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We present 500 and 700 au resolution 1 and 3 mm Atacama Large Millimeter/submillimeter Array observations, respectively, of protostellar cores in protoclusters Sagittarius B2 (Sgr B2) North (N) and Main (M), parts of the most actively star-forming cloud in our Galaxy. Previous lower-resolution (5000 au) 3 mm observations of this region detected ∼150 sources inferred to be young stellar objects (YSOs) with M > 8 M _⊙ . With a 10-fold increase in resolution, we detect 371 sources at 3 mm and 218 sources in the smaller field of view at 1 mm. The sources seen at low resolution are observed to fragment into an average of two objects. About one-third of the observed sources fragment. Most of the sources we report are marginally resolved and are at least partially optically thick. We determine that the observed sources are most consistent with Stage 0/I YSOs, i.e., rotationally supported disks with an active protostar and an envelope, that are warmer than those observed in the solar neighborhood. We report source-counting-based inferred stellar mass and the star formation rate of the cloud: 2800 M _⊙ and 0.0038 M _⊙ yr ^−1 for Sgr B2 N and 6900 M _⊙ and 0.0093 M _⊙ yr ^−1 for Sgr B2 M, respectively.

We report the discovery of nine new hot molecular cores in the Deep South (DS) region of Sagittarius B2 using Atacama Large Millimeter/submillimeter Array Band 6 observations. We measure the rotational temperature of CH _3 OH and derive the physical conditions present within these cores and the hot core Sgr B2(S). The cores show heterogeneous temperature structure, with peak temperatures between 252 and 662 K. We find that the cores span a range of masses (203–4842 M _⊙ ) and radii (3587–9436 au). CH _3 OH abundances consistently increase with temperature across the sample. Our measurements show the DS hot cores are structurally similar to Galactic disk hot cores, with radii and temperature gradients that are comparable to sources in the disk. They also show shallower density gradients than disk hot cores, which may arise from the Central Molecular Zone’s higher density threshold for star formation. The hot cores have properties which are consistent with those of Sgr B2(N), with three associated with Class II CH _3 OH masers and one associated with an ultra-compact H ii region. Our sample nearly doubles the high-mass star-forming gas mass near Sgr B2(S) and suggests the region may be a younger, comparably massive counterpart to Sgr B2(N) and (M). The relationship between peak CH _3 OH abundance and rotational temperature traced by our sample and a selection of comparable hot cores is qualitatively consistent with predictions from chemical modeling. However, we observe constant peak abundances at higher temperatures ( T ≳ 250 K), which may indicate mechanisms for methanol survival that are not yet accounted for in models.

We report the first extragalactic detection of the higher-order millimeter hydrogen recombination lines (Δ n > 2). The γ -, ϵ -, and η -transitions have been detected toward the millimeter continuum source N 105–1 A in the star-forming region N 105 in the Large Magellanic Cloud with the Atacama Large Millimeter/submillimeter Array. We use the H40 α line, the brightest of the detected recombination lines (H40 α , H36 β , H50 β , H41 γ , H57 γ , H49 ϵ , H53 η , and H54 η ), to determine the electron temperature and study ionized gas kinematics in the region, and the 3 mm free–free continuum emission to determine the physical parameters: the size, emission measure, and electron density. We compare the physical properties of N 105–1 A to a large sample of Galactic compact and ultracompact (UC) H ii regions and conclude that N 105–1 A is similar to the most luminous ( L > 10 ^5 L _⊙ ) UC H ii regions in the Galaxy. N 105–1 A is ionized by an O5.5 V star; it is deeply embedded in its natal molecular clump, and likely associated with a (proto)cluster. We incorporate high-resolution molecular line data including CS, SO, SO _2 , and CH _3 OH (∼0.12 pc), and HCO ^+ and CO (∼0.087 pc) to explore the molecular environment of N 105–1 A. Based on the CO data, we find evidence for a cloud–cloud collision that likely triggered star formation in the region. We find no clear outflow signatures, but the presence of filaments and streamers indicates ongoing accretion onto the clump hosting the UC H ii region. Sulfur chemistry in N 105–1 A is consistent with the accretion shock model predictions.

The role of massive (≥ 8 |$\, {\rm M}_{\odot }$|⁠) stars in defining the energy budget and chemical enrichment of the interstellar medium in their host galaxy is significant. In this first paper from the Tracing Evolution in Massive Protostellar Objects (TEMPO) project we introduce a colour-luminosity selected (L* ∼ 3 × 103 to 1 × 105 L⊙) sample of 38 massive star-forming regions observed with ALMA at 1.3 mm and explore the fragmentation, clustering, and flux density properties of the sample. The TEMPO sample fields are each found to contain multiple fragments (between 2 and 15 per field). The flux density budget is split evenly (53 per cent–47 per cent) between fields where emission is dominated by a single high flux density fragment and those in which the combined flux density of fainter objects dominates. The fragmentation scales observed in most fields are not comparable with the thermal Jeans length, λ J , being larger in the majority of cases, suggestive of some non-thermal mechanism. A tentative evolutionary trend is seen between luminosity of the clump and the 'spectral line richness' of the TEMPO fields; with 6.7 GHz maser associated fields found to be lower luminosity and more line rich. This work also describes a method of line-free continuum channel selection within ALMA data and a generalized approach used to distinguishing sources which are potentially star-forming from those which are not, utilizing interferometric visibility properties. [ABSTRACT FROM AUTHOR]

Aims. We aim to investigate the chemistry of internal photon-dominated regions (PDRs) surrounding deeply embedded hypercompact (HC) and ultracompact (UC) HII regions. We search for specific tracers of this evolutionary stage of massive star formation that can be detected with current astronomical facilities. Methods. We modeled hot cores with embedded HC/UCHII regions (called HII region models in the article despite the fact that we do not model the HII region itself), by coupling the astrochemical code Saptarsy to a radiative transfer framework obtaining the spatio-temporal evolution of abundances as well as time-dependent synthetic spectra. In these models where we focused on the internal PDR surrounding the HII region, the gas temperature is set to the dust temperature and we do not include dynamics thus the density structure is fixed. We compared this to hot molecular core (HMC) models and studied the effect on the chemistry of the radiation field which is included in the HII region models only during the computation of abundances. In addition, we investigated the chemical evolution of the gas surrounding HII regions with models of different densities at the ionization front, different sizes of the ionized cavity and different initial abundances. Results. We obtain the time evolution of synthetic spectra for a dozen of selected species as well as ratios of their integrated intensities. We find that some molecules such as C, N2H+, CN, and HCO do not trace the inner core and so are not good tracers to distinguish the HII/PDR regions to the HMCs phase. On the contrary, C+ and O trace the internal PDRs, in the two models starting with different initial abundances, but are unfortunately currently unobservable with the current achievable spatial resolution because of the very thin internal PDR (Δ rPDR < 100 AU). The emission of these two tracers is very dependent on the size of the HII region and on the density in the PDR. In addition, we find that the abundance profiles are highly affected by the choice of the initial abundances, hence the importance to properly define them. [ABSTRACT FROM AUTHOR]

The formation of high-mass stars is one of the major topics of astrophysical research, in particular the process of accretion from largescale clouds down to small-scale cores. We have selected the nearby, filamentary, high-mass star forming complex NGC6334 to study the gas velocity at different scales and probe the infall rates onto the protostellar cores embedded in the NGC6334-I and I(N) clusters. This study makes use of single-dish and interferometric submillimeter observations, complemented with 3D numerical non-LTE radiative transfer modeling. We measure a mass accretion rate of 10-5Mʘ yr-1 throughout the filament increasing up to 10-3Mʘ yr-1 towards the densest regions where high-mass stars are forming. At smaller scales, our 3D model is consistent with accretion rates of 10-3Mʘ yr-1 towards the clusters, and 10-4Mʘ yr-1 onto the protostars. [ABSTRACT FROM AUTHOR]

A review on current theories and observations of high-mass star formation is given. Particularly the influence of magnetic fields and feedback mechanisms, and of varying initial conditions on theories are discussed. The, in my biased view, most important observations to put strong constraints on models of high-mass star formation are presented, in particular bearing on the existence and properties of highmass starless cores, the role of filaments in the mass transport to highmass cores, and the properties of disks around high-mass stars. [ABSTRACT FROM AUTHOR]

CCAT is a 25 meter submm telescope proposed to be built at 5600 meters elevation on Cerro Chajnantor overlooking the ALMA site in northern Chile. The CCAT site is the best submm site that is accessible by truck, so that with its large aperture, exceptionally good surface accuracy (~17 µm rms total wavefront error, WFE), state-of-theart instrumentation and large (≥20 arcmin) field-of-view (FoV) CCAT will deliver unsurpassed point source sensitivity and mapping speeds across the submm telluric windows. Our primary science goals are: (1) to trace the obscurred star formation (SF) history of the Universe through multicolor submm surveys of 100's deg² on the sky followed up by spectroscopy to characterize the energy sources in dusty SF galaxies; (2) to measure and characterize the SF process in the Milky Way galaxy and nearby resolved galaxies through submm spectroscopic and dust continuum surveys; and (3) to probe galaxy cluster astrophysics through the Sunyaev-Zeldovich (SZ) effect. [ABSTRACT FROM AUTHOR]

We have observed five sulphur-bearing molecules in foreground diffuse molecular clouds lying along the sight-lines to five bright continuum sources. We have used the GREAT instrument on SOFIA to observe the SH 1383 GHz 2Π3/2 ← = 5/2 = 3/2 lambda doublet toward the star-forming regions W31C, G29.96-0.02, G34.3+0.1, W49N and W51, detecting foreground absorption towards all five sources; and the EMIR receivers on the IRAM 30 m telescope at Pico Veleta to detect the H2S 110-101 (169 GHz), CS J = 2-1 (98 GHz) and SO 32-21 (99 GHz) transitions. Upper limits on the H3S+ 10-00 (293 GHz) transition were also obtained at the IRAM 30 m. In nine foreground absorption components detected towards these sources, the inferred column densities of the four detected molecules showed relatively constant ratios, with N(SH)/N(H2S) in the range 1.1-3.0, N(CS)/N(H2S) in the range 0.32-0.61, and N(SO)/N(H2S) in the range 0.08-0.30. The column densities of the sulphur-bearing molecules are very well correlated amongst themselves, moderately well correlated with CH (a surrogate tracer for H2), and poorly correlated with atomic hydrogen. The observed SH/H2 ratios - in the range 5 to 26 × 10-9 - indicate that SH (and other sulphur-bearing molecules) account for «1% of the gas-phase sulphur nuclei. The observed abundances of sulphur-bearing molecules, however, greatly exceed those predicted by standard models of cold diffuse molecular clouds, providing further evidence for the enhancement of endothermic reaction rates by elevated temperatures or ion-neutral drift. We have considered the observed abundance ratios in the context of shock and turbulent dissipation region (TDR) models. Using the TDR model, we find that the turbulent energy available at large scale in the diffuse ISM is sufficient to explain the observed column densities of SH and CS. Standard shock and TDR models, however, fail to reproduce the column densities of H2S and SO by a factor of about 10; more elaborate shock models - in which account is taken of the velocity drift, relative to H2, of SH molecules produced by the dissociative recombination of H3S+ - reduce this discrepancy to a factor ~3. [ABSTRACT FROM AUTHOR]

Context. Hot molecular cores (HMCs) are intermediate stages of high-mass star formation and are also known for their rich chemical reservoirs and emission line spectra at (sub-)mm wavebands. Complex organic molecules (COMs) such as methanol (CH3OH), ethanol (C2H5OH), dimethyl ether (CH3OCH3), and methyl formate (HCOOCH3) produce most of these observed lines. The observed spectral feature of HMCs such as total number of emission lines and associated line intensities are also found to vary with evolutionary stages. Aims. We aim to investigate the spectral evolution of these COMs to explore the initial evolutionary stages of high-mass star formation including HMCs. Methods. We developed various 3D models for HMCs guided by the evolutionary scenarios proposed by recent empirical and modeling studies. We then investigated the spatio-temporal variation of temperature and molecular abundances in HMCs by consistently coupling gas-grain chemical evolution with radiative transfer calculations. We explored the effects of varying physical conditions on molecular abundances including density distribution and luminosity evolution of the central protostar(s) among other parameters. Finally, we simulated the synthetic spectra for these models at different evolutionary timescales to compare with observations. Results. Temperature has a profound effect on the formation of COMs through the depletion and diffusion on grain surface to desorption and further gas-phase processing. The time-dependent temperature structure of the hot core models provides a realistic framework for investigating the spatial variation of ice mantle evaporation as a function of evolutionary timescales. We find that a slightly higher value (15 K) than the canonical dark cloud temperature (10 K) provides a more productive environment for COM formation on grain surface. With increasing protostellar luminosity, the water ice evaporation font (~100 K) expands and the spatial distribution of gas phase abundances of these COMs also spreads out. We calculated the temporal variation of the radial profiles of these COMs for different hot core models. These profiles resemble the so-called jump profiles with relative abundances higher than 10-9 within the evaporation font will furthermore be useful to model the observed spectra of hot cores. We present the simulated spectra of these COMs for different hot core models at various evolutionary timescales. A qualitative comparison of the simulated and observed spectra suggests that these self-consistent hot core models can reproduce the notable trends in hot core spectral variation within the typical hot core timescales of 105 year. These models predict that the spatial distribution of various emission line maps will also expand with evolutionary time; this feature can be used to constrain the relative desorption energies of the molecules that mainly form on the grain surface and return to the gas phase via thermal desorption. The detailed modeling of the thermal structure of hot cores with similar masses along with the characterization of the desorption energies of different molecules can be used to constrain the luminosity evolution of the central protostars. The model predictions can be compared with high resolution observation that can probe scales of a few thousand AU in high-mass star forming regions such as from Atacama Large Millimeter/submillimeter Array (ALMA). We used a spectral fitting method to analyze the simulated spectra and find that it significantly underestimates some of the physical parameters such as temperature. The coupling of chemical evolution with radiative transfer models will be particularly useful to decipher the physical structure of hot cores and also to constrain the initial evolutionary stages of high-mass star formation. [ABSTRACT FROM AUTHOR]

Context. How molecular clouds form out of the atomic phase and what the relative fractions of carbon are in the ionized, atomic, and molecular phase are questions at the heart of cloud and star formation. Aims. We want to understand the kinematic processes of gas flows during the formation of molecular clouds. In addition to that, we aim at determining the abundance ratios of carbon in its various gas phases from the ionized to the molecular form. Methods. Using multiple observatories from Herschel and SOFIA to APEX and the IRAM 30m telescope, we mapped the ionized and atomic carbon as well as carbon monoxide ([CII] at 1900 GHz, [CI] at 492 GHz, and C18O(2-1) at 220 GHz) at high spatial resolution (12"-25") in four young massive infrared dark clouds (IRDCs). Results. The three carbon phases were successfully mapped in all four regions, only in one source does the [CII] line remain a nondetection. With these data, we dissect the spatial and kinematic structure of the four IRDCs and determine the abundances of gas phase carbon in its ionized, atomic, and most abundant molecular form (CO). Both the molecular and atomic phases trace the dense structures well, with [CI] also tracing material at lower column densities. [CII] exhibits diverse morphologies in our sample from compact to diffuse structures, probing the cloud environment. In at least two out of the four regions, we find kinematic signatures strongly indicating that the dense gas filaments have formed out of a dynamically active and turbulent atomic and molecular cloud, potentially from converging gas flows. The atomic carbon-to-CO gas mass ratios are low between 7% and 12% with the lowest values found toward the most quiescent region. In the three regions where [CII] is detected, its mass is always higher by a factor of a few than that of the atomic carbon. While the ionized carbon emission depends on the radiation field, we also find additional signatures that indicate that other processes, for example, energetic gas flows can contribute to the [CII] excitation as well. Conclusions. Combining high-resolution maps in the different carbon phases reveals the dynamic interplay of the various phases of the interstellar medium during cloud formation. Extending these studies to more evolved stages and combining the observations with molecular cloud formation simulations including the chemistry and radiative transfer will significantly improve our understanding of the general interstellar medium, cloud, and star formation processes. [ABSTRACT FROM AUTHOR]

Context. Star formation effciency (SFE) theories are currently based on statistical distributions of turbulent cloud structures and a simple model of star formation from cores. They remain poorly tested, especially at the highest densities. Aims. We investigate the effects of gas density on the SFE through measurements of the core formation effciency (CFE). With a total mass of ∼2 × 104 M☉ the W43-MM1 ridge is one of the most convincing candidate precursors of Galactic starburst clusters and thus one of the best places to investigate star formation. Methods. We used high-angular resolution maps obtained at 3 mm and 1 mm within the W43-MM1 ridge with the IRAM Plateau de Bure Interferometer to reveal a cluster of 11 massive dense cores, and, one of the most massive protostellar cores known. A Herschel column density image provided the mass distribution of the cloud gas. We then measured the "instantaneous" CFE and estimated the SFE and the star formation rate (SFR) within subregions of the W43-MM1 ridge. Results. The high SFE found in the ridge (∼6% enclosed in ∼8 pc3) confirms its ability to form a starburst cluster. There is, however, a clear lack of dense cores in the eastern part of the ridge, which may be currently assembling. The CFE and the SFE are observed to increase with volume gas density, while the SFR per free fall time steeply decreases with the virial parameter, αvir. Statistical models of the SFR may describe the outskirts of the W43-MM1 ridge well, but struggle to reproduce its inner part, which corresponds to measurements at low αvir. It may be that ridges do not follow the log-normal density distribution, Larson relations, and stationary conditions forced in the statistical SFR models. [ABSTRACT FROM AUTHOR]

We investigate the physical and chemical processes at work during the formation of a massive protostar based on the observation of water in an outflow from a very young object previously detected in H2 and SiO in the IRAS 17233-3606 region. We estimated the abundance of water to understand its chemistry, and to constrain the mass of the emitting outflow. We present new observations of shocked water obtained with the HIFI receiver onboard Herschel. We detected water at high velocities in a range similar to SiO. We self-consistently fitted these observations along with previous SiO data through a state-of-the-art, one-dimensional, stationary C-shock model. We found that a single model can explain the SiO and H2O emission in the red and blue wings of the spectra. Remarkably, one common area, similar to that found for H2 emission, fits both the SiO and H2O emission regions. This shock model subsequently allowed us to assess the shocked water column density, NH2O = 1.2 × 1018 cm-2, mass, MH2O = 12.5 M⊕, and its maximum fractional abundance with respect to the total density, xH2O = 1.4 × 10-4. The corresponding water abundance in fractional column density units ranges between 2.5×10-5 and 1.2×10-5, in agreement with recent results obtained in outflows from low- and high-mass young stellar objects. [ABSTRACT FROM AUTHOR]

The formation of high-mass stars is tightly linked to that of their parental clouds. Here, we focus on the high-density parts of W43, a molecular cloud undergoing an efficient event of star formation. Using a column density image derived from Herschel continuum maps, we identify two high-density filamentary clouds, called the W43-MM1 and W43-MM2 ridges. Both have gas masses of 2.1 × 104M☼ and 3.5 × 104M☼ above >10 and within areas of ∼6 and ∼14 pc2, respectively. The W43-MM1 and W43-MM2 ridges are structures that are coherent in velocity and gravitationally bound, despite their large velocity dispersion measured by the N2H+ (1-0) lines of the W43-HERO IRAM large program. Another intriguing result is that these ridges harbor widespread (∼10 pc2) bright SiO (2-1) emission, which we interpret to be the result of low-velocity shocks (⩽10 km s–1). We measure a significant relationship between the SiO (2-1) luminosity and velocity extent and show that it distinguishes our observations from the high-velocity shocks associated with outflows. We use state-of-the-art shock models to demonstrate that a small percentage (10%) of Si atoms in low-velocity shocks, observed initially in gas phase or in grain mantles, can explain the observed SiO column density in the W43 ridges. The spatial and velocity overlaps between the ridges of high-density gas and the shocked SiO gas suggest that ridges could be forming via colliding flows driven by gravity and accompanied by low-velocity shocks. This mechanism may be the initial conditions for the formation of young massive clusters. [ABSTRACT FROM AUTHOR]

Context. One of the big questions in astrochemistry is whether complex organic molecules are formed in the gas phase after evaporation of the icy mantles of interstellar dust grains or at intermediate temperatures within these icy mantles. Dimethyl ether (CH3OCH3) is one of these species that may form through either of these mechanisms, but it is yet unclear which is dominant. Aims. The goal of this paper is to determine the respective importance of solid state vs. gas phase reactions for the formation of dimethyl ether. This is done by a detailed analysis of the excitation properties of the ground state and the torsionally excited states, v11 = 1 and v15 = 1, toward the high-mass star-forming region G327.3-0.6. Methods. With the Atacama Pathfinder EXperiment 12 m submillimeter telescope, we performed a spectral line survey toward G327.3-0.6 around 1.3, 1.0, and 0.9 mm as well as at 0.43 and 0.37 mm. The observed CH3OCH3 spectrum is modeled assuming local thermal equilibrium. Results. CH3OCH3 has been detected in the ground state, v= 0, and in the torsionally excited states v11 = 1 and v15 = 1, for which lines have been detected here for the first time. The emission is modeled with an isothermal source structure as well as with a non-uniform spherical structure. In the isothermal case two components at 80 and 100 K are needed to reproduce the dimethyl ether emission, whereas an abundance jump at 85 K or a model with two abundance jumps at 70 and 100 K fit the emission equally well for the non-uniform source model. The emission from the torsionally excited states, v11 = 1 and v15 = 1, is very well fit by the same model as the ground state. Conclusions. For non-uniform source models one abundance jump for dimethyl ether is sufficient to fit the emission, but two components are needed for the isothermal models. This suggests that dimethyl ether is present in an extended region of the envelope and traces a non-uniform density and temperature structure. Both types of models furthermore suggest that most dimethyl ether is present in gas that is warmer than 100 K, but a smaller fraction of 5%-28% is present at temperatures between 70 and 100 K. The dimethyl ether present in this cooler gas is likely formed in the solid state, while gas phase formation probably is dominant above 100 K. Finally, the v11 = 1 and v15 = 1 torsionally excited states are easily excited under the density and temperature conditions in G327.3-0.6 and will thus very likely be detectable in other hot cores as well. [ABSTRACT FROM AUTHOR]

Context. The APEX Telescope Large Area Survey of the GALaxy (ATLASGAL) is the first systematic survey of the inner Galactic plane in the sub-millimetre. The observations were carried out with the Large APEX Bolometer Camera (LABOCA), an array of 295 bolometers observing at 870 μm (345 GHz). Aims. Here we present a first version of the compact source catalogue extracted from this survey. This catalogue provides an unbiased database of dusty clumps in the inner Galaxy. Methods. The construction of this catalogue was made using the source extraction routine SExtractor. We have cross-associated the obtained sources with the IRAS and MSX catalogues, in order to constrain their nature. Results. We have detected 6639 compact sources in the range from 330 ≤ ℓ ≤ 21 degrees and ∣b∣ ≤ 1.5 degrees. The catalogue has a 99% completeness for sources with a peak flux above 6σ, which corresponds to a flux density of ∼0.4 Jy beam-1. The parameters extracted for sources with peak fluxes below the 6σ completeness threshold should be used with caution. Tests on simulated data find the uncertainty in the flux measurement to be ∼12%, however, in more complex regions the flux values can be overestimated by a factor of 2 due to the additional background emission. Using a search radius of 30″ we found that 40% of ATLASGAL compact sources are associated with an IRAS or MSX point source, but, ∼50% are found to be associated with MSX 21 μm fluxes above the local background level, which is probably a lower limit to the actual number of sources associated with star formation. Conclusions. Although infrared emission is found towards the majority of the clumps detected, this catalogue is still likely to include a significant number of clumps that are devoid of star formation activity and therefore excellent candidates for objects in the coldest, earliest stages of (high-mass) star formation. [ABSTRACT FROM AUTHOR]

Using the Mopra telescope, we have undertaken a 3-mm spectral-line imaging survey of a 5 × 5 arcmin2 area around Sgr B2. We covered almost the complete spectral range from 81.7 to 113.5 GHz, with 2.2 MHz wide spectral channels or and have observed 24 lines, with 0.033 MHz wide, or channels. We discuss the distribution of around 50 lines, and present velocity-integrated emission images for 38 of the lines. In addition, we have detected around 120 more lines, mostly concentrated at the particularly spectral-line-rich Sgr B2(N) source. There are significant differences in molecular emission, pointing to both abundance and excitation differences throughout the region. Seven distinct spatial locations are identified for the emitting species, including peaks near the prominent star-forming cores of Sgr B2(N), (M) and (S) that are seen in infrared (IR)-to-radio continuum images. The other features are a ‘north ridge’ and a ‘north cloud’ to the north of the Sgr B2 N-M-S cores, a ‘south-east peak’ and a ‘west ridge’. The column density, as evident through C18O, peaks at the Sgr B2(N) and (M) cores, where strong absorption is also evident in otherwise generally bright lines such as HCO+, HCN and HNC. Most molecules trace a ridge line to the west of the Sgr B2 N-M-S cores, wrapping around the cores and extending north-east to the north cloud. This is most clearly evident in the species HC3N, CH3CN, CH3OH and OCS. They are found to be closer in distribution to the cooler dust traced by the submillimetre continuum than either the warmer dust seen in the mid-IR or to the radio continuum. The molecule CN, in contrast, is reasonably uniform over the entire region mapped, aside from strong absorption at the positions of the Sgr B2(N) and (M) cores. [ABSTRACT FROM AUTHOR]