating oil. A group of service-aged distribution transformers were selected for practical investigation based on oil samples and different kinds of tests. Based on the maintenance and planning strategy of the power utility and a weighted combination of measured chemical indicators, a neural network was also developed to categorize the state of the transformer in certain classes. The method proved to be able to improve the diagnostic capability of chemical indicators, thus providing power utilities with more reliable maintenance tools and avoiding catastrophic failure of transformers. [ABSTRACT FROM AUTHOR]

Operational factors are known to affect the health of an in-service power transformer and to reduce the capabilities and readiness for energy transmission and distribution. Hence, it is important to understand the degradation rate and corresponding behavioral aspects of different insulating fluids under various fault conditions. In this article, the behavior of mineral oil and two environmentally friendly fluids (a synthetic and a natural ester) are reported under arcing, partial discharges, and thermal fault conditions. Arcing, partial discharges and thermal faults are simulated by 100 repeated breakdowns, top oil electrical discharge of 9 kV for five hours, and local hotspots respectively by using different laboratory-based setups. Some physicochemical properties along with the gassing tendency of fresh and aged insulating liquids are investigated after the different fault conditions. UV spectroscopy and turbidity measurements are used to report the degradation behavior and dissolved gas analysis is used to understand the gassing tendency. The changes in the degradation rate of oil under the influence of various faults and the corresponding dissolved gasses generated are analyzed. The fault gas generations are diagnosed by Duval's triangle and pentagon methods for mineral and non-mineral oils. It is inferred that; the gassing tendency of the dielectric fluids evolve with respect to the degradation rate and is dependent on the intensity and type of fault. [ABSTRACT FROM AUTHOR]

The intent of this work is to understand the influence of low energy discharge electric faults in mineral oil and synthetic esters on liquid degradation and gassing tendency at different aging conditions (based on acidity values). A low energy discharge electric fault has been created by continuous discharge of 9 kV for five hours on the liquid surface using a suitable laboratory setup. Liquid degradation is reported by adopting UV spectroscopy, turbidity, and particle counter measurements. The gassing tendency is understood by dissolved gas analysis using Duval's triangle and Duval's pentagon methods for mineral oil and non-mineral oils accordingly. It is observed that the influence of low energy discharges on liquid degradation is higher in mineral oils than synthetic esters. The fault gasses in mineral oil are involved with electrical and thermal faults accompanied by stray gassing whereas only partial discharge activity is noticed for synthetic esters. Importantly, the existence of low energy discharge faults like corona discharges will involve a generation of excess high molecular weight products as compared to low molecular weight products that are soluble in liquid volume. [ABSTRACT FROM AUTHOR]

• Thermal degradation of cellulose in ester and ester nanofluid. • Performance analysis based on breakdown voltage, thermal conductivity and tensile strength measurements. • Influence of the nanoparticle concentration on the degradation of cellulose insulation. Natural ester nanofluids offer improved dielectric and thermal properties than non-biodegradable mineral oil. In the present work, cellulose samples impregnated with unfilled and nanofilled mineral oil and ester are subjected to thermal aging at 130 °C for 168, 336, 504, and 1200 h under open beaker conditions. After 1200 h of thermal stress, the AC breakdown voltage, thermal conductivity, and tensile strength of natural ester impregnated cellulose is 36.13%, 0.46%, and 1.09 times higher than that of mineral oil impregnated cellulose samples, respectively. Also, the AC Breakdown voltage, thermal conductivity, and tensile strength of 0.02 wt% natural ester nanofluid impregnated cellulose is 37.81%, 1.7%, and 1.1 times higher than that of cellulose impregnated with 0.02 wt% mineral oil nanofluid, respectively. The present measurements demonstrate an improvement in the solid insulation performance with natural ester nanofluids, suggesting a possibility of extended service life of solid insulation in liquid filled high voltage transformers. [ABSTRACT FROM AUTHOR]