6 results on '"Echeverria, Coro"'
Search Results
2. On the influence of imidazolium ionic liquids on cellulose derived polymers.
- Author
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Paiva, Tiago, Echeverria, Coro, Godinho, Maria H., Almeida, Pedro L., and Corvo, Marta C.
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IONIC liquids , *NUCLEAR magnetic resonance spectroscopy , *POLYMERS , *HYDROPHILIC interactions , *MAGNETIC measurements - Abstract
• The influence and interactions of ILs in LC-HPC solutions were studied. • HRMAS unveiled non-polar IL domain and more hydrophobic HPC surface interactions. • Both hydrophilic and hydrophobic interactions take place between HPC and ILs. • Longer side-chain ILs produce swelling on LC-HPC solutions. The demand for better cellulose solvents has driven the search for new and improved materials to enable the processing of this polysaccharide. Ionic liquids have been debated for a long time as interesting alternatives, but the molecular details on the solubilization mechanism have been a matter of controversy. Herein, for the first time, the structure and dynamics of hydroxypropylcellulose (HPC) liquid crystal solutions were probed in the presence of imidazolium ionic liquids (ILs), conjugating rheological measurements with magnetic resonance spectroscopy. This study provides a characterization of the solutions macroscopic behaviour, where the liquid crystalline (LC) properties were maintained. Using ILs with different side chain lengths, the influence of the hydrophobic IL domain in the solvation abilities of ILs towards a cellulose derived polymer was accessed, providing experimental evidence on these interactions. [ABSTRACT FROM AUTHOR]
- Published
- 2019
- Full Text
- View/download PDF
3. Two negative minima of the first normal stress difference in a cellulose-based cholesteric liquid crystal: Helix uncoiling.
- Author
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Echeverria, Coro, Almeida, Pedro L., Aguilar Gutierrez, Oscar F., Rey, Alejandro D., and Godinho, Maria Helena
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CHOLESTERIC liquid crystals , *CELLULOSE , *OSCILLATING chemical reactions , *POSSIBILITY , *BIOPOLYMERS , *RHEOLOGY - Abstract
ABSTRACT The shear rate dependence of material functions such as shear viscosity ( η) and the first normal stress difference ( N1) were given and interpreted earlier by Kiss and Porter. Their widely accepted work revealed the possibility of having a negative minimum of N1 for polymeric liquid crystals. In this work, we disclose for the first time the evidence of two negative N1 minima on a sheared cellulosic lyotropic system. The lower shear rate minimum is ascribed to the uncoiling of the cholesteric helix, as theoretically predicted earlier. Our findings contribute also to the understanding of the other minimum already reported in the literature and attributed to the nematic director tumbling mode. Moreover, the elastic change that the LC-HPC sample undergoes during the helix unwinding of the cholesteric structure is also by means of oscillatory measurements. This study is a contribution for the understanding of the structure-properties relationship linked with the complex rheological behavior of chiral nematic cellulose-based systems and may help to improve their further processing. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017, 55, 821-830 [ABSTRACT FROM AUTHOR]
- Published
- 2017
- Full Text
- View/download PDF
4. A cellulosic liquid crystal pool for cellulose nanocrystals: Structure and molecular dynamics at high shear rates.
- Author
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Echeverria, Coro, Almeida, Pedro L., Feio, Gabriel, Figueirinhas, João L., and Godinho, Maria H.
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NANOCRYSTAL synthesis , *CELLULOSE , *LIQUID crystalline solvents , *SHEAR (Mechanics) , *NANOCRYSTALS - Abstract
Cellulose and its derivatives, such as hydroxypropylcellulose (HPC) have been studied for a long time but they are still not well understood particularly in liquid crystalline solutions. These systems can be at the origin of networks with properties similar to liquid crystalline (LC) elastomers. The films produced from LC solutions can be manipulated by the action of moisture allowing for instance the development of a soft motor (Geng et al., 2013) driven by humidity. Cellulose nanocrystals (CNC), which combine cellulose properties with the specific characteristics of nanoscale materials, have been mainly studied for their potential as a reinforcing agent. Suspensions of CNC can also self-order originating a liquid–crystalline chiral nematic phases. Considering the liquid crystalline features that both LC-HPC and CNC can acquire, we prepared LC-HPC/CNC solutions with different CNC contents (1, 2 and 5 wt.%). The effect of the CNC into the LC-HPC matrix was determined by coupling rheology and NMR spectroscopy – Rheo-NMR a technique tailored to analyse orientational order in sheared systems. [ABSTRACT FROM AUTHOR]
- Published
- 2015
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5. Understanding the influence of carbon nanotubes on the flow behavior of liquid crystalline hydroxypropylcellulose: A Rheo-NMR study.
- Author
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Echeverria, Coro, Almeida, Pedro L., Figueirinhas, João L., and Godinho, Maria H.
- Subjects
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CHOLESTERIC liquid crystals , *CARBON nanotubes , *LIQUID crystal states , *MULTIWALLED carbon nanotubes - Abstract
Hydroxypropylcellulose (HPC) is an important cellulose derivative that has been widely studied due to its water-solubility, biocompatibility and biodegradability, but even more significant due to its ability to form liquid crystalline phases. HPC is able to form, under certain conditions, chiral nematic (cholesteric) structures in water solutions. Previous work confirmed that films prepared from liquid crystalline HPC/water solutions (LC-HPC) gave rise to anisotropic networks, with similar mechanical and optical characteristics of Liquid Crystalline Elastomers (LCE), capable to respond to humidity. It was also demonstrated that the incorporation of carbon nanotubes (CNTs) significantly improved the actuator responsiveness. In the work presented herein, we investigate how the incorporation of carbon nanotubes affects the flow behavior of LC-HPC solutions, and thus the structure-properties relationship, through a detailed Rheo-NMR study. As observed from the results, when shearing the samples, the degree of order reached (maximum quadrupolar peak splitting) by LC-HPC solutions increases with CNT content. Regarding the subsequent relaxation process, only the incorporation of 0.01 wt% of CNTs (lowest content) contributes to a faster recovery of cholesteric structure. Image 1 • Study of CNTs effect in the flow behavior of liquid crystalline HPC solution. • CNTs align in the direction of shear increasing LC-HPC achieved degree of order during shear. • CNTs contributes to a faster recovery of LC-HPC cholesteric structure during relax. [ABSTRACT FROM AUTHOR]
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- 2019
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6. Gelation of Cellulose Derivatives: Searching for ionic liquid paper
- Author
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Rosete, Inês M. Micael, Corvo, Marta, and Echeverria, Coro
- Subjects
Cellulose derivatives ,Nuclear Magnetic Resonance ,Engenharia e Tecnologia::Engenharia Química [Domínio/Área Científica] ,Cellulose ,Rheology ,Gels ,polymer ionic liquid - Abstract
Cellulose is the world’s most abundant, biocompatible, non-toxic, biodegradable polymer obtained from renewable sources. However its dissolution problems hampers a more generalized application. ILs are generally defined as organic/inorganic salts with a melting point lower than 100 C which present a good solubility for polar and non-polar compounds such as organic, inorganic or polymeric materials like cellulose. Cellulose solvents are scarce and, as such, the modification of its properties is a challenge. In this dissertation the main goal was to combine some of the unique IL’s properties with the intrinsic cellulose features. Thus, our strategy was to synthesize cellulose derivatives that enable the dissolution process in order to, later on, obtain a polymer gel. In the first stage we obtained ionic liquid grafted cellulose derivatives. Afterwards, we performed an extensive solubilization study to select the appropriate conditions to obtain the gel state. To further understand the solvents’ dynamics and their relevance in the gelation process, these conditions were followed by NMR and Rheology. The obtained results allowed the proposal of a gelation model for these cellulosic polymers. The proposed strategy could be a starting point to design and produce Ionic Liquid Paper (ILP), a material that could have potential for electrochemical applications.
- Published
- 2016
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