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This work aimed to explore the effect of cBN (cubic boron nitride) content on the microstructures and wear-corrosion resistance of the CoCrFeNiTi0.8-xcBN (x = 0, 2, 4, 6 wt.%) particle-reinforced high-entropy alloy coatings. Laser cladding technology was used to prepare the coatings on TC18 substrate. The microstructures, volume wear rates and polarization curves were characterized. The results showed that the CoCrFeNiTi0.8-xcBN coatings had an optimal forming quality under the process parameters: laser power of 1500 W, scanning rate of 12 mm/s and overlapping rate of 60%. As the cBN content increased, plenty of TiN and TiB2 hard particles formed in situ in the coatings, significantly improved the wear resistance. As a result, the volume wear rate of CoCrFeNiTi0.8-6cBN was only 4.0% and 16.5% of that of TC18 substrate and CoCrFeNiTi0.8 coating, respectively; the wear mechanism changed from adhesive wear + oxidative wear to abrasive wear + oxidative wear gradually. Moreover, CoCrFeNiTi0.8-xcBN coatings can effectively inhibit the infiltration of corrosive media by dense organizational characteristics and the physical barrier effect of oxidation-protective films. After 480 h of neutral salt spray (NSS) test, the CoCrFeNiTi0.8-xcBN coatings exhibited excellent corrosion resistance, both of the appearance and protection rating reached level 10. Therefore, it can be used as the wear-corrosion-resistant coating for the TC18 substrate in a NSS environment. [ABSTRACT FROM AUTHOR]

In order to explore the corrosion damage behavior of plasma-sprayed NiCoCrAlY/magnesia-stabilized zirconia (18~22 wt.% MgO-ZrO2, MSZ) thermal barrier and anti-ablation coatings in a salt spray environment, a series of neutral salt spray (NSS) tests for 96 h (N-2), 192 h (N-4) and 288 h (N-6) were carried out on the coatings. The microstructures, composition distributions, potentiodynamic polarization curves, bonding strengths and anti-ablation properties of the coatings before and after the NSS tests were characterized. The results show that, with the increase in salt spray time, the expansion and overflow of corrosion products (FexOy) led to more defects forming inside the coating; the porosity of the top coat (TC) of N-6 increased to 15.2% in comparison to that of the blank control sample (N-0), which was 8.5%. According to the potentiodynamic polarization curves, accelerated corrosion occurred in the coating samples after the salt spray time reached 192 h, and the corrosion current density rapidly surged from 2.2 × 10−8 A·cm−2 (N-4) to 2.2 × 10−5 A·cm−2 (N-6). Similar degradation tends could be found in the bonding strengths and mass ablation rates of the coatings due to the accumulation of loose corrosion products on the substrate, which affected the bonding states of the coatings and promoted their spalling under an oxyacetylene flame (OAF). As a result, the maximum service life of the NiCoCrAlY/MSZ coatings in the neutral salt spray environment was about 192 h. This work is instructive for studying the environmental adaptability of metal/ceramic double-layer coatings. [ABSTRACT FROM AUTHOR]

The effects of three pyridine derivative additives, 4-hydroxypyridine, 4-picolinic acid, and 4-cyanopyridine, on Al-Mn coatings were investigated in 1-ethyl-3-methylimidazolium chloride-AlCl3-MnCl2 (EMIC-AlCl3-MnCl2) ionic liquids. The smooth mirror-like bright Al-Mn coatings were obtained only in the EMIC-AlCl3-MnCl2 ionic liquids containing 4-cyanopyridine, while the matte Al-Mn coatings were electrodeposited from EMIC-AlCl3-MnCl2 without additives or containing either 4-hydroxypyridine or 4-picolinic acid. The scanning electron microscope and X-ray diffraction showed that the bright Al-Mn coatings consisted of nanocrystals and had a strong (200) preferential orientation, while the particle size of matte Al-Mn coatings were within the micron range. The brightening mechanism of 4-cyanopyridine is due to it being adsorbed onto the cathode to produce the combined effect of (1) generating an overpotential to promote Al-Mn nucleation; (2) inhibiting the growth of the deposited nuclei and enabling them grow preferentially, making the coating composed of nanocrystals and with a smooth surface. The brightening effect of 4-cyanopyridine on the Al-Mn coatings was far better than that of the 4-hydroxypyridine and the 4-picolinic acid. In addition, the bright Al-Mn coating was prepared in a bath with 6 mmol·L−1 4-cyanopyridine and displayed superior corrosion resistance relative to the matte coatings, which could be attributed to its unique nanocrystalline structure that increased the number of grain boundaries and accelerated the formation of the protective layer of the corrosion products. [ABSTRACT FROM AUTHOR]

Mg Al LDHs (layered double hydroxides) coatings were deposited on the surface of titanium alloy Ti10V2Fe3Al, accompanied by modification with ZrO 2 and MoS 2 nanoparticles through electrophoretic deposition. FE-SEM, XRD and EDS measurements were used to investigate the microstructure and composition of the composite coatings. Corrosion resistance was measured by potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS) in 3.5 wt% NaCl solution. The LDHs/MoS 2 composite coating exhibited the best corrosion resistance. Ball on disc tests was implemented to obtain morphology, the friction coefficient and wear loss of the worn surfaces. The LDHs/ZrO 2 composite coating exhibited the best wear resistance. A mechanism for enhancing the wear-resistance of the different nanoparticles-modified MgAl-LDHs coatings was proposed. • Both the LDHs/ZrO 2 and LDHs/MoS 2 composite coatings protected the substrate from wear. • LDHs coating and nanoparticles had a synergistic effect on anti-wear performance. • The LDHs/MoS 2 and LDHs/ZrO 2 composite coatings exhibited the best corrosion resistance and wear resistance, respectively. [ABSTRACT FROM AUTHOR]