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To solve the problems of low flame retardant efficiency and weak low-temperature performance of asphalt modified by conventional flame retardants (CFR), in this study, halloysite nanotubes (HNTs) and CFR were used to prepare nanocomposite flame retardants (NCFR) to modify asphalt. A fluorescence microscope (FM), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscope/energy dispersive spectrometer (SEM/EDS) were used to characterize the microstructure of NCFR-modified asphalt. An oxygen index meter, Cleveland open cup, and cone calorimeter were used to test the flame retardant properties of the asphalt. A dynamic shear rheometer, bending beam rheometer, and force ductility tester were used to test the rheological properties of asphalt. At the same time, flame retardant–modified asphalt mixtures were prepared to verify the flame retardancy and road performance of the flame retardant–modified asphalt. The research results showed that the asphalt modified with 8% CFR and 1% HNTs (MA/CFR/1% HNTs) showed better dispersibility. The increase of limiting oxygen index and self-ignition temperature and the decrease of heat release rate and smoke production rate of MA/CFR/1% HNTs indicated that it has good flame retardancy. At 64°C, compared with modified asphalt (MA), the rutting factor of MA/CFR/1% HNTs increased by 88.17%, the creep recovery increased, and the irreversible creep decreased, indicating that its high-temperature performance improved significantly. At −18°C , compared with that of MA/CFR, the low-temperature creep stiffness of MA/CFR/1% HNTs decreased by 36 MPa and the creep rate of MA/CFR/1% HNTs increased by 0.034, indicating that only 1% HNTs can improve the effect of degraded CFR on the low-temperature performance of MA. Simultaneously, MA/CFR and MA/CFR/1% HNTs can improve the high-temperature performance and water stability of asphalt mixtures. Adding 1% HNTs to a MA/CFR-modified asphalt mixture can improve the low-temperature performance of the asphalt mixture to the level of the low-temperature performance of the modified asphalt mixture. In summary, the modification of asphalt with 1% HNTs and 8% CFR can effectively improve the flame retardant efficiency and significantly improve the road performance of asphalt. [ABSTRACT FROM AUTHOR]

In order to solve the problems of the smooth surface of basalt fiber and its weak interfacial adhesion with emulsified asphalt cold recycled mixture, a silane coupling agent (KH550) was used to treat the surface of basalt fiber and the effects of treatment concentration and soaking time on fiber modification were studied. The influence of silane coupling-modified basalt fiber (MBF) on the rheological properties of emulsified asphalt evaporation residue was studied at high and low temperatures using three routine index tests: a dynamic shear rheological test (DSR), a bending beam rheological test (BBR), and a force ductility test. The elemental changes of the fiber before and after modification and the microstructure of the emulsified asphalt evaporation residue with the coupling-modified fiber were analyzed by Fourier infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), and X-ray energy dispersive spectroscopy (EDS), which is used to study the modification mechanism of emulsified asphalt evaporation residue reinforced by coupling-modified fiber. The results indicate that the concentration and soaking time of the silane coupling agent have a great influence on the surface morphology and mechanical properties of the fiber, and that the optimal treatment concentration is 1.0% and the optimal soaking time is 60 min. The addition of coupling-modified fibers can reduce the phase angle and unrecoverable creep compliance of emulsified asphalt evaporation residue, increase the rutting factor and creep recovery rate, and improve the elastic recovery ability and permanent deformation resistance. However, excessive fiber will weaken the ductility of emulsified asphalt at low temperatures. The appropriate content of silane coupling-modified fiber (MBF) is 1.5%. After silane coupling modification, the fiber surface becomes rough and cohesion is enhanced between the fiber and the emulsified asphalt base. Silane coupling-modified basalt fiber (MBF) acts as reinforcement for stability and bridging cracks. [ABSTRACT FROM AUTHOR]

In order to improve the safety of the tunnel asphalt pavement in the event of a fire, and reduce the deterioration of the low temperature crack resistance of the asphalt by the flame retardant. The research uses aluminum hydroxide (ATH) as a smoke suppressant, diethyl aluminum hypophosphite (ADP) as a flame retardant, and halloysite nanotubes (HNTs) as a synergist to modified styrene-butadiene-styrene block copolymer (SBS) modified asphalt (MA). First, the content of ATH, ADP, and HNTs was used as the response variable. The physical properties (Penetration, Softening point, Ductility) and static flame retardant properties (Limiting oxygen index meter, Ignition point) of the asphalt modified by nanocomposite flame-retardant (HNTs-CFRMA) were the response variables. The response surface methodology was used to design the test, and regression models were established to analyze the influence of flame retardants on the performance of asphalt. Then, comprehensively considering the effects of physical properties and flame retardant properties, the normalized desirability function was used to perform a multi-objective optimization design on the components of the nanocomposite flame retardant modifier to obtain the best flame retardant formula. Finally, the rheological properties of MA, conventional flame-retardant modified asphalt (CFRMA), and HNTs-CFRMA were tested based on Dynamic shear rheometer, Multiple stress creep test, Force ductility tester, and Bending beam rheometer. The performance of flame-retardant and smoke suppression were tested by the Cone calorimeter tests. The result shows that ATH, ADP, and HNTs can enhance the high temperature performance of asphalt, reduce the penetration. The addition of HNTs can increase significantly the softening point and reduce the deteriorating effect of flame retardants on the low temperature performance of asphalt; the addition of ATH and HNTs can improve significantly the flame retardancy of asphalt. Based on the desirability function of power exponent, the formulation of the nanocomposite flame retardant with better physical properties and flame retardant properties is ATH:ADP:HNTs = 3:5:1, and the total content is 9 wt%. Nanocomposite flame retardants can improve obviously the high temperature rheological properties of asphalt. The rutting factor and the cracking factor of HNTs-CFRMA improve markedly, and the irrecoverable creep compliance is reduced, compared with MA and CFRMA. Nanocomposite flame retardant can make up for the deterioration of conventional flame retardants on asphalt's low temperature performance. At the same time, it has better flame-retardant performance and smoke suppression performance. [ABSTRACT FROM AUTHOR]