7 results on '"Jiao, Qingjie"'
Search Results
2. Facile Recrystallization Process for Tuning the Crystal Morphology and Thermal Safety of Industrial Grade PYX.
- Author
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Zhang, Mi, Fu, Jianbo, Ren, Hui, Li, Shengfu, Sun, Xiaole, and Jiao, Qingjie
- Subjects
CRYSTAL morphology ,RECRYSTALLIZATION (Metallurgy) ,INDUSTRIAL safety ,CHEMICAL structure ,EXPLOSIVES ,SCANNING electron microscopy ,EXPLOSIONS ,DIMETHYL sulfoxide - Abstract
In this study, the crystal appearance of industrial grade 2,6-diamino-3,5-dinitropyridine (PYX) was mostly needle-shaped or rod-shaped with an average aspect ratio of 3.47 and roundness of 0.47. According to national military standards, the explosion percentage of impact sensitivity s about 40% and friction sensitivity is about 60%. To improve loading density and pressing safety, the solvent–antisolvent method was used to optimize the crystal morphology, i.e., to reduce the aspect ratio and increase the roundness value. Firstly, the solubility of PYX in DMSO, DMF, and NMP was measured by the static differential weight method, and the solubility model was established. The results showed that the Apelblat equation and Van't Hoff equation could be used to clarify the temperature dependence of PYX solubility in a single solvent. Scanning electron microscopy (SEM) was used to characterize the morphology of the recrystallized samples. After recrystallization, the aspect ratio of the samples decreased from 3.47 to 1.19, and roundness increased from 0.47 to 0.86. The morphology was greatly improved, and the particle size decreased. The structures before and after recrystallization were characterized by infrared spectroscopy (IR). The results showed that no chemical structure changes occurred during recrystallization, and the chemical purity was improved by 0.7%. According to the GJB-772A-97 explosion probability method, the mechanical sensitivity of explosives was characterized. After recrystallization, the impact sensitivity of explosives was significantly reduced from 40% to 12%. A differential scanning calorimeter (DSC) was used to study the thermal decomposition. The thermal decomposition temperature peak of the sample after recrystallization was 5 °C higher than that of the raw PYX. The thermal decomposition kinetic parameters of the samples were calculated by AKTS software, and the thermal decomposition process under isothermal conditions was predicted. The results showed that the activation energy (E) of the samples after recrystallization was higher by 37.9~527.6 kJ/mol than raw PYX, so the thermal stability and safety of the recrystallized samples were improved. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
3. Probing the Reaction Mechanisms of 3,5-Difluoro-2,4,6-Trinitroanisole (DFTNAN) through a Comparative Study with Trinitroanisole (TNAN).
- Author
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Jiao, Qingjie, Li, Tianqi, Ou, Yapeng, Jing, Suming, and Wang, Fang
- Subjects
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POLYCYCLIC compounds , *GROUP 15 elements , *TRICHLOROPHENOL , *MOLECULAR structure , *COMPARATIVE studies , *FLUORINE compounds , *EXPLOSIVES - Abstract
To probe the thermal decomposition mechanisms of a novel fluorinated low-melting-point explosive 3,5-difluoro-2,4,6-trinitroanisole (DFTNAN), a comparative study with trinitroanisole (TNAN) was performed under different heating conditions. The thermal decomposition processes and initial reactions were monitored by DSC-TG-FTIR-MS and T-jump-PyGC-MS coupling analyses, respectively. The results show that fluorine decreased the thermal stability of the molecular structure, and the trigger bond was transferred from the ortho-nitro group of the ether to the para-nitro group. The possible reaction pathway of DFTNAN after the initial bond breakage is the rupture of the dissociative nitro group with massive heat release, which induces the ring opening of benzene. Major side reactions include the generation of polycyclic compounds and fluorine atom migration. Fluorine affects the thermal stability and changes the reaction pathway, and fluorinated products appear in the form of fluorocarbons due to the high stability of the C-F bond. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
4. Influence of Fluorinated Polyurethane Binder on the Agglomeration Behaviors of Aluminized Propellants.
- Author
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Shen, Chen, Yan, Shi, Ou, Yapeng, and Jiao, Qingjie
- Subjects
PROPELLANTS ,FOURIER transform infrared spectroscopy ,POLYURETHANE elastomers ,POLYURETHANES ,TWO-phase flow ,CAMCORDERS - Abstract
In this study, fluorinated polyurethane (FPU) was prepared from dialcohol-terminated perfluoropolyether as a soft segment; isophorone diisocyanate (IPDI) as a curing agent; 1,2,4-butanetriol (BT) as a crosslinker; and 1,4-butanediol (BDO) as a chain extender. Fourier transform infrared spectroscopy (FTIR) and
1 H NMR were used to characterize the structure of the FPU. The mechanical properties of the FPUs with different BDO and BT contents were also measured. The tensile strength and breaking elongation of the optimized FPU formula were 3.7 MPa and 412%, respectively. To find out the action mechanism of FPU on Al, FPU/Al was prepared by adding Al directly to FPU. The thermal decomposition of the FPU and FPU/Al was studied and compared by simultaneous differential scanning calorimetry-thermogravimetry-mass spectrometry (DSC-TG-MS). It was found that FPU can enhance the oxidation of Al by altering the oxide-shell properties. The combustion performance of the FPU propellant, compared with the corresponding hydroxyl-terminated polyether (HTPE)-based polyurethane (HPU) propellant, was recorded by a high-speed video camera. The FPU propellants were found to produce smaller agglomerates due to the generation of AlF3 in the combustion process. These findings show that FPU may be a useful binder for tuning the agglomeration and reducing two-phase flow losses of aluminized propellants. [ABSTRACT FROM AUTHOR]- Published
- 2022
- Full Text
- View/download PDF
5. Studies on the Thermal Behaviors of Hexogen, Ammonium Perchlorate and Their Mixtures by TG-DSC
- Author
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Jiao Qingjie, Zhao Jiachen, Xueyong Guo, Shuo Wang, Jinyao Zhang, Zhang Jingyuan, Yang Guo, and Yajuan Zhou
- Subjects
Chemistry ,Composite number ,Thermal decomposition ,02 engineering and technology ,Calorimetry ,021001 nanoscience & nanotechnology ,Ammonium perchlorate ,01 natural sciences ,010406 physical chemistry ,0104 chemical sciences ,chemistry.chemical_compound ,Chemical engineering ,Thermal ,Particle size ,0210 nano-technology - Abstract
In order to study the effect of the oxidizer ammonium perchlorate (AP) on the energy release of composite energetic materials, the thermal decomposition of AP with different particle size, Hexogen (RDX), and their mixtures were studied by means of thermogravimetry-differential scanning calorimetry (TG-DSC). The results showed that RDX had one weight loss step and there were two weight loss steps for AP and the mixture of AP and RDX. We can also conclude that RDX and AP accelerate the thermal decomposition of each other and the change of particle size of AP has no effect on this acceleration.
- Published
- 2019
6. Application of Liquid Paraffin in Castable CL-20-Based PBX
- Author
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Zhang Jingyuan, Jiao Qingjie, Pu Zhang, and Xue-yong Guo
- Subjects
Viscosity ,Phase transition ,Polybutadiene ,Materials science ,Physics and Astronomy (miscellaneous) ,Detonation velocity ,Liquid paraffin ,Thermal decomposition ,Detonation ,Thermal stability ,Composite material - Abstract
Hydroxy-terminated polybutadiene (HTPB)/CL-20 castable explosives plasticized with liquid paraffin were processed successfully by a cast-curing method. The compatibility of liquid paraffin with CL-20, influence of liquid paraffin on CL-20 phase transition, and viscosity of the cast mixture were tested and analyzed. The thermal decomposition characteristics, thermal stability, mechanical sensitivity, and velocity of detonation (VOD) of the HTPB/CL-20 plastic-bonded explosives (PBXs) were also measured. The experimental results showed that liquid paraffin was well compatible with CL-20, and it did not have a distinct effect on the ϵ- to γ-phase transition of CL-20. In addition, the casting mixture was free-flowing with sufficiently low viscosity. When the content of CL-20 is 90% by weight, the measured VOD reached 8,775 m/s (density of 1.78 g/cm3), and the PBXs exhibited moderate mechanical sensitivity and good thermal stability.
- Published
- 2014
7. Pyrolysis pathway redirection of HNIW by nano-aluminum.
- Author
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Zhang, Honglei, Jiao, Qingjie, Ou, Yapeng, and Guo, Xueyong
- Subjects
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ALUMINUM compounds , *PYROLYSIS , *DIFFERENTIAL scanning calorimetry , *THERMOGRAVIMETRY , *FOURIER transform infrared spectroscopy , *SCISSION (Chemistry) , *THERMAL stability - Abstract
Highlights • Nano-Al enhances the thermal stability of HNIW. • HNIW undergoes synchronous bond cleavage due to high molecular strain. • Pyrolysis of HNIW/nano-Al is trigged by the cleavage of C N bond. Abstract The pyrolysis behavior of hexanitrohexaazaisowurtzitane (HNIW) and HNIW/nano-Aluminum are investigated by non-isothermal differential scanning calorimetry/thermogravimetry/Pyrolysis-mass spectrometry/Fourier transform infrared spectroscopy (DSC/TG/Py-MS/FTIR) coupling analysis. The result shows that nano-Al improves the thermal stability of HNIW by swinging the very beginning of pyrolysis from synchronous bond cleavage of the highly strained molecular to the formation of HONO free radical corresponding with the increment of apparent activation energy. After the initial stage, nano-Al catalyzes the pyrolysis pathway to primary cleavage of C–N bond and releasing hyperbaric unstable N 2 O, which sequentially reacts with other gaseous products and Al. [ABSTRACT FROM AUTHOR]
- Published
- 2019
- Full Text
- View/download PDF
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