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Pyrobitumen has been discovered in the dolostone reservoir of the Central Sichuan Basin, southwest China, accumulates coevally with hydrothermal minerals in pores. The pyrobitumen has strong anisotropy with an evolutionary sequence from mosaic to a fibrous texture. A similar sequence of anisotropy has also been observed in mesophase pitch during the process of coking coal. Reflectance of the pyrobitumen shows a positive correlation with anisotropic evolution and increasing depth. Hopane and sterane biomarkers are abundant in extracts of highly anisotropic pyrobitumen with smooth, rough, hyperplastic surface and honeycomb micropores. Methylpyrene and methylchrysene maturity indicators and the reflectance values of pyrobitumen show a positive linear correlation in Cambrian samples, but show random correlation in Sinian samples. Fluid inclusion microthermometry of hydrothermal minerals, together with the burial and heat flow history of the reservoir indicate an abrupt thermal event that may have impacted the generation and evolution of pyrobitumen. This appears to be confirmed by the reflectance values of pyrobitumen in the source rock and reservoir. The pyrobitumen in source rock was less heated by the hydrothermal fluid due to its poor porosity and have lower reflectance values. However, the pyrobitumen in weathering crust reservoir was more heated by the hydrothermal fluid and have higher reflectance values, because the reservoir rocks have higher porosity. The occurrence and characteristics of pyrobitumen indicate an in-situ pyrolysis of oil, which was triggered by an abrupt thermal event in the reservoir. The reconstruction of burial history and heat flow, as well as the hydrothermal fluid minerals of the dolomite reservoir all indicate the thermal event of the Sichuan Basin might correlate with the Emei mantle plume in Late Permian.

The lower Cambrian sediments including the Qiongzhusi and Maidiping formations in the Sichuan Basin are generally considered as the main source rocks of Precambrian-Cambrian petroleum system. A comprehensive study integrated with multiple geochemical methods was conducted on 119 lower Cambrian drillcore samples collected from the upper Yangtze Platform. The results show that the fluctuation of sea level and climate during the deposition of the Qiongzhusi and Maidiping formations act as the critical factors controlling the watermass conditions and thus OM accumulation. During the deposition of upper Maidiping Formation (Є1m), the paleoclimate was arid and sea level was relatively low in the study area. The depositional environment indexes (UEF-MoEF, gammacerane index, β-carotane and VEF) suggested that the upper Є1m was deposited in a strong restricted marine setting with high water salinity and anoxic water conditions in Ziyang-Weiyuan area. However, during the early Qiongzhusi Formation period, the paleoclimate became humid and sea level rose in the study area. High paleoproductiviy caused by high concentrations of nutrients brought by seawater and freshwater plays an important role in OM accumulation in the basal part of the Qiongzhusi Formation (Є1q). Furthermore, the model of paleoproductivity promotion caused by the coordinated control of climate and extensive transgression in the lower part of Є1q may also be applicable to interpret the origin of high organic carbon abundance in the strata deposited in the same period with the Є1q (such as Shiyantou, Shuijingtuo and Niutitang formations) in other parts of the upper Yangtze Platform.

Dibenzofuran and its methyl substituted homologues are the important oxygen-containing polycyclic aromatic compounds in crude oils. The ratio of 1-/4-methyldibenzofuran has been successfully used in sandstone reservoir tracing oil migration orientation. Here we focus on the geo-chromatographic fractionation effect of methyldibenzofuran (MDBF) in dolomite reservoirs. We calculated the charge density differences between 1-methyldibenzofuran (1-MDBF) and 4-methyldibenzofuran (4-MDBF) based on density functional theory. The E I n between MDBF isomers and dolomite (104) surface was also calculated according to molecular dynamics simulation. The result show that comparing with the 4-MDBF, there is strong interaction between 1-MDBF and dolomite (104) surface leading the ratio of 1-MDBF and 4-MDBF increase with the migration distance. There is no significant correlation between bitumen reflectance and the ratio of 1-MDBF and 4-MDBF in our samples. In addition, molecular simulation results show that the MDBF isomers are thermodynamically stable and dissociation of Ph-CH3 is difficult to occur under geological condition. All these demonstrate that 1-MDBF and 4-MDBF can be survived after oil-cracking to gas and pyrobitumen. Therefore, in theory, the ratio of 1-/4-methyldibenzofuran is also regarded as an index for oil migration orientation in dolomite reservoir. Gas chromatography-mass spectrometry results show that MDBFs occur at relatively higher abundance in the bitumens of the Ediacaran Dengying Formation (Z2dn4) and Cambrian Longwangmiao Formation (Є1l) in the Sichuan Basin. The ratio of 1-/4-methyldibenzofuran has been successfully used to trace the crude oil filling pathway in the Z2dn4 and Є1l dolomite reservoir in the Sichuan Basin in this study. Two preferential filling orientations (i.e. from west to east and from north to south) for paleo-oil have been identified in the contour maps of 1-/4-methyldibenzofuran in the Z2dn4 and Є1l, which is consistent with the geological background.

Two sets of coal-bearing measures, the Upper Triassic Xujiahe Formation (T 3 x) and the Upper Permian Longtan Formation (P 2 l), have been extensively developed in the Sichuan Basin, SW China and some large gas fields related to these coal-bearing measures have been discovered. The stable carbon and hydrogen isotopic composition of alkane gases sourced from the two sets of coal-bearing measures (T 3 x and P 2 l gases) have been investigated in this study. The main controls on the gas composition and isotopic abundances of gases in the Sichuan Basin have been identified and distinguished on the basis of their molecular and isotopic composition. The carbon and hydrogen isotopic compositions of methane ( δ 13 C C1 : − 42.5‰ to − 26.8‰; δ D C1 : − 173‰ to − 107‰) vary widely and show a positive correlation with the thermal maturity of the source rocks. The δ 13 C C2 value of the T 3 x and P 2 l gases in the Sichuan Basin ranged from − 28.2‰ to − 21.3‰, and showed less variations with increasing maturity from R o values of 1.2% to 2.8%. However, these δ 13 C C2 values differ greatly from that of oil-associated gas in the Sichuan Basin. Thus we provide further evidence that the value of δ 13 C C2 is a useful parameter to distinguish coal-derived and oil associated gases. The hydrocarbon gases in the Xujiahe and Jurassic reservoirs in contrast showed little isotopic difference indicating that secondary migration has little influence on their carbon and hydrogen isotope compositions. In addition, the δ 13 C values of P 2 l CO 2 (− 2.6− to 3.3‰) may reflect an origin from dissolution of the carbonates in the reservoir by acidic fluids containing H 2 S.