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Nitrogen dioxide (NO 2) in the lower marine atmosphere, mainly emitted by maritime shipping, plays a crucial role in air pollution formation and global human health. However, few measurements of marine atmospheric NO 2 hinder knowledge of trace gas trends and atmospheric chemistry evolution due to shipping emissions. In this study, we use long-term satellite observations of tropospheric NO 2 column from the European TROPOspheric Monitoring Instrument (TROPOMI) and the Chinese Environmental trace gases Monitoring Instrument (EMI) to analyze marine atmospheric NO 2 variations, especially during the global COVID-19 pandemic and escalating geopolitical crises. First, we demonstrate the detection of NO 2 enhancements along shipping routes, including the North Atlantic route, the North Pacific route, and the Cape route, indicating significant emissions of atmospheric NO 2 from on-ocean shipping. Second, we observe and quantify the response of marine atmospheric NO 2 concentrations to major shipping events, such as the Suez Canal blockage, the Los Angeles-Long Beach port congestion, and the Russia-Ukraine war, resulting in local NO 2 concentration variations of approximately 40% decrease to 70% increase. Long-term analysis reveals reduced NO 2 concentrations in most coastal ports and maritime shipping routes during the COVID-19 lockdown, with reductions exceeding 50% or durations lasting up to 200 days. However, some rapidly developing ports, such as Beibu Gulf (China) and Dakar (Senegal), did not experience a decrease in NO 2 concentrations, suggesting that local authorities need to pay more attention to these fast-growing yet underestimated emission sources. In addition, by excluding the impact of meteorology using statistical models, we find that the current Emission Control Area (ECA) policies have effectively reduced NO 2 concentrations in Chinese coastal ports. These results contribute to understanding spatiotemporal characteristics of marine atmospheric NO 2 , including ports and open-sea shipping routes, and guide further ECA policies to control marine NO 2 pollution. • New-generation satellites including TROPOMI and EMI can detect enhanced NO 2 pollution over maritime shipping routes. • Major shipping events have led to from −40% to 70% variations in local marine atmospheric NO 2 concentrations. • The COVID-19 pandemic reduced NO 2 pollution by > 50%, for a maximum of 200 days in the world's top ports. • Shipping emission control policies have effectively improved NO 2 pollution in Chinese ports since January 2019. [ABSTRACT FROM AUTHOR]