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As interest in smart textiles grows, fiber-based supercapacitors are gaining attention as promising devices for powering wearable electronics. Herein, we have demonstrated a two-step manufactured hybrid fiber with excellent energy storage properties. Anhydrous MXene (Ti3C2Tx) sheets are primarily spun in synergy with liquid crystal carbon nanotubes (CNTs) to produce a continuous fiber as a promising electrode material, which solves the problem of poor rate capability owing to the sheet re-stacking of MXene. MnO2@MXene/CNT fibers are subsequently prepared by electrochemical deposition with controlled time. The optimal content of MXene (10 wt%) and a perfect thickness of the MnO2 layer (4 μm) are testified to achieve an excellent capacitance of 371.1 F cm−3 in three-electrode system, which is about 200% and 1800% higher than that of 10 wt%-MXene/CNT and CNT fiber electrode, respectively. Symmetric fiber supercapacitor is assembled by paralleling two fibers with LiCl/PVA gel electrolyte, manifesting a superior cycling stability of 86.3% after 10000 cycles. Anhydrous MXene nanosheets and CNTs are incorporated by a high yield spinning technique to prepare continuous hybrid fibers as a conductive framework for MnO2 deposition, exhibiting stable and outstanding energy storage properties in supercapacitor. [ABSTRACT FROM AUTHOR]

Summary: All‐solid‐state flexible supercapacitors (FSCs) are promising energy‐storage devices in wearable smart electronics. Carbon cloth (CC) has emerged as an ideal candidate as it can fulfill all the required properties for conductive, corrosion‐resistant, and lightweight FSC substrates. However, commercial CC is difficult to adhere to without crosslinkers and binders owing to the hydrophobic surface. Herein, oxygen plasma and chemistry methods are selected for hydrophilic modification of commercial CC. Then, Ti3C2Tx flakes are coated on the surface of modified CC as active materials. These modified morphologies were characterized by scanning electron microscope and mechanical properties were investigated by a fabric tensile tester. The electrochemical properties of the MXene‐based electrodes by two modification methods were compared. Chemistry modification CC/Ti3C2Tx electrode exhibits an areal capacitance of 513 mF cm−2, which is 88% higher than that of oxygen plasma‐modified CC/MXene electrode, and capacitance retention remains above 92% after 10 000 cycles. This work proposes a feasible strategy, offering a platform for rational designs of flexible electronics based on textiles, as well as employing a large family of MXenes and their heterostructures. [ABSTRACT FROM AUTHOR]

The ubiquity of wearables, coupled with the increasing demand for power, presents a unique opportunity for nanostructured fiber-based mobile energy storage systems. When designing wearable electronic textiles, there is a need for mechanically flexible, low-cost and light-weight components. To meet this demand, we have developed an all-in-one fiber supercapacitor with a total thickness of less than 100 μm using a novel facile coaxial wet-spinning approach followed by a fiber wrapping step. The formed triaxial fiber nanostructure consisted of an inner poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) core coated with an ionically conducting chitosan sheath, subsequently wrapped with a carbon nanotube (CNT) fiber. The resulting supercapacitor is highly flexible, delivers a maximum energy density 5.83 Wh kg−1 and an extremely high power of 1399 W kg−1 along with remarkable cyclic stability and specific capacitance. This asymmetric all-in-one fiber supercapacitor may pave the way to a future generation of wearable energy storage devices. [ABSTRACT FROM AUTHOR]