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• Mineral liners from pre-treated dredged material may fail in distinct phases. • A mineral liner from pre-treated dredged material performed well for 20 years. • The design of the entire cover system is important for the liner performance. • A "slow" lateral drainage layer keeps the liner surface moist. • Hydro-chemical data are helpful for identifying hydrologic processes. The water balance and effectiveness of a landfill cover containing a liner from fine-grained dredged material ('METHA-material') and a drainage layer from sandy dredged material ('METHA-sand') from the Port of Hamburg (Northern Germany) was investigated for 20 years using two test fields (lysimeters), each 500 m2 in size. The layering within the standard design test field (FS) is identical to the layering of the cover on the landfill, whereas the alternative design test field (FA) was designed to provoke desiccation of the liner. The setup abstained from continuous side walls cutting through the liners in order to allow for material properties representative for the landfill cover, at the cost of possible minor lateral inflows or outflows, which were, however, considered negligible. By example of the lysimeter FA the risk of desiccation-induced failure of a liner from METHA-material under the given climate could be shown. In contrast, the discharges and hydro-chemical parameters measured for the lysimeter FS indicate continuous high efficiency of the liner until today. The average discharge below the liner was 14.9 mm/yr. The entire cover contributes to the good liner performance. Reason are (1) the low hydraulic conductivity of the liner (5 × 10−10 m/s) and its large thickness (1.5 m); (2) the increased stresses on the liner due to the 2.5 m thick overlaying cover; (3) the 1.0 m thick drainage layer from slowly-draining METHA-sand, allowing for a continuous nearly water-saturated fringe above the liner; and (4) the sufficient amount of plant available water in the recultivation layer. [ABSTRACT FROM AUTHOR]

The paper reports investigation results on the use of fine sediments to replace a part of the raw materials in Portland cement (PC) clinker. Representative samples of sediments from three different French dam reservoirs are studied. These materials have a mineral composition that includes some of oxides components essential to cement manufacturing, such as SiO2, CaO, Al2O3 and Fe2O3. Their potential for use as replacement of clays in cement industry was considered. Nine mixes of PC clinkers were synthesised with feedstock mixtures containing between 20.6 and 31.1% of sediments according to their chemical composition. In all cases studied, usual clay materials are completely substituted by dam sediments. Clinkers were characterised using ICP-AES, XRD and optical microscopy. Results showed that synthesised clinkers have similar chemical and mineralogical composition than ordinary PC clinker. Finally fine-grained sediments might be considered as natural resource, they are an interesting alternative raw material for PC clinker production. [ABSTRACT FROM AUTHOR]

Abstract Previous research has found butyltin pollution at dumping sites, which are the final fate of dredged material mostly originating from harbors and navigation systems. The distribution and impacts of butyltins were assessed in sediments at 12 dumping sites of China. Total butyltins (monobutyltin, dibutyltin, and tributyltin) concentrations ranged from 1.76 to 486.62 ng Sn g−1 dw. This study also presents evidence of considerable historic inputs of tributyltin (TBT) to Dumping sites 01, 05, 06, 08, 09 and 11, with evidence of heavier recent TBT input at Dumping site 04 and 10. The butyltin contamination at dumping sites was comparatively light and historic compared to research in other countries, but was more serious than other sea regions. TBT levels at Dumping site 09 probably have negative effects on biological systems. Overall, more attention should be paid to the level and impacts of butyltins in the sediment at dumping sites in China. Highlights • Levels of butyltins in sediment at dumping sites in China were investigated. • The results presented historic TBT source at Dumping site 01, 05, 06, 08, 09, 11. • It showed evidence of heavier recent input of TBT at Dumping site 04 and 10. • The butyltin levels at dumping sites were higher than other sea regions in China. • TBT level at dumping sites probably has negative effects on biology of organisms. [ABSTRACT FROM AUTHOR]

It has been shown that the current approach to the assessment of contamination in the sediments obtained during the dredging works in the Baltic countries indicates the presence of "non-contaminated" dredged material. The concentration limits of heavy metals, Polycyclic Aromatic Hydrocarbons (PAHs), Polychlorinated Biphenyls (PCBs) have been exceeded only in 1% of the samples obtained during the dredging works (2005–2015) within the Polish coastal zone. After 2008, no contaminated sediments have been found. Also, in the remaining Baltic countries, sediments are very rarely contaminated. As a result of this assessment, the sediments can be stored in the sea or have a practical application. However, it has been questioned whether the large cost of determining the numerous chemical parameters is justified. It has been proposed to carry out simple screening tests. Following the preliminary screening, the decision on more detailed (and expensive) chemical tests of individual pollutants would be made. [ABSTRACT FROM AUTHOR]

In 2014, the concentrations of 13 heavy metals in surface sediments from 14 sampling stations were analyzed and compared to samples from previous years to evaluate the remediation effectiveness of the “rest-year” (RY) system and capping with dredged material at the Yellow Sea-Byung dumping site offshore Korea. Since the 2006 introduction of the RY system, annual variations in metal concentrations at stations within the RY zone have gradually decreased over time. Heavy metal concentrations at most stations were lower than sediment quality guidelines, indicating the success of the RY system. Additionally, the effects of capping the contaminated sediment with dredged materials were investigated. The results indicate that dredged materials successfully capped the contaminated sediment within the dredged material dumping area, as the concentrations of Cr and total organic carbon were significantly reduced. We conclude that dredged materials may be used as capping materials for the remediation of contaminated sediments. [ABSTRACT FROM AUTHOR]

Large amounts of sediments are dredged annually from Chinese oceans. Dredged materials (DMs) possess poor geotechnical properties and are normally treated as waste. This paper presents the first large-scale engineering application of DM solidification treatment in China. The technique has been used to treat approximately 1.8 × 106 m3of DM from Taihu Lake to produce fill soils. Portland cement was chosen as the solidification material, the amount of which is confirmed through indoor unconfined compressive strength (UCS) tests. Special solidification machines process DM at 120 m3/hours. Field-based DM solidification engineering began in September 2006. Curing specimens were examined over 28 days. Results show that both UCS and failure strain of solidified DM could meet fill soil requirements. Bearing capacity was also assessed with a cone penetrometer test. Samples were examined after 2 years (after project completion), and the mean UCS of the specimens was 237.2 kPa, which completely satisfied the engineering request. Wuxi Taihu City Science and Technology Industrial Park has now been established on top of the solidified DM storage yard. The successful engineering of such facilities results in economic and environmental benefits; thus, engineering applications of DM solidification treatment are widely promoted in China. [ABSTRACT FROM AUTHOR]

Declining of the storage capacity and the lifetime of water storage reservoirs, significantly reduced by the inflow of sediments, are at present major sediment-related problem. The possible outcome in sediment management is sediment dredging. Sediments are classified as waste by legislation frameworks generating a negative image for sediment. Nevertheless sediments can represent a valuable material and should be increasingly regarded as a resource rather than as a waste. Regarding sediment perpetual availability and specific chemical and physical characteristics, their use in construction applications and concrete production is promising. This paper summarizes the results of the case study about the potential use of the sediments dredged from the Ruzin reservoir (Slovakia) as a partial (40%) substitute of Portland cement in concrete. The experiments were carried out with sediment mechanically activated by dry milling and chemically activated sediment milled together with NaOH. The effect of the sediment as a binder on the compressive and flexural strength of blended concrete specimens after 28 and 90 days is determined. The results confirmed the beneficial effect of sediment mechanical activation on achieved strengths of prepared concrete specimens. [ABSTRACT FROM AUTHOR]

The availability of steelmaking slag, an industrial by-product, was examined as a component of a basal medium for the creation and regeneration of shallow habitats in coastal ecosystems. We investigated nutrient dynamics in sediments prepared with slag and dredged materials by conducting a core incubation experiment for 379 days. Silica sand was used as the reference material. Although slag caused alkalization of pore water, the pH in the surface layer recovered within a few days. The use of slag had limited influence on the dissolved inorganic nitrogen content, but pore water phosphate concentrations were considerably suppressed in slag-based media, especially when the pH was high. Nutrient diffusion fluxes from slag- and sand-based sediment cores were comparable to those in natural coastal environments. After 379 days, more than 90 % of the nutrients remained in the top 5 cm of the cores. Moreover, the sustained release of nutrients from basal media prepared with slag may play an important role in sustaining the productivity of macrophytobenthic ecosystems, including seagrass meadows. The mesocosm-scale experiment we proposed could evaluate long-term variations of nutrient dynamics in the artificial basal media. Because of wide variations in chemical properties among the different types of slag and dredged materials, approaches similar to this study may be essential before any large-scale application to marine environments. [ABSTRACT FROM AUTHOR]

The potential impact of dredged sediment has been assessed at sixteen areas of the high-traffic port of Vilagarcia (Northwest Spanish Atlantic coast). The assessment has been done by three weight-of-evidence tools, which integrated data on sediment characteristics and toxicity responses of Ampelisca brevicornis , Vibrio fischeri and eggs and embryos of Paracentrotus lividus . Two of the tools also represented management options regarding the disposal of dredged material. The comparison of the logic in these tools revealed essential differences in the type and the necessity of bioassays and threshold values for chemical concentrations. However, despite this difference, assessment results and the derived management options coincided in most of the sediments. The potential toxicity of sediments was relatively low especially for eggs and embryos possibly due to different contaminant availability in solid and liquid phases. The importance of a battery of toxicity tests in the dredged material quality assessment has been emphasized to avoid an underestimation of sediment toxicity for solid phase organisms, if only liquid phase responses are considered. The potential false implications, which may result from the application of the third tool, were highlighted. The strengths and weaknesses of the tools were discussed from the dredged material management perspective. [ABSTRACT FROM AUTHOR]

The article discusses the possibility of protecting the shore by disposing of dredged material at shallow depths. An example of a permanently eroded open marine shore segment located south of the Vistula Lagoon inlet (south-eastern part of the Baltic Sea) is considered. This shore segment is permanently caused by downstream erosion due to the moles bordering the entrance to the Vistula Lagoon (Baltiysk Strait) and interrupting longshore sediment transport. Changes of sediment distribution resulting from a demonstration disposal of clean fine sand at depths of seven to nine metres opposite the eroded segment of the shore are examined. A supplementary numerical modelling analysis of sediment transport for different winds showed that the disposed material is transported northward or southward alongshore depending on the wind direction, and almost none of it is stored at the shore slope. The demonstration disposal and numerical modelling results demonstrate that the only way to use the dredged material to protect the eroded shore near the inlet of the Vistula Lagoon is to dispose it directly onto the beach and not into the shallow water nearby. [ABSTRACT FROM AUTHOR]

The maintenance of navigation channels to ports and the development of their facilities present a need to conduct dredging operations, and the subsequent disposal of dredged material at sea. Contaminant concentrations in candidate dredged material are determined and their possible impacts considered during the licensing process, which can result in the exclusion of some material from sea disposal. Monitoring of disposal sites is conducted in order to ensure that no undesirable impacts are occurring. In this study we consider the levels of polycyclic aromatic hydrocarbons (PAHs) in sediments at a number of disposal sites monitored in 2013 and variations in concentrations over time at three sites during the period 2008–2013. These were assessed using established sediment quality guidelines. Elevated PAH concentrations were generally observed only within the boundaries of the disposal sites studied. [ABSTRACT FROM AUTHOR]

The results of sediment quality assessment by two different weight-of-evidence methodologies were compared. Both methodologies used the same dataset but as criteria and procedures were different, the results emphasized different aspects of sediment contamination. One of the methodologies integrated the data by means of a multivariate analysis and suggested bioavailability of contaminants and their spatial distribution. The other methodology, used in the dredged material management framework recently proposed in Spain, evaluated sediment toxicity in general by assigning categories. Despite the differences in the interpretation and presentation of results, the methodologies evaluated sediment risk similarly, taking into account chemical concentrations and toxicological effects. Comparison of the results of different approaches is important to define their limitations and thereby avoid implications of potential environmental impacts from different management options, as in the case of dredged material risk assessment. Consistent results of these two methodologies emphasized validity and robustness of the integrated, weight-of-evidence, approach to sediment quality assessment. Limitations of the methodologies were discussed. [ABSTRACT FROM AUTHOR]

Flow visualization experiments were performed in a glass-walled recirculating flume to observe the fate of sediments released instantaneously in a current. For releases at the surface, criteria were developed to characterize ambient currents as 'weak,' 'transitional,' or 'strong' as a function of particle size. In weak ambient currents, particle clouds were advected downstream with a velocity equal to the ambient current, but otherwise their behavior and structure were similar to those in quiescent conditions. A substantial portion of the mass initially released, up to 30%, was not incorporated into the parent cloud and formed the trailing stem. This percentage was dependent on the initial release variables, with the greatest sensitivity on particle size. The 'loss' of sediment during descent, defined as the fraction of mass missing a designated target with a radius equal to the water depth, was quantified and found to increase sharply with current speed. Laws of geometric, kinematic, and dynamic similitude provide a basis for scaling laboratory results to the real world and formulating guidelines to reduce the losses that could result from open-water sediment disposal. [ABSTRACT FROM AUTHOR]

The effects of regular surface waves on the descent of instantaneously released sediments were investigated experimentally. The detailed wave characteristics, including wave height (), wave period (), and wave phase of release, were controlled systematically through a wave synchronization system. The results showed that the sediment cloud was passively advected by the wave orbital motion, and there was no significant phase lag between the sediments and surrounding water particles. The motion of the center of mass and the growth rate of the sediment cloud averaged over four representative wave phases of release were found to be similar to those in a stagnant ambient condition. However, a shift (in the range of ) in the horizontal equilibrium position of the oscillatory motion was observed and could be related to the wave phase of release. A passive advection model was proposed to predict the motion of a sediment cloud in the wave environment by superimposing the wave orbital velocity onto the descent velocity of the sediment cloud induced by buoyancy excess. The prediction was found to be in reasonable agreement with the experimental data. [ABSTRACT FROM AUTHOR]

Many years of untreated effluent discharge from residential areas, a shipyard, a marina, and a large fish market resulted in substantial contamination of bottom sediment in Southern Busan Harbor, South Korea. Contaminants in these sediments include heavy metals and organic compounds. Newly introduced regulations for ocean disposal of dredged material in South Korea pose significant challenges, because the previous practice of offshore disposal of contaminated dredged material was no longer possible after August 2008. The South Korean government has mandated that such sediments be assessed in a way that identifies the most appropriate dredged material management alternative, addressing environmental, social, and cost objectives. An approach using multicriteria decision analysis (MCDA) in combination with comparative risk assessment was used as a systematic and transparent framework for prioritizing several dredged sediment management alternatives. We illustrate how MCDA can recognize the multiple goals of contaminated sediment management. Values used in weighting decision criteria were derived from surveys of stakeholders who were sediment management professionals, business owners, or government decision makers. The results of the analysis showed that land reclamation was the preferred alternative among cement-lock, sediment washing, 3 contained aquatic disposal alternatives (one in combination with a hopper dredge), geotextile tubes, solidification, and land reclamation after solidification treatment. Land reclamation was the preferred alternative, which performed well across all MCDA objectives, because of the availability of a near-shore confined disposal facility within a reasonable distance from the dredging area. [ABSTRACT FROM AUTHOR]

This paper summarises the performance of simple multivariate exploratory analyses to investigate on their potential application for dredged material characterization and management. The data from 25 sampling stations located at 7 different Spanish ports, produced a matrix consisting of 300 observations on 10 variables: the metals Cd, Cu, Cr, Hg, Ni, Pb and Zn, the metalloid As, the sum of PAHs and PCB congeners, and the proportion of fines and organic matter content. The cluster analysis was suitable to separate the sediments according to the extent of contamination while the PCA indicated that the data was defined by two principal factors: a first one that accounts for 56.4% of the total variance, describing the metallic contaminants except Ni and Cr, and a second one that accounts for 14.4% of the total variance describing the organic contaminants PAHs and PCBs. The use of these two simple and untutored multivariate techniques seems a cost-effective approach for future pre-dredging investigations in the studied areas providing useful information for dredged material characterization and management with little additional effort. [Copyright &y& Elsevier]

This article discusses a study which assessed the sediment quality of the Guadalete Estuary sediments in Spain. The study carried out the purpose by means of an in situ seven day toxicity test and the determination of sublethal responses including a battery of enzymatic biomarkers using the polychaete Arenicola marina. It found that the presence of chemicals leads to gluthation-S-traesferase (GST) induction in and presumably in consequence, to lipid peroxidation (LPO) inhibition. It also showed that GST activity resulted to be the main protection mechanism against oxidative stress in Arenicola marina.

Harbor sediments containing large deposits of organotin compounds constitute a potential threat to the marine environment. Samples of harbor sediments were collected twice in the years 2003 and 2005 from the following locations: Ziółkowskiego, Siarkowe, Wiślane, Węglowe, Chemików and Paliw Płynnych Quays. The cores of 25cm length sliced into 2- and 5-cm segments were analyzed. After drying and homogenization, samples were split into two granulometric fractions, i.e. <2.00 and <0.063mm. The dominant fraction in whole sediment, i.e. fraction grain diameter <2.00mm, was sand (grain diameter 2.00–0.063mm). However, the highest concentrations of butyltin (BT) and phenyltin (PT) compounds were found in the fine sediment fraction. The mean values of tributyltin (TBT), dibutyltin (DBT) and monobutyltin (MBT) in the analyzed samples in the <2.00mm fraction were 2144.9, 434.7 and 148.1ngSng−1 d.w., respectively, while the corresponding mean values in the <0.063mm fraction were 6556.4, 1593.7 and 450.0ngSng−1 d.w. The mean concentrations of monophenyltin (MPhT) have been estimated at 29.0 and 49.9ngSng−1 d.w. for the <2.00 and <0.063mm fraction sizes, respectively. The estimated content levels of diphenyltin (DPhT) and triphenyltin (TPhT) were in most cases below the detection limit of the applied method. The sediment cores collected from the locations characterized by high industrialization and intense exploitation (Wiślane, Węglowe Quays) contained the highest concentrations of BT and PT. [Copyright &y& Elsevier]

Organotin compounds are widely used in almost all sectors of industry. Antifouling paints, which were applied to ship hulls to protect from fouling organisms, are the main source of TBT and TPhT derivatives loaded into the sea. The global ban on the use of these compounds in antifouling systems was introduced by the IMO in 2001. However, the ban did not solve the problem of the use of alternatives to TBT in the ship industry. Moreover, the issue of storing the organotins-containing dredged spoils at sea still remains unresolved. The pollution load deposited in port sediments may become an additional threat to the organisms that dwell in a given water basin. In such cases, it is necessary to establish appropriate norms for the quality classification of dredged spoils. Unfortunately, detailed guidelines concerning the disposal of dredged spoils are still lacking. [ABSTRACT FROM AUTHOR]

Abstract: The degree of contamination and toxicity in sediment from four Spanish ports (Cádiz, Huelva, Pasajes and Bilbao) was assessed in the present study. Two marine invertebrate species, the shore crab Carcinus maenas and the clam Ruditapes philippinarum, were exposed to the different sediments under laboratory conditions for 28days. Relationships were developed among metal contamination (As, Cd, Cr, Cu, Fe, Hg, Mn, Ni, Pb and Zn) in sediments, metal accumulation in gill tissues and histopathological lesions in different biological tissues to assess sediment toxicity. A multivariate analysis approach was used to calculate sediment quality guidelines (SQGs) by linking metal concentration in sediments with histopathological lesions measured in the exposed organisms. The results showed significant contaminant accumulation and histopathological lesions due to As, Pb and Zn in sediments at the port of Huelva; As, Cr, Cu, Hg and Ni at the ports of Pasajes and Cádiz; and Cr and Hg at the port of Bilbao. The link between chemical concentration in sediments and histopathological lesions allowed the determination of SQGs for the chemicals As, Cd, Cu, Cr, Hg, Ni and Zn. [Copyright &y& Elsevier]

Environment Canada's Disposal at Sea Programme hosted the Contaminated Dredged Material Management Decisions Workshop in Montreal, Quebec, Canada, on 28-30 November 2006. The workshop brought together over 50 sediment assessment and management experts from academic, industrial, and regulatory backgrounds and charged them with drafting a potential framework to assess contaminated dredged materials and compare the risks of various disposal alternatives. This article summarizes the recommendations made during the workshop concerning the development of sediment assessment tools, the interpretation of these tools, and the essential attributes of a comparative risk assessment process. The major outcomes of the workshop include a strong recommendation to develop a national dredging or sediment management strategy, a potential decision-making framework for the assessment of dredged materials and comparative risk assessment of disposal options, and the expansion of minimum sediment characterization requirements for nonroutine disposal permit applications. [ABSTRACT FROM AUTHOR]

Since the 1997 local ban on ocean dumping of dredged sediments, the States of New York and New Jersey have pursued a policy of environmentally sound solutions to the management of dredged material, including beneficial use of stabilized dredged material (SDM) in transportation applications. A pilot study was initiated in 1998 to evaluate the use of SDM in the construction of highway embankments. Utilizing 80,000 cubic yards of dredged material, two embankments were constructed from SDM on a commercial development area adjacent to the Harbor. Geotechnical properties and handling of SDM were evaluated both during and one year post - construction. This article presents the evaluation of the embankments themselves, including constructability and performance. The results demonstrate that SDM satisfies most of the geotechnical criteria for fill construction, except those for durability, requiring proper coverage and protection similar to that provided for fills constructed on cohesive soils. This same characteristic precludes long term stockpiling of SDM prior to final placement, limiting applications to those that have schedules overlapping with dredging projects. Increased costs for the use of SDM can be as high as $8 per cubic yard over traditional fills; however, this cost may be recouped through management fees collected from dredging projects. [ABSTRACT FROM AUTHOR]

Background. Under anoxic conditions typically prevailing in disposal sites for dredged sediment, methanogenesis is the terminal step during microbial degradation of sediment organic matter. Sediment gas production may pose several problems to site management and post-closure utilisation. Depending on the magnitude of gas/methane formation and the intended utilisation of the site, countermeasures will have to be effected during and after deposition of the dredged material. For this purpose it may be of interest to pre-estimate the extent of gas formation from simple sediment variables. Therefore, the aim of the investigations presented here was to analyse the interrelations between gas formation and sediment physical, chemical and biological qualities. Methods. Freshly sampled riverbed sediment from nine German federal waterways was analysed for standard solid physical and chemical parameters, pore water composition, cell counts of methanogenic and sulfate-reducing bacteria, and gas formation over a period of 500 days. Particle size and density fractionation were carried out in order to characterise organic matter quality. Correlations between methane formation and sediment chemical, physical and microbiological characteristics were tested using linear and multiple correlation analysis. Results and Discussion. The selected sediments, including two with marine influence, differed strongly regarding texture, chemical parameters, pore water composition, and methanogen cell counts. The course of methane formation was found to follow distinct phases. The commencement of methane formation was preceded by a lag phase of variable duration. The lag phase was followed by a strong increase of the methane formation rate up to a sediment-characteristic maximum of 5–30 nmol CH4 h-1 g dw-1. Eventually, the rate of methane formation decreased and reached a more stable, long-term level. The extent and amplitude of each phase varied strongly between sediments and could be correlated well with only a few standard analytical parameters, despite the strong heterogeneity of sediment with respect to chemical, physical, and biological characteristics. Lag phase duration depended strongly on the content of inorganic electron acceptors and also on the number of methanogens present at the beginning of the experiment. Maximum and steady state methanogenesis were mainly determined by sediment total nitrogen. As analysis of sediment density fractions revealed that total nitrogen reflected the share of readily degradable macroorganic matter. Conclusion and Outlook. The results imply that the observed methane formation is a function of the temporally changing balance of the availability of electron acceptors and H2, and the share of easily degradable organic matter. For fresh riverbed sediments, the latter may be deduced from total nitrogen content. Overall, the results showed that methane formation by freshly dredged material may well be pre-estimated from standard analytical data within the first few years of deposition. However, the differently degradable organic matter pools will change over time with respect to size, chemical nature and association with the sediment mineral phase. It can thus be expected that the correlations found in this study will not be readily transferable to older materials. Further studies on the gas formation and organic matter quality by older sediments, e.g. from older dredged material disposal sites of known age, should be conducted and results should be combined with existing organic matter degradation models in order to improve the prediction of sediment gas formation over time. [ABSTRACT FROM AUTHOR]

The traditional approach to assessing sediment quality involves chemical analysis. However, this is not sufficient to ensure safe disposal of dredged material or to determine the impact on biota of sediment contamination. The toxic effect on flora and fauna is related to the bioavailability of contaminants. Because of the potential transfer of contaminants along food chains, not only the local habitat can be affected, but also organisms at higher trophic levels. The consumption of seafood may lead to adverse effects on human health.Biomarkers are useful tools as early warnings to determine exposure to contaminants and the effect of contaminants on organisms before the damage becomes irreversible. They may link the bioavailability of compounds with their concentrations at target organs and intrinsic toxicity. Nevertheless, other confounding factors must be taken into account when the results are interpreted.We review different biomarkers used to determine the quality of marine sediment and dredged material. Also, we consider evaluation of the use of biomarkers in environmental risk assessment (ERA) and links between laboratory and field surveys. We integrate available information to determine the validity of the different biomarkers, their relevance for assessing contaminated sediments and the suitability of the methodology. We consider the results in a tiered approach to testing at levels characterizing toxic effects and validating in situ changes. [Copyright &y& Elsevier]

In order to assess heavy metal mobility in dredged harbour sediments, six superficial sediment samples covering a range of pollution levels and environments were collected in Barcelona Harbour. Samples were characterised in terms of major compounds (Al, Ca, Fe, Mn, Si, Ti, Mg, K and Na); total C, N and S contents; organic matter; and water content. Pseudo-total trace metal contents were assessed after aqua regia digestion (ISO 11466:1995). The modified BCR three-step sequential extraction procedure (BCR-SEP) was applied, and both major compounds (Al, Ca, Fe and Mn) and trace metals (Cd, Cr, Cu, Ni, Pb and Zn) were determined in the different extracts. Both the pseudo-total digestion method and the BCR-SEP were validated using two sediment certified materials from lakes (BCR CRM 701 and BCR CRM 601). The highest metal concentrations were observed in one of the sampling points which receives an urban discharge. The observed mobility order (percentage of metal extracted in the first step) of the six trace metals studied was Cd>Zn>Pb>Cu>Ni>Cr. The good agreement observed with the results obtained as the sum of the four steps (extractable+residue) and the pseudo-total content shows that laboratory working conditions were under control. [Copyright &y& Elsevier]

Sediment toxicity in silty marine harbor sediments is frequently dominated by ammonia or sulfide, leaving the adverse effects of persistent toxic substances unnoticed. To investigate the latter, we subjected interstitial water from three contaminated silty sediments to toxicity identification evaluation (TIE) phase I manipulations and tested for toxicity with four bioassays: the amphipod Corophium volutator (survival as an endpoint), the sea urchin Psammechinus miliaris (fertilization, embryo development) and the bacterium Vibrio fischeri (bioluminescence inhibition).The graduated pH manipulations identified the prominent toxicity of ammonia in the amphipod and sea urchin embryo tests, and also sulfide toxicity in the bacterium test. In two of the three samples tested with the amphipods, sea urchin embryos and bacteria, a small but significant reduction in interstitial water toxicity was achieved by removing persistent compounds through C18 solid phase extraction. EDTA chelation resulted in a slight detoxification of the interstitial water for the amphipods and sea urchin embryos, but this was not related to any measured trace metals. Despite the presence of toxic levels of ammonia and sulfide in the harbor sediments, we established the adverse biological effects of persistent constituents by means of the TIE manipulations and in vivo interstitial water bioassays. [Copyright &y& Elsevier]

The presence of dioxin-like compounds in sediments from harbors and reference sites along the Dutch coast was investigated using the dioxin receptor-chemically activated luciferase gene expression (DR-CALUX) bioassay. The DR-CALUX response varied between 0.2 and 136 ng/kg dry weight expressed in units of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) toxic equivalency quotients (TEQ). The highest CALUX-TEQ values (>50 ng TEQ/kg dry wt) were found in sediments from the center of the Port of Rotterdam and from the North Sea canal near Amsterdam. The DR-CALUX activity of harbor sediments was classified by setting guideline values. None of the 257 harbor sediment samples investigated exceeded the maximum value of 1,000 ng TEQ/ kg, while 94% of the samples fail the target value of 2 ng TEQ/kg. Threshold values (25 and 50 ng TEQ/kg) are intended as pass/ fail criteria for offshore disposal of dredged material and were exceeded in 12 and 3% of the samples, respectively. DR-CALUX response did not always match with contamination of polychlorinated biphenyls (PCBs) as determined in bulk sediments (Σ7-PCB ranging from <1 to 456 µg/kg dry wt). Concentrations of planar PCBs, polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated-dibenzofuranes (PCDFs), polybrominated biphenyls (PBBs), and polybrominated-diphenylethers (PBDEs) were determined in 20 selected sediment extracts. On average, PCDD/Fs explained 50% of the DR-CALUX activity and planar PCBs 6%. Further research is needed to elucidate the unexplained part of the DR-CALUX response. The DR-CALUX is a highly sensitive and reproducible bioassay that can usefully complement standard PCB analysis, improving the hazard assessment of the disposal of dredged material in the North Sea. [ABSTRACT FROM AUTHOR]

Dredging rivers is needed to ensure safe navigable waters, rivers and waterways. To anticipate the management of dredged materials in the case of the river Seine basin, the quality of the sediments in the river is checked every 3 years before dredging operations. The river Seine Basin is heavily submitted to pollution pressure from nearby industrial activities and urban expansion of Paris and its region. Here, the micropollutant content of the sediment sampled in 1996, 1999 and 2000 before dredging is discussed compared to regulatory standards. The results indicate that most of the sediment samples from the river Seine basin are lightly to moderately contaminated with organic and inorganic micropollutants (heavy metals, PAH, PCB), which makes the management after dredging easier. This pollution is strongly correlated with the organic matter content and to the fine fraction (<50 μm) of the sediment. These results can lead to other management options than the ones already used in the river Seine basin: (1) dumping of lightly to moderately polluted sediments in quarries; and (2) physical treatment (sieving, hydrocycloning) of contaminated sediments issued from ‘hot spots’. [Copyright &y& Elsevier]

Industrial activities in the river basin of the Elbe have a very long tradition, and have been resulting in the contamination of sediments for centuries. Contamination lasted until the fall of the iron curtain; since then, the situation has improved significantly. In the transition zone between freshwater systems and the marine environment, ports like Hamburg still have to bear this burden of history. An overall (contaminated) management strategy should be developed in the context of the European Water Framework Directive with the emphasis on source control. [ABSTRACT FROM AUTHOR]

In rivers, sediments are frequently accumulating persistent chemicals, especially for those that are more contaminated as a consequence of pressure related to environmental pollution and human activity. The Seine river basin (France) is heavily polluted from nearby industrial activities, and the urban expansion of Paris and its suburbs within the Ile de France region and the sediments present in the Seine river basin are contaminated. To ensure safe, navigable waters, rivers and waterways must be dredged. In this paper, the quality of the sediment dredged in 1996, 1999 and 2000 is discussed. Physico-chemical characteristics of the sediment itself and of the pore-water are presented. Seine basin sediments show very diverse compositions depending on the sampling site. Nevertheless, a geographic distribution study illustrated that the Paris impact is far from being the only explanation to this diversity, the quality of this sediment is also of great concern. The sediment once dredged is transported via barges to a wet disposal site, where the dredged material is mixed with Seine water in order to be pumped into the receiving site. This sort of dumping might be responsible for the potential release of contaminants to the overlying water from the significantly contaminated sediments. [Copyright &y& Elsevier]

Biomagnification of organochlorine and other persistent organic contaminants by higher trophic level organisms represents one of the most significant sources of uncertainty and variability in evaluating potential risks associated with disposal of dredged materials. While it is important to distinguish between population variability (e.g., true population heterogeneity in fish weight, and lipid content) and uncertainty (e.g., measurement error), they can be operationally difficult to define separately in probabilistic estimates of human health and ecological risk. We propose a disaggregation of uncertain and variable parameters based on: (1) availability of supporting data; (2) the specific management and regulatory context (in this case, of the U.S. Army Corps of Engineers/U.S. Environmental Protection Agency tiered approach to dredged material management); and (3) professional judgment and experience in conducting probabilistic risk assessments. We describe and quantitatively evaluate several sources of uncertainty and variability in estimating risk to human health from trophic transfer of polychlorinated biphenyls (PCBs) using a case study of sediments obtained from the New York-New Jersey Harbor and being evaluated for disposal at an open water off-shore disposal site within the northeast region. The estimates of PCB concentrations in fish and dietary doses of PCBs to humans ingesting fish are expressed as distributions of values, of which the arithmetic mean or mode represents a particular fractile. The distribution of risk values is obtained using a food chain biomagnification model developed by Gobas by specifying distributions for input parameters disaggregated to represent either uncertainty or variability. Only those sources of uncertainty that could be quantified were included in the analysis. Results for several different two-dimensional Latin Hypercube analyses are provided to evaluate the influence of the uncertain versus variable disaggregation of... [ABSTRACT FROM AUTHOR]

Sediment dredging impacts coastal environments by promoting the resuspension of fine particles and remobilization of contaminants that may trigger toxic effects. In this study, we evaluated the sediment quality in harbor areas of Mucuripe bay, a semi-arid ecosystem located in Ceará state (Brazil), which is subject to dredging activities. A sampling survey was conducted right after dredging operations and data compared to another survey performed prior dredging. Sediments were analyzed for fine particles, organic carbon, nutrients, metals, hydrocarbons, and tributyltin (TBT). Toxicity of whole-sediment and liquid phase exposures were also determined. The concentrations of Cd, Cr, Cu, and Zn decreased after dredging, which was confirmed by the geoaccumulation index. Levels of TBT dropped while phosphorus, aliphatic and polycyclic aromatic hydrocarbons increased. Toxic effects persisted, indicating a post-dredging recontamination combined with other sources such as urban runoff, wastewater discharges, harbor activities, and antifouling particles. Data from Mucuripe and Pecém harbors were compiled and site-specific sediment quality values (SQVs) were developed by using multivariate methods. The threshold values proposed by our study were lower and more effective to predict toxicity compared to international guidelines, indicating levels of contamination for this tropical region in which toxic effects may occur. Considering the large geographic area with different sediment characteristics of the Brazilian coast, this study represents a significant contribution to sediment toxicity assessment of dredging activities in semi-arid environments. Image 1 • Data on sediment quality of harbor areas in a Brazilian semi-arid region were analyzed. • Remobilization and reduced levels of contamination were observed after dredging activities. • Site-specific sediment quality values were developed by using multivariate methods. • Threshold values were more effective to predict toxicity compared to international guidelines. [ABSTRACT FROM AUTHOR]