1. Polystyrene as a versatile nucleating agent for polypropylene
- Author
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Phillips, Andrew, Zhu, Peng-Wei, and Edward, Graham
- Subjects
- *
POLYSTYRENE , *NUCLEATION , *POLYPROPYLENE , *CRYSTALLINE polymers , *HEATING , *CRYSTALLIZATION , *SHEAR (Mechanics) , *SMALL-angle X-ray scattering - Abstract
Abstract: The morphology of isotactic polystyrene (iPS) particles which had been compounded into an isotactic polypropylene (iPP) matrix was varied in-situ by selective heat treatment to be either amorphous (iPSamorphous) or semicrystalline (iPScrystalline). The influence of iPS morphology on the quiescent and shear-induced isothermal crystallisation of iPP was then studied using differential scanning calorimetry (DSC), in-situ simultaneous small and wide angle X-ray scattering (SAXS/WAXS) and polarised optical microscopy (POM). In the quiescent condition iPScrystalline was found to selectively nucleate the β phase while iPSamorphous nucleated the α phase of iPP. Compared to the control sample (iPPcontrol), the presence of both morphologies of iPS increased the number of shear-induced oriented crystal precursors that form as a result of the step shear. During isothermal crystallisation the shear-induced nuclei promote oriented α form crystal growth, accelerate the crystallisation kinetics and ultimately swamp the effect of the nucleating particles present. [Copyright &y& Elsevier]
- Published
- 2010
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