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A simple and low-cost fabrication method of dye-sensitized solar cells (DSSCs) was developed to improve the structure and performance of the photoanode with the pressed layer and compact TiO2 thin film using spin coating, screen printing, and mechanical compression. In this study, four different TiO2 layers were adopted to fabricate photoanodes: a mesoporous TiO2 nanoparticles (NPs) layer, a pressed TiO2 NPs layer, a mesoporous TiO2 NPs layer on the TiO2 compact thin film, and a pressed TiO2 NPs layer on the TiO2 compact thin film. The compact thin film was deposited on the fluorine-doped tin oxide (FTO) glass via spin coating, while the mesoporous TiO2 NPs layer was deposited via the screen-printing method. The pressed TiO2 NPs layer was produced by compressing the mesoporous TiO2 NPs layer with a hydraulic press machine. When using the pressed TiO2 NPs layer for the photoanode of DSSC, the power conversion efficiency of DSSC was enhanced the most. The electron lifetime for DSSC with photoanodes based on the pressed TiO2 NPs and mesoporous TiO2 NPs layers were 8.217 and 6.287 ms, respectively. The power conversion efficiency of DSSC with photoanodes based on the pressed TiO2 NPs layer was 5.4%, while that based on the mesoporous TiO2 NPs layer was 4.08%. DSSC with photoanodes based on the pressed TiO2 NPs layer showed a significant increase in the power conversion efficiency by 36.16% compared to that based on the mesoporous TiO2 NPs layer. [ABSTRACT FROM AUTHOR]

In this study, dye-sensitized solar cells (DSSCs) were fabricated using nanocrystalline titanium dioxide (TiO 2) nanoparticles as photoanode. Photoanode thin films were prepared by doctor blading method with 420 kg/cm 2 of mechanical compression process and heat treatment in the air at 500°C for 30 min. The optimal thickness of the TiO 2 NP photoanode is 26.6 μm with an efficiency of 9.01% under AM 1.5G illumination at 100 mW/cm 2. The efficiency is around two times higher than that of conventional DSSCs with an uncompressed photoanode. The open-circuit voltage of DSSCs decreases as the thickness increases. One DSSC (sample D) has the highest conversion efficiency while it has the maximum short-circuit current density. The results indicate that the short-circuit current density is a compromise between two conflict factors: enlargement of the surface area by increasing photoanode thickness and extension of the electron diffusion length to the electrode as the thickness increases. [ABSTRACT FROM AUTHOR]

Pinning phenomena were investigated in the superconducting Nb thin film with composite hexagonal arrays. The composite pinning arrays were consisting of two kinds of pinning sites with different pinning sizes. The smaller pinning defects were added to the center of every honeycomb pinning array to observe the configuration of the vortices, comparing to the periodic triangular and honeycomb arrays. The film with this kind of composite array can be regarded as a transition between the films with triangular array and honeycomb array. The critical current as a function of magnetic field for four samples were measured. Regular 150 Oe interval of the matching fields for the triangular arrays was found, while for the honeycomb arrays, the interstitial vortices were caged at the center of every honeycomb array, causing 50 Oe interval of the matching fields. For the samples with composite arrays, the 100 Oe or 50 Oe intervals of matching fields correspond to every larger or smaller pinning site capturing one more vortex, respectively. We found that the relative pinning strength of the large pinning sites is greater than that of the small ones. We conducted the simulations based on the time dependent Ginzburg-Landau theory to confirm that the interstitial vortices did exist in the honeycomb arrays which caused the various intervals between the matching fields. [ABSTRACT FROM AUTHOR]