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Speleothems (cave stalagmites) contain inorganic and organic substances that can be used to infer past changes in local and regional paleoenvironmental conditions. Specific biomarkers can be employed to elucidate the history of past fires, caused by interactions among climate, regional hydrology, vegetation, humans, and fire activity. We conducted a simple solid–liquid extraction on pulverised carbonate samples to prepare them for analysis of 16 polycyclic aromatic hydrocarbons (PAHs) and three monosaccharide anhydrides (MAs). The preparation method requires only small samples (0.5–1.0 g); PAHs and MAs were measured by GC–MS and LC–HILIC–MS, respectively. Detection limits range from 0.05–2.1 ng for PAHs and 0.01–0.1 ng for MAs. We applied the method to 10 samples from a ∼ 400-year-old stalagmite from Cenote Ch'en Mul, at Mayapan (Mexico), the largest Postclassic Maya capital of the Yucatán Peninsula. We found a strong correlation (r = 0.75, p < 0.05) between the major MA (levoglucosan) and non-alkylated PAHs (Σ 15). We investigated multiple diagnostic PAH and MA ratios and found that although not all were applicable as paleo-fire proxies, ratios that combine PAHs with MAs are promising tools for identifying different fire regimes and inferring the type of fuel burned. In the 1950s and 1960s, levoglucosan and Σ 15 concentrations roughly doubled compared to other times in the last 400 years, suggesting greater fire activity at Mayapan during these two decades. The higher concentrations of fire markers may have been a consequence of land clearance at the site and exploration of the cave by Carnegie Institution archaeologists. [ABSTRACT FROM AUTHOR]

Speleothem initial uranium isotope ratios ((234U/238U)i) can be influenced by processes along the seepage water flow‐path including alpha‐recoil into porewater during 238U decay and hostrock weathering, the balance of which can reflect the infiltration rate. Thus, speleothem (234U/238U)i may provide information about past changes in rainfall amounts. However, the utility of (234U/238U)i as a paleo‐infiltration proxy has only been explored in a limited set of rainfall regimes. We present a speleothem (234U/238U)i record from Mawmluh Cave in northeast India, an area influenced by the Indian Summer Monsoon, covering 1964–2012 CE. Speleothem (234U/238U)i was relatively constant from 1964 to 1984 but then linearly increased by 0.05 over ∼15 years, a trend that does not correspond with observed rainfall changes. To evaluate potential drivers of (234U/238U)i variability, we model the evolution of water (234U/238U) in a simple karst system using an advection‐reaction model parameterized by Mawmluh Cave variables. Although varying infiltration influences modeled water (234U/238U), the larger, sustained change observed in the speleothem record can only be modeled by varying the U concentration and (234U/238U) of the weathering hostrock. This suggests that larger shifts in speleothem (234U/238U)i may result from flow path changes, bringing waters in contact with hostrock of variable U characteristics. Consideration of published Mawmluh Cave records suggests that these mechanisms may also explain variability in stalagmite (234U/238U)i on precessional timescales. Further examination of speleothems (234U/238U)i from climates characterized by high rainfall and extensive weathering is warranted to better constrain the controls on (234U/238U)i in these dynamic environments. Plain Language Summary: Chemical indicators from stalagmites are useful in reconstructing changes in monsoon systems. However, the chemical measurements typically made on stalagmites do not provide direct reconstructions of rainfall amount. We developed a record of uranium isotope variability over the last 60 years in a stalagmite from Northeast India to evaluate this potential metric of past monsoon rainfall. We use a geochemical model to evaluate the climatic and environmental controls on uranium isotopes in cave drip waters and stalagmites. Comparison of our record with measured rainfall indicates that the relationship between rainfall amount and uranium isotope ratios is opposite to that observed in arid environments. Further, a large linear increase in uranium isotopes between ∼1985 and 2000 CE does not correspond to a change in rainfall. Rather, our model suggests that large changes in uranium isotopes likely result from the opening up of new water flow paths and the dissolution of fresh hostrocks. Investigation of previously analyzed stalagmites from the cave reveals a correspondence between uranium isotopes and insolation, suggesting that sustained changes in rainfall amount, coupled with opening of new flow paths, may be recorded in stalagmite uranium isotopes over the past ∼100,000 years. Key Points: Modern record of speleothem initial uranium isotope ratios from NE India shows a linear increase that does not correspond to rainfallGeochemical model shows that dripwater U isotopes respond to changing infiltration and changing U characteristics of weathering rockLong‐term variations in speleothem U isotope ratios from NE India record infiltration with additional control of changes in flow path [ABSTRACT FROM AUTHOR]

Recent wildfire activity in semi-arid regions like western North America exceeds the range of historical records. High-resolution paleoclimate archives such as stalagmites could illuminate the link between hydroclimate, vegetation change, and fire activity in pre-anthropogenic climate states beyond the timescale of existing tree-ring records. Here we present an analysis of levoglucosan, a combustion-sensitive anhydrosugar, and lignin oxidation products (LOPs) in a stalagmite, reconstructing fire activity and vegetation composition in the California Coast Range across the 8.2 kyr event. Elevated levoglucosan concentrations suggest increased fire activity while altered LOP compositions indicate a shift toward more woody vegetation during the event. These changes are concurrent with increased hydroclimate volatility as shown by carbon and calcium isotope proxies. Together, these records suggest that climate whiplash (oscillations between extreme wetness and aridity) and fire activity in California, both projected to increase with anthropogenic climate change, were tightly coupled during the early Holocene. A California stalagmite records vegetation shifts and increased fire activity during the 8.2 kyr event. These changes occur alongside oscillations between wet and dry extremes suggesting tight coupling between climate whiplash and fire activity. [ABSTRACT FROM AUTHOR]

Close coupling of Iberian hydroclimate and North Atlantic sea surface temperature (SST) during recent glacial periods has been identified through the analysis of marine sediment and pollen grains co-deposited on the Portuguese continental margin. While offering precisely correlatable records, these time series have lacked a directly dated, site-specific record of continental Iberian climate spanning multiple glacial cycles as a point of comparison. Here we present a high-resolution, multi-proxy (growth dynamics and δ13C , δ18O , and δ234U values) composite stalagmite record of hydroclimate from two caves in western Portugal across the majority of the last two glacial cycles (∼220 ka). At orbital and millennial scales, stalagmite-based proxies for hydroclimate proxies covaried with SST, with elevated δ13C , δ18O , and δ234U values and/or growth hiatuses indicating reduced effective moisture coincident with periods of lowered SST during major ice-rafted debris events, in agreement with changes in palynological reconstructions of continental climate. While in many cases the Portuguese stalagmite record can be scaled to SST, in some intervals the magnitudes of stalagmite isotopic shifts, and possibly hydroclimate, appear to have been somewhat decoupled from SST. [ABSTRACT FROM AUTHOR]

The study of modern cave deposits forming under near isotopic equilibrium conditions can potentially help disentangle the processes influencing the oxygen isotope system and suitability of stalagmites as archives of past hydrological or thermal changes. We used cave monitoring to evaluate the impact of kinetic isotope fractionation and assess the conditions under which modern cave carbonates form in the Caumont cave and quarry system, located in Normandy, northwest France. Over 20 months, we collected climatological data, dripwater, and modern carbonate samples at 2–4-week intervals at three different stations inside the Caumont cave and quarry system. We find highly stable (10.4 ± 0.3°C – 11.3 ± 0.1°C) temperature in the deeper sections of the Caumont cave and quarry system. The temporal dynamics of δ18Odrip indicates that the drip water composition in Caumont reflects the original (though subdued) signal of precipitation, rather than the impact the seasonal to inter-annual cave air temperature has on isotopic fractionation. The monitoring reveals that δ13C of modern carbonate is influenced by prior carbonate precipitation that occurs during the summer season when evapotranspiration can minimize effective infiltration. Comparison of δ18O from dripwater and modern calcite, precipitated on glass plates and collected every two to four weeks, reveals that modern calcite forms near oxygen isotope equilibrium. A Hendy test on modern carbonate deposited on a stalagmite-shaped glass flask over 20 months confirms this finding because neither does δ13C increase with distance from the apex, nor are δ13C and δ18O positively correlated. We conclude that the δ13C signal in speleothems reflect summer (and longer-term) prior carbonate precipitation in response to effective infiltration dynamics, and that the δ18O signal likely reflects annual to multi-annual changes in the composition of precipitation above the cave. [ABSTRACT FROM AUTHOR]

The nature of cave ventilation is of interest to cavers, speleologists, and paleoclimatologists working with stalagmites. Because cave ventilation systematics may change over the growth span of a stalagmite, understanding what factors affect them is critical for determining events that may have affected climate proxies within the stalagmite. Similarly, understanding how the hydrology of the drips feeding a stalagmite evolves through time is key to building robust records of paleoclimate, particularly because stalagmite records have become critical archives of climate change information of the last 500,000 years. Here we present data from an extensive, on-going monitoring effort at Yok Balum Cave, Belize, initiated in 2011, that characterizes high-resolution ventilation dynamics at this site. Clear seasonal ventilation regimes exist, driven by thermally induced inside-outside air density differences. The winter regime is dominated by air inflow into the cave, decreased drawdown from the epikarst into the cave, and a limited diurnal signal. Conversely, summer ventilation is dominated by air outflow from the cave, greater CO2 drawdown and drip water degassing, and a strong diurnal signal. Active monitoring during a large (M7.4) earthquake in November 2012 provides a unique opportunity to assess the response of the cave atmosphere and hydrology to substantial seismic activity. Cave atmosphere dynamics and hydrology are found to be highly resilient to seismic activity, with no observable disturbance occurring around the earthquake, despite there being considerable evidence of physical disruption in the cave. Monitoring included different kinds of drips, and the earthquake affected none of the monitored drip types. This suggests that stalagmite-derived paleoclimate records are not affected by seismic activity, except in extreme cases where the stalagmite or conjugate stalactite is damaged or reoriented. [ABSTRACT FROM AUTHOR]