1. Nitrate pollution source apportionment, uncertainty and sensitivity analysis across a rural-urban river network based on δ 15 N/δ 18 O-NO 3 - isotopes and SIAR modeling.
- Author
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Ji X, Shu L, Chen W, Chen Z, Shang X, Yang Y, Dahlgren RA, and Zhang M
- Subjects
- Bayes Theorem, China, Ecosystem, Environmental Monitoring methods, Humans, Nitrates analysis, Nitrogen analysis, Nitrogen Isotopes analysis, Nitrogen Oxides, Sewage, Uncertainty, Rivers, Water Pollutants, Chemical analysis
- Abstract
Nitrate pollution is of considerable global concern as a threat to human health and aquatic ecosystems. Nowadays, δ
15 N/δ18 O-NO3 - combined with a Bayesian-based SIAR model are widely used to identify riverine nitrate sources. However, little is known regarding the effect of variations in pollution source isotopic composition on nitrate source contributions. Herein, we used δ15 N/δ18 O-NO3 - , SIAR modeling, probability statistical analysis and a perturbing method to quantify the contributions and uncertainties of riverine nitrate sources in the Wen-Rui Tang River of China and to further investigate the model sensitivity of each nitrate source. The SIAR model confirmed municipal sewage (MS) as the major nitrate source (58.5-75.7%). Nitrogen fertilizer (NF, 8.6-20.9%) and soil nitrogen (SN, 7.8-20.1%) were also identified as secondary nitrate sources, while atmospheric deposition (AD, <0.1-7.9%) was a minor source. Uncertainties associated with NF (UI90 = 0.32) and SN (UI90 = 0.30) were high, whereas those associated with MS (UI90 = 0.14) were moderate and AD low (UI90 = 0.0087). A sensitivity analysis was performed for the SIAR modeling and indicated that the isotopic composition of the predominant source (i.e., MS in this study) had the strongest effect on the overall riverine nitrate source apportionment results., (Copyright © 2022 Elsevier B.V. All rights reserved.)- Published
- 2022
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