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This study builds upon prior research by exploring droplet oscillation dynamics for surface tension determination using a drop-on-demand high-temperature droplet generator. Computational fluid dynamics (CFD) simulations were conducted to analyse frequency shifts over time, comparing two different materials with consistent results. The findings suggest potential for developing correction factors for oscillations with larger initial deformations. Additionally, frequency shifts relative to evolving aspect ratios of droplets starting with higher initial deformations were compared. Corrective measures can be applied, particularly beneficial for short-term measurements based on image analysis with minimal overall frequency shift. Slight asymmetry in oscillation with increasing aspect ratio could be accredited to droplet cross-sectional geometry or energy availability for returning prolate droplets to a spherical state. Experimental results indicated minimal frequency shift within a measurement duration of up to 40 ms, affirming the adequacy of using a fitted sine function without a time-dependent frequency term for overall frequency determination. A dimensionless criterion can be used to filter out unsuitable droplets. A temperature-dependent surface tension trend for AlCu10 alloy consistent with literature findings is introduced. [ABSTRACT FROM AUTHOR]