Search

Hydrophobization of hydrophilic jute fiber, is of great importance as it can expand the applications of jute fiber in many fields. This work reports the hydrophobization of jute fiber by high‐energy radiation treatment which is an easy, single‐step, economical, and environment friendly method. Surface wettability of hydrophilic jute fiber is tuned by attaching long chain hydrocarbon molecules, namely butyl methacrylate, octyl acrylate and lauryl methacrylate, using gamma radiation. Lauryl methacrylate is found to be the most suitable agent among the molecules used for generating desired extent of hydrophobicity. Important reaction parameters, namely total dose, dose rate, monomer concentration, and solvent composition are optimized to achieve the desired degree of modification, for imparting hydrophobicity. Mechanical and thermal analysis reveals that there is no considerable damage to the base structure of fibers during modification. Scanning electron microscopy (SEM) is supporting evidence of the intactness of fiber after modification. The successful grafting of jute fiber has also been evidenced by SEM. This lauryl methacrylate modified jute can separate oily toxic liquids from aqueous media. The modified jute fiber may get enhanced applications in various fields. [ABSTRACT FROM AUTHOR]

Flax fibre reinforced polyolefin composite is a great interest of today's scientists. But the preparation of such composites with desired properties is a great challenge due to the dissimilar surface wettability (surface energy) of polyolefin and flax fibre. In this work, we have developed a linear low density polyethylene (LLDPE)/flax fibre based composite successfully. First, flax fibre is subjected to gamma radiation-assisted surface modification through covalent attachment of long chain hydrocarbon. Therefore, the surface wettability of flax fibre turns closer to that of LLDPE, and consequently a LLDPE/flax fibre composite with a strong interface is formed easily. Due to the designing of strong interface and consequently higher load transferring capability, properties are improved considerably. Young's modulus and tensile strength values of composites with surface modified flax fibre become considerably higher compared to pure LLDPE and LLDPE/pure flax fibre composites. Strong reinforcement is reflected in the dynamic mechanical properties also. The highly improved dispersion and strong interfacial strength of LLDPE/modified flax fibre are observed in SEM (scanning electron microscopy). Thermal degradation temperatures of LLDPE and flax fibre are also improved in the composites. [ABSTRACT FROM AUTHOR]