1. New selection rule of resonant Raman scattering in MoS2 monolayer under circular polarization
- Author
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Jianqi Huang, Zhidong Zhang, Zhiyong Liu, and Teng Yang
- Subjects
Materials science ,Polymers and Plastics ,Mechanical Engineering ,Metals and Alloys ,Laser ,law.invention ,Photoexcitation ,symbols.namesake ,Mechanics of Materials ,law ,Monolayer ,Materials Chemistry ,Ceramics and Composites ,symbols ,Tensor ,Atomic physics ,Raman spectroscopy ,Absorption (electromagnetic radiation) ,Raman scattering ,Circular polarization - Abstract
The first-order resonant Raman spectra of monolayer MoS2 are calculated under the circularly polarized photoexcitation. The anomalously nonzero Raman intensity of the in-plane E mode under the Z ¯ ( σ + σ + ) Z or Z ¯ ( σ − σ − ) Z geometry, which goes against the conventional selection rule, appears under some circumstances when optical absorption occurs at some special reciprocal points between the zone-center Γ and the zone-edge-center M points. At that moment, the valley selectivity to the circular polarization is lifted. The analysis shows that the anomalous Raman intensity of the E mode for the same circularly polarized incident and scattered light is consistent with the pseudo-angular-momentum conservation law. The calculated E Raman tensor of monolayer MoS2 is found to vary with laser energy. The two diagonal terms of the Raman tensor change their signs from mutually opposite to the same when the relative intensity of the in-plane E mode to the out-of-plane A 1 ′ mode increases, indicating the increasingly important role played by the Frolich-type electron-phonon interaction over the deformation potential. Our study may shed new light on the understanding of the novel electron-photon process and assist in the design of new type of optoelectronic devices.
- Published
- 2022