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A series of marginal-sea basins and fault-depression basins were formed in eastern China under the background of subduction of the West Pacific plate. Different types of helium-rich natural gas reservoirs (He>1000 ppm, 1 ppm=1 µmol mol−1) have been found in these basins: helium-rich CO2 gas reservoirs, helium-rich N2 gas reservoirs, and helium-rich hydrocarbon gas reservoirs. Based on the analysis of gas geochemical data, the source and accumulation mechanism of helium in these helium-rich natural gas reservoirs were discussed. Helium-rich natural gas has relatively high 3He/4He ratios (0.88–4.91 Ra, average 2.82 Ra). The 3He/4He ratio characteristics of mantle xenoliths and mantle-derived CO2 gas reservoirs indicate that the helium in these helium-rich natural gas reservoirs is mainly mantle-derived (>70%). The original mantle volatile is mainly CO2 with a low helium concentration (He<200 ppm), and the enrichment of mantle-derived helium in the gas reservoir is mainly related to the dissolution and mineralization of CO2. During this process, the CO2/3He ratio decreases from 2×109 to approximately 2×106. As CO2 dissolves and mineralizes, the concentration of conservative gases (He and N2) increases in the remaining CO2 gas proportionally to the loss of CO2. Large amounts of carbonate minerals, such as dawsonite, which are relatively enriched in 13C, are found in CO2 reservoirs in eastern China. The relative enrichment of 12C in residual CO2 gas is important evidence of the dissolution and mineralization of CO2. The relative abundance of mantle-derived helium and N2 gas increases thousands of times during the dissolution and mineralization of CO2, which is the main accumulation mechanism of mantle-derived helium-rich CO2 gas reservoirs and helium-rich N2 gas reservoirs. Helium-rich gas from the mantle is mixed with alkane gas generated by organic matter in the sedimentary basin to form helium-rich hydrocarbon gas reservoirs. [ABSTRACT FROM AUTHOR]

The hydrogen isotope composition of methane is an important parameter in natural gas research and provides complementary information to that provided by carbon isotopes. The stable hydrogen isotope ratios of 313 natural gas samples from six of China’s sedimentary basins are used to evaluate the factors that influence the stable hydrogen isotopic composition of methane. An important factor is the δD of organic matter in hydrocarbon source rocks, which is influenced by the sedimentary environment and type of organic matter. Natural gases generated from sapropelic organic matter have relatively less negative δ D CH 4 , while natural gases generated from humic organic matter have relatively more negative δ D CH 4 . The other factor is thermal maturity. Increased thermal maturity leads to δ D CH 4 becoming less negative and there exists a two stage linear relationship between the δ D CH 4 and the logarithm of the vitrinite reflectance ( R o) value for natural gases generated from type III kerogen. The third factor is the environmental conditions of the aqueous medium in the original depositional environment and after sedimentation. Elemental hydrogen from water participates in biochemical processes as organisms grow and is exchanged during the sedimentation and diagenesis of organic matter as well as maturity process of kerogen to generate gases. The influence of the aqueous medium on δ D CH 4 after formation of natural gases can be ignored. Among these factors, the aqueous medium is the key constraining factor. The δ D CH 4 in natural gases can be combined with the use of stable carbon isotopic composition to identify the origins of natural gases and to aid gas-source correlations. [ABSTRACT FROM AUTHOR]

Helium is an exhaustible natural resource and the main commercial helium was separated from helium-rich natural gas. The helium in the sedimentary basin is mainly the radiogenic origin of crustal rocks with high level of uranium and thorium. Data from 242 natural gas samples were used to investigate the distribution and formation mechanism of helium-rich gases in the Sichuan Basin of China. All gas samples show remarkably low 3He/4He ratios with ranging from 0.002 to 0.05 Ra, which represent typical crustal helium. The Weiyuan gas pool in the southern Sichuan Basin possesses high levels of helium (1500–18770 ppm, average 2785.7 ppm) in Precambrian and Cambrian strata. A positive relationship were observed in the helium and nitrogen contents increased with reservoir layer age for all Weiyuan gas samples. Presinian granite was considered as the main helium source for the Weiyuan gas pool. Gaoshiti–Moxi and Weiyuan gas pools belonged to the same ancient gas pool before the Late Cretaceous, but the helium abundance of Gaoshiti–Moxi gas pool is relatively low (200–891 ppm). The change of pressure and fracture system caused by the uplift of Weiyuan structure in the Himalayan orogenesis led to the helium accumulation and enrichment of Weiyuan gas pool. The shale of the Silurian Longmaxi Formation has high contents of uranium and thorium and generated a large amount of helium while forming large quantities of hydrocarbon gases. Generally, the helium abundance of shale gases and conventional gases generated from the Longmaxi Formation ranges from 63 to 1500 ppm and some of the gas pool are sufficient for commercial helium resource exploitation. Therefore, the relative quantities of helium and hydrocarbon gases are act as a key factor influencing the formation of helium-rich natural gas reservoirs. • Helium in the sedimentary basin is mainly the radiogenic origin. • Helium-rich gas is generally the crust-derived heterogenous type. • Presinian granite was the main source of helium in the Weiyuan gas field. [ABSTRACT FROM AUTHOR]

Helium is an important, scarce, and strategic resource that is critical to national security and advanced technology development. Although helium originates from mantle degassing and the radioactive decay of uranium (U) and thorium (Th) in minerals, commercial helium resources are primarily derived from natural gas reservoirs with He concentrations higher than 1000 ppm. The gas geochemistry characteristics of 920 natural gas samples from nine petroliferous basins in China were used to classify and discuss the enrichment mechanisms of helium. Helium-bearing natural gas reservoirs can be divided into the following three types: basement source-migration-rich accumulation, self-generating and self-preserving, and crust–mantle complex types. The basement source-migration-rich accumulation, which is the most common type of proven helium-rich natural gas reservoir, occurs primarily in inherited anticlines and dome traps located on basement uplifts. Ancient shale systems demonstrate the potential to form helium-rich shale gas that belongs to the self-generating and self-preserving type. Crust–mantle complex helium-rich natural gas reservoirs develop in petroliferous basins in active magmatic–tectonic areas. The origins of helium and hydrocarbon gas are different, but the entrainment of helium during hydrocarbon gas accumulation is a key factor influencing the formation of helium-rich natural gas reservoirs. The nitrogen concentration in helium-rich gas samples is often extremely high, indicating that the nitrogen and the helium are derived from the same source rock or both are extracted from water by migrating gas. • Helium-rich gas includes basement source-migration-rich accumulation, self-generating and self-preserving, and crust–mantle complex types. • Exsoluion gathering of underground dissolved helium is the key mechanism of helium enrichment. • High-quality matching between helium and natural gas is crucial for the helium-rich gas accumulation. [ABSTRACT FROM AUTHOR]