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The 7d unconfined compressive strength tests of alkali-activated tungsten tailings and the microscopic characteristics tests of scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD) were conducted to investigate the effect of alkali-solid ratio on the properties of alkali-activated tungsten tailings. The test results indicate that the unconfined compressive strength of alkali-activated tungsten tailings increased with the alkali-solid ratio. However, the strength decreases slightly when the alkali-solid ratio is 12%. The microstructures of the gels generated in the alkali-activated tungsten tailings are affected by the alkali-solid ratio. The details are as follows: the microstructure is honeycomb in low alkali-solid ratio (7%, 8% and 10%), with N-A-S–H as its primary form, and flocculation in high alkali-solid ratio (14% and 15%), mainly in the form of C-A-S–H. When the alkali-solid ratio is at the medium level (12%), the microstructure is a small round bead, and the N-A-S–H is equivalent to the C-A-S–H. The more C-A-S–H content, the greater the strength. This study can provide a scientific basis and technical reference for the resource utilization of tungsten tailings. [ABSTRACT FROM AUTHOR]

Conventionally, red clay is used for agricultural purposes in southern China. Fertilizers, especially urea, are commonly introduced into the red clay to improve the crop yields. However, due to the rapid urbanization in China, large areas of lands with red clays have been converted into sites for domestic and industrial constructions. Nevertheless, few researchers focused on the effect of urea on the strength and compressibility of red clay. In this research, the shear strength and compressibility of the red clay saturated by different concentrations of the (NH4)2CO3 solution (urea's hydrolysates) were experimentally investigated using direct shear as well as oedometer tests, respectively. It was noticed that both the shear strength and stiffness of the red clay significantly decreased after exposure to the urea solution. In addition, the micromechanisms of the strength and compressibility of the red clay treated by the (NH4)2CO3 were studied by the scanning electron microscope test and X‐ray diffraction test. Based on the test results, a new model was developed to simulate the chemomechanical behavior of saturated clayey soil by modifying the Barcelona basic model (BBM) for unsaturated soils. The proposed model introduces four additional parameters, compared to the BBM, to account for the nonlinear shear strength behavior of the red clay. This model accounts for most of the complex features related to the strength and stiffness behavior of clayey soils. The parameter calibration procedures, by using the oedometer and direct shear test results, are also presented. To validate the proposed model, experimental results from the literature are considered in which illite clay samples were either mechanically or chemically or both mechanically and chemically loaded. Part of the experimental results is used to calibrate the model parameters and the other part along with the calibrated parameters is used to verify the proposed model. A comparison between experimental data and predicted results demonstrated that the proposed model is able to capture the main features related to the chemomechanical coupling behavior of saturated soils. [ABSTRACT FROM AUTHOR]