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To prove the hypothesis that paddy rice utilizes soil nonexchangeable potassium (neK) and causes associated structural changes in clay minerals, K status and clay mineralogy of 22 surface soils from three paddy fields under long‐term fertilizer management for 51–93 years were investigated. Soil neK content was determined as the difference between 1 mol L−1 hot HNO3 extractable K and 1 mol L−1 ammonium acetate exchangeable K. Clay mineralogy was identified by X‐ray diffraction (XRD). The radiocesium interception potential (RIP), an index of frayed edge sites in the interlayer sites of 2:1 type clay minerals, was also determined. The neK contents under the ‐K and NPK treatments were considerably lower than those under the unfertilized treatment in all the fields, indicating the exploitation of soil neK by rice. XRD analysis of the clay samples revealed 7% shift from the 1.0 peak to 1.4 nm one under the ‐K treatment compared with the unfertilized one, and the amounts of neK were negatively correlated with those of RIP (p <.01), suggesting the expansion of interlayer spaces of the 2:1 type phyllosilicates such as mica due to the release of neK. In addition, the neK content positively correlated with K balance of the long‐term experiments (p <.05). The differences of neK between unfertilized K and ‐K treatments corresponded to 22–157 kg K ha−1, or 0.42–1.68 kg K ha−1 year−1. In conclusion, utilization of considerable amount of soil neK under K depleted conditions should be considered to establish sustainable K management for paddy rice. [ABSTRACT FROM AUTHOR]

Potassium (K) and radiocaesium (RCs) were chemically extracted from soils derived from granite (G soils) and sedimentary rock (S soils) in Fukushima, Japan. The extractants employed were 1 M HNO3, concentrated HNO3, and HF + HClO4. As S soils contain a lower amount of trioctahedral 2:1 phyllosilicates than G soils, the RCs/K ratio was higher in S soils than in G soils with 1 M HNO3 extraction, indicating that the potential risk of soil-to-plant transfer of RCs is higher in S soils than in G soils. In conclusion, information about surface geology is important in predicting the spatial pattern of soil characteristics related to transferability of RCs. [ABSTRACT FROM AUTHOR]

Radiocesium (RCs) is selectively adsorbed on interlayer sites of weathered micaceous minerals, which can reduce the mobility of RCs in soil. Therefore, soils developed from mica-deficient materials (e.g. serpentine soils) may have a higher risk of soil-to-plant transfer of RCs. Soils were collected from three serpentine soil profiles; Udepts in Oeyama, Japan, and Udepts and Udox in Kinabalu, Malaysia. Soil was sampled every 3 cm from 0 to 30 cm depth and sieved to isolate soil particles of ≤20 μm diameter for the assessment of radiocesium interception potential (RIP) after a series of pretreatments. One subset was treated with H 2 O 2 to remove organic matter (OM). Another subset was further treated with hot sodium citrate to remove hydroxy-Al polymers (Al(OH)x). RIP untreated was <0.4 mol kg−1 whereas mica-K content was <0.02% by weight for ≤20-μm soil particles from Udepts and Udox in Kinabalu, Malaysia, values as low as those of non-micaceous minerals (e.g. kaolinite and smectite). Neither OM nor Al(OH)x removal resulted in a large increase in RIP value for these soils. These results clearly indicated that serpentine soils in Malaysia have very few RCs selective adsorption sites due to the absence of micaceous minerals. In contrast, soil from Udepts in Oeyama, Japan showed average RIP untreated of 5.6 mol kg−1 and mica-K content of 0.72% by weight for the ≤20-μm particles. Furthermore, the RIP value was significantly increased to an average of 22.5 mol kg−1 after removing both OM and Al(OH)x. These results strongly suggest that weathered micaceous minerals primarily control the ability to retain RCs. These micaceous minerals cannot originate from serpentine minerals, and are probably incorporated as an exotic material, such as Asian dust. This hypothesis is supported by the δ18O value of quartz isolated from the ≤20-μm soil particles from Oeyama, Japan (+16.13‰±0.11‰), very similar to that of Asian dust. In conclusion, serpentine soils in Japan may exhibit a reduced risk of soil-to-plant transfer of RCs due to the historical deposition of Asian dust. • RCs adsorption capability is high in serpentine soils from Japan and low in those from Malaysia. • Mica and quartz levels in the ≤20-μm fraction are high in the serpentine soils from Japan. • The δ18O value of the ≤20-μm quartz from Japan was 16.13‰±0.11‰, very similar to that of Asian dust. • Asian dust deposition may primarily control RCs retention ability in serpentine soils. [ABSTRACT FROM AUTHOR]

To examine the exchangeability of 137Cs and K in soils of agricultural fields after decontamination, 173 soil samples were collected in 2016 from the plowed layer (0–15 cm depth) of decontaminated agricultural fields in Tomioka town, Fukushima prefecture, Japan. We investigated total 137Cs, exchangeable 137Cs, exchangeable K, and nonexchangeable K content for these soils. The total 137Cs content in soils was, on average, 1,200 Bq kg−1 (value range: 20–4,400 Bq kg−1), which was an 80% decrease from the values determined before the decontamination. This result indicated that the decontamination process considerably reduced the total 137Cs content in the plowed layer. The exchangeable K content in soils was on average 172 mg kg−1 (value range: 27.9 – 743 mg kg−1). More than 80% of soils showed the exchangeable K content lower than the recommended threshold value for paddy soils needed in order to reduce the 137Cs transfer from soil to plant (i.e. 200 mg kg−1). The nonexchangeable K content showed a wide range of values (value range: 98.8–1,280 mg kg−1) and no significant correlation with the exchangeable K content. Because nonexchangeable K is released more slowly but is comparable to exchangeable K as a reservoir of phytoavailable K, more frequent K application is recommended for soils with lower contents of both exchangeable and nonexchangeable K. The total 137Cs content in soils showed a significant positive correlation with the exchangeable K content in soils (p < 0.01), which means that decontamination efforts intended to reduce the total 137Cs content in soils might also lead to a reduction in the exchangeable K content. In conclusion, the application of K fertilizer is strongly recommended in the decontaminated agricultural fields because the decontamination causes a considerable decrease in exchangeable K content along with a reduction in total 137Cs content. [ABSTRACT FROM AUTHOR]

The nonexchangeable potassium (neK) content of 178 agricultural soils in Japan was determined by subtracting the amount of K extracted with 1 mol L−1ammonium acetate, i.e., exchangeable K (exK) from that extracted with boiling 1 mol L−1HNO3. The statistical relationships between the neK content and physico-chemical properties of the soils were examined to investigate the factors controlling neK content. The neK content of agricultural soils in Japan ranged from 0 to 1120 mg kg−1with an arithmetic mean and median of 303 and 255 mg kg−1, respectively. It showed a significant positive correlation with the total K content, fixed ammonium content, and silt content (p < 0.01) and a significant negative correlation with Alo+1/2 Feo content and total carbon content (p < 0.01). These results suggest that the controlling factors of neK are mainly the total K content and 2:1 type phyllosilicates such as mica and vermiculite, with the indirect negative influence of organic matter and amorphous materials. Terrestrial Regosols, Brown Lowland soils, and Dark Red soils had relatively high neK contents. In contrast, Andosols, Wet Andosols, and Volcanogenous Regosols had relatively low neK contents. The neK content showed no significant correlation with exK content, suggesting that neK is a moderately to slowly available fraction of soil K, which is independent of exK. In conclusion, evaluation of nonexchangeable K in combination with exchangeable K would enhance the rational management of agricultural soils in terms of K fertility by taking account of longer term K-supplying power of soils. [ABSTRACT FROM PUBLISHER]

Land use intensity in the Cameroon plateaus, where Ferralsols and the associated highly weathered soils are dominant, has been steadily increasing, so that soil fertility status and its controlling factors on these plateaus should be elucidated to establish long-term land management strategies. Although it is known that Ferralsols have small, but variable CEC values, it has not been fully determined which clay components are the main source of CEC clay in Ferralsols. Here, soils in three Cameroon plateau regions of different altitude (the lower South Cameroon (SC) Plateau with an altitude of 300–600 m, SC L ; the upper SC Plateau with an altitude of 600–900 m, SC H ; and the Adamawa Plateau with an altitude above 900 m, ADM) were collected, and their physicochemical and mineralogical properties were investigated. The relative abundance of illitic minerals, which are a minor but the most promising source of CEC clay in Ferralsols, was determined by using three indicators: the relative abundances of 1.0 nm-thick structures as represented by XRD peak intensity (XRD 1.0 nm ), structural K in illitic minerals as represented by clay-K content, and the quantity of intermediate interlayer sites between illite and vermiculite structures (i.e., frayed edge sites) as represented by the radiocesium interception potential (RIP). The relative abundances of two low-activity clay components, kaolinite and gibbsite, were determined by differential thermal analysis, and the degree of Al-substitution in goethite was determined by differential x-ray diffraction analysis. All three quantitative indicators for illitic minerals decreased along the altitude gradient, SC L > SC H > ADM, and were positively correlated with CEC clay . While kaolinite also showed a decreasing trend at higher altitude, it did not show any significant correlation with CEC clay . In contrast to the decrease in these Si-bearing minerals, gibbsite and Al-substituted goethite increased along the same altitude gradient. These associative changes strongly indicate that illitic minerals were the clay component largely controlling CEC clay and that de-silication or aluminization may proceed at higher altitude or on stable surfaces with older formation ages in the Cameroon plateau regions. Thus, mineralogical properties well explained the distribution of Ferralsols; they were marginal in the SC L region, while those with relatively high CEC clay were dominant in the SC H region and those with lower CEC clay were dominant in the ADM region. [ABSTRACT FROM AUTHOR]

To evaluate the content of nitrogen (N) fractions of agricultural soils in Java, Indonesia, in relation to soil type and land use, 46 surface soil samples, 23 from paddy and 23 from upland, were collected throughout Java to include various types of soils. Soil N was separated into four fractions according to form and availability: inorganic extractable nitrogen (Iex-N), fixed ammonium nitrogen (Ifix-N), organic mineralizable nitrogen (Omin-N) and organic stable nitrogen (Osta-N). The total-N content was determined by the dry combustion method. The Iex-N content was determined by extraction with a 2 mol L−1potassium chloride (KCl) solution and the Ifix-N content by extraction with an hydrofluoric and hydrochloric acid (HF-HCl) solution after removal of organic-N. The Omin-N content was evaluated as the potentially mineralizable N based on a long-term incubation method. The Osta-N content was calculated as the difference between the contents of total-N and the three other fractions. The total-N content was 2.06 g kg−1on average. The contents of Iex-N, Ifix-N, Omin-N and Osta-N were 25.8, 99.1, 103 and 1,832 mg kg−1, respectively, and corresponded to 1.3, 4.8, 5.0 and 88.9% of the total-N. Hence, available (Iex-N and Omin-N) and stable (Ifix-N and Osta-N) fractions accounted for 6.3% and 93.7% of the total-N, respectively. Correlation analysis indicated that the contents of total-N and Osta-N had positive correlation with (Alo + 1/2Feo) as an index of amorphous minerals (p < 0.01), suggesting strong influence of volcanic materials for the accumulation of organic matter in Java soils. The content of Ifix-N had a positive correlation with nonexchangeable potassium (K) content (p < 0.01), suggesting the contribution of 2:1 clay minerals which can fix both ammonium (NH4+) and K+in their interlayer sites. On the contrary, Omin-N did not have any significant correlation with soil properties, implying the importance of management for the improvement of the available N level in soils, rather than intrinsic soil properties. Soil N status further showed strong topographical trends depending on the elevation where soil developed. The contents of total N, Iex-N, Ifix-N, Omin-N and Osta-N in Java soils were on average 80, 69, 90, 65 and 80% of those in Japanese soils, respectively, suggesting that the soil N level in Java was lower than that in Japan, probably due to accelerated decomposition of organic matter, especially degradable fractions, reflecting high temperature, but that the level was relatively high for tropical soils due to the effect of volcanic materials. In conclusion, these results should be taken into account for the sustainable management of soil N in agricultural fields in Java, Indonesia. [ABSTRACT FROM PUBLISHER]