1. Detection of vibrationally excited HC7N and HC9N in IRC +10216.
- Author
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Pardo, J. R., Bermúdez, C., Cabezas, C., Agúndez, M., Gallego, J. D., Fonfría, J. P., Velilla-Prieto, L., Quintana-Lacaci, G., Tercero, B., Guélin, M., and Cernicharo, J.
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EXCITED state energies ,AB-initio calculations ,QUANTUM numbers ,EXCITED states ,CIRCUMSTELLAR matter - Abstract
Observations of IRC +10216 with the Yebes 40 m telescope between 31 and 50 GHz have revealed more than 150 unidentified lines. Some of them can be grouped into a new series of 26 doublets, harmonically related with integer quantum numbers ranging from J
up = 54 to 80. The separation of the doublets increases systematically with J, that is to say, as expected for a linear species in one of its bending modes. The rotational parameters resulting from the fit to these data are B = 290.8844 ± 0.0004 MHz, D = 0.88 ± 0.04 Hz, and q = 0.1463 ± 0.0001 MHz. The rotational constant is very close to that of the ground state of HC9 N. Our ab initio calculations show an excellent agreement between these parameters and those predicted for the lowest energy vibrationally excited state, ν19 = 1, of HC9 N. This is the first detection, and complete characterization in space, of vibrationally excited HC9 N. An energy of 41.5 cm−1 is estimated for the ν19 state. In addition, 17 doublets of HC7 N in the ν15 = 1 state, for which laboratory spectroscopy is available, were detected for the first time in IRC +10216. Several doublets of HC5 N in its ν11 = 1 state were also observed. The column density ratio between the ground and the lowest excited vibrational states are ≈127, 9.5, and 1.5 for HC5 N, HC7 N, and HC9 N, respectively. We find that these lowest-lying vibrational states are most probably populated via infrared pumping to vibrationally excited states lying at ≈600 cm−1 . The lowest vibrationally excited states thus need to be taken into account to precisely determine absolute abundances and abundance ratios for long carbon chains. The abundance ratios N(HC5 N)/N(HC7 N) and N(HC7 N)/N(HC9 N) are 2.4 and 7.7, respectively. [ABSTRACT FROM AUTHOR]- Published
- 2020
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