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1. Enhanced H2 Uptake in Solvents Confined in Mesoporous Metal—Organic Framework.

Author

Clauzier, Stephanie, Linh Ngoc Ho, Pera-Titus, Marc, Coasne, Benoit, and Farrusseng, David

Subjects
*MESOPOROUS materials, *METAL-organic frameworks, *SOLVENTS, *HYDROGEN, *SORBENTS, *HEXANE, *SOLUBILITY, *SURFACE chemistry
Abstract

Hydrogen uptake at 298 K and 30 bar in hybrid sorbents consisting of n-hexane confined in MIL-101 is found to be 22 times larger than in sole n-hexane. The enhanced solubility in MIL-101, found to be 3 times larger than in mesoporous silica of similar pore size, highlights the key roles played by surface chemistry and accessible surface area. [ABSTRACT FROM AUTHOR]

Published
2012
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