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Based on the total carbon emission data of 30 provinces and cities in China from 2000 to 2020, this paper used non-parametric kernel density estimation and traditional and spatial Markov probability transfer matrix methods to explore the temporal and spatial dynamic evolution characteristics of carbon dioxide emissions in China and then used a super-SBM model to calculate the carbon emission reduction potential of each province. The results showed that: (1) from 2000 to 2020, the total carbon emissions in China showed an upward trend of fluctuation, from 1.35 Gt to 4.90 Gt year by year, with an annual growth rate of 13.10%. (2) The core density curve showed a double peak form of "main peak + right peak," indicating that a polarization phenomenon occurred in the region. (3) The overall trend of carbon dioxide emissions shifting to superheavy carbon emissions was significant, and the probability of transition was as high as 74.69%, indicating that it was challenging to achieve leapfrog transition in the short term. (4) Based on the principle of fairness and efficiency of provincial carbon emission reduction, mainland China's 30 provincial administrative regions can be divided into four types. Finally, the carbon emission reduction path is designed for each province. [ABSTRACT FROM AUTHOR]