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Measurements of broadband downward longwave (LW) irradiance are carried out at Lampedusa, Italy, in the Mediterranean, jointly with solar irradiance, since 2004 using shaded and unshaded Eppley Precision Infrared Radiometers (PIRs) and Kipp & Zonen CGR4 pyrgeometers. The calibrations of the different pyrgeometers are traceable to the Physikalisch-Meteorologisches Observatorium Davos World Radiation Center (PMOD/WRC). Nighttime measurements from intercalibrated pyrgeometers agree within ±2 W m−2. The performance of the pyrgeometers when operated unshaded has been analyzed by comparison with shaded instruments. For the PIR, the nonhomogeneous dome temperature in cloud-free conditions produces differences in LW irradiance within ±4 W m−2, depending on the time of the day and the season. The effect of the LW fraction of solar radiation reaching the sensor and a possible shortwave leakage of the dome interference filter produces differences between shaded and unshaded pyrgeometers during daytime. In cloud-free conditions, the unshaded PIR overestimates the LW irradiance measured by a shaded PIR by up to 10 W m−2, and by up to 12 W m−2 compared to a shaded CGR4. Conversely, the unshaded CGR4 LW irradiances agree with those of a shaded PIR within the measurements' uncertainties. An empirical formula to correct the solar effect of the PIR has been derived. Applying this correction, the average LW irradiance overestimate for cloud-free conditions decreases from 3.8 ± 1.8 to 0.0 ± 1.3 W m−2 in spring, and from 3.2 ± 1.7 to 0.0 ± 1.3 W m−2 in summer. Thus, LW irradiance from an unshaded PIR can be derived within about ±2 W m−2 of a shaded PIR. [ABSTRACT FROM AUTHOR]

Geostationary observations offer the unique opportunity to resolve the diurnal cycle of the Earth's Radiation Budget at the top of the atmosphere (TOA), crucial for climate-change studies. However, a drawback of the continuous temporal coverage of the geostationary orbit is the fixed viewing geometry. As a consequence, imperfections in the angular distribution models (ADMs) used in the radiance-to-flux conversion process or residual angular-dependent narrowband-to-broadband conversion errors can result in systematic errors of the estimated radiative fluxes. In this work, focusing on clear-sky reflected TOA observations, we compare the overlapping views from Meteosat Second Generation satellites at 0° and 41.5 °E longitude which enable a quantification of viewing-angle-dependent differences. Using data derived from the Spinning Enhanced Visible and InfraRed Imager (SEVIRI), we identify some of the main sources of discrepancies, and show that they can be significantly reduced at the level of one month. This is achieved, separately for each satellite, via a masking procedure followed by an empirical fit at the pixel-level that takes into account all the clear-sky data from that satellite, calculated separately per timeslot of the day, over the month of November 2016. The method is then applied to each month of 2017, and gives a quadratic mean of the albedo root-mean squared difference over the dual-view region which is comparable from month to month, with a 2017 average value of 0.01. Sources of discrepancies include the difficulty to estimate the flux over the sunglint ocean region close to the limbs, the fact that the data processing does not include dedicated angular distribution models for the aerosol-over-ocean case, and the existence of an observer-dependent diurnal-asymmetry artefact affecting the clear-sky-albedo dependence on the solar zenith angle particularly over land areas. [ABSTRACT FROM AUTHOR]

Abstract: Measurements of UV spectra, total ozone, cloud cover, and cloud optical thickness, obtained at Lampedusa (central Mediterranean), are used to investigate the influence of clouds on the spectral UV irradiance, through the cloud modification factor (CMF), and on five biological processes. The CMF decreases with cloud optical thickness (COT), from about 0.5 for COT∼15 to 0.25 for COT∼45, and decreases with increasing wavelength above 315–320-nm. Observations display an increase in the CMF from 295 to 320-nm, which is related to enhanced absorption by tropospheric ozone due to the long photon path lengths under cloudy conditions. The use of a wavelength independent CMF instead of the experimentally determined spectral curves produces an overestimation of the biological effects of UV irradiance. The overestimation may be as large as 30% for the DNA damage, 20% for vitamin D synthesis, 12% for plant damage, and 8–10% for phytoplankton inhibition and erythema. [Copyright &y& Elsevier]