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Objectives: This study aimed to evaluate the dentin bond performance of various resin luting cement (RLC) systems combined with universal adhesives in different luting strategies., Materials and Methods: Three self-adhesive resin luting cements (SRLCs) were used with universal adhesives as primers. Twelve specimens per group were prepared to measure shear bond strength (SBS) under distinct luting strategies in etch-&-rinse and self-etch modes. Regarding luting strategies, the bonded specimens were categorized into four groups based on tooth primer application and the curing mode of the SRLC paste: (i) with light irradiation of the tooth primer (wL) + dual-cure mode (DC) of the SRLC paste, (ii) wL + self-cure mode (SC) of the SRLC paste, (iii) without light irradiation of the tooth primer (woL) + DC mode of the SRLC paste, and (iv) woL + SC mode of the SRLC paste. Specimens were also subjected to different storage conditions: 24 h in water (baseline condition) and 10,000 cycles of thermal cycling., Results: Luting strategy, storage condition, and SRLC system type significantly influenced dentin SBS values in both etching modes. Notably, certain SRLCs exhibited significantly higher dentin SBS when the primer was light-irradiated compared with no primer irradiation., Conclusion: Most SRLCs demonstrated higher dentin bond strength with light-irradiated primers, suggesting potential enhancement of dentin bond performance via primer light irradiation., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

This study aimed to observe and compare the resin luting cement (RLC)/dentin interfaces of different types of RLC systems with scanning electron microscopy (SEM). This study evaluated six self-adhesive resin luting cement systems (SARLCs), four systems combining a SARLC with a tooth primer (SARLCPs), and six conventional resin luting cement systems (CVRLCs). Cured resin composite rods were bonded to bovine dentin using RLCs in different etching modes. The morphological features at the interfaces were observed using SEM. Although all RLCs in etch-&-rinse (ER) mode showed a clear hybrid layer, most SARLCs had a thinner and more porous hybrid layer than the SARLCPs and CVRLCs. All SARLCPs with primer and CVRLCs showed a thin high-density layer below the primer layer in both etching modes. CVRLCs and SARLCPs with primer treatment systems may be more versatile and reliable when compared to simplified RLC systems.

Objectives: This study aimed to investigate the immediate dentin bond performance and bond durability of self-adhesive resin luting cements (RLCs) in combination with universal adhesives in different curing modes., Methods: Two self-adhesive RLCs were used with universal adhesives as primers. They were also used alone as self-adhesive RLCs. Two multiple-step RLC systems were used as comparison materials. To measure the shear bond strength (SBS) in different curing modes, 12 specimens were prepared for each group. Stainless-steel rods were bonded to bovine dentin, and the bonded specimens were assigned to the baseline group (stored for 24 h) and artificially aged group (thermal cycling [TC], 10,000 cycles). After each storage period, the SBS of the bonded specimens was measured. The Knoop hardness number (KHN) of the cured RLCs was measured with or without primer application in different curing modes at 24 h and after 10,000 TC. The representative RLC/dentin interfaces were observed using scanning electron microscopy (SEM)., Results: Dentin SBS was significantly influenced by the RLC system but not by the curing mode. Self-adhesive RLCs alone showed significantly lower SBS values than self-adhesive RLCs with primer regardless of the curing mode or storage period. The storage period, curing mode, and RLC system significantly influenced the KHN., Significance: The use of universal adhesives as a primer may help enhance the immediate dentin bond performance and bond durability of self-adhesive RLCs., Competing Interests: Declaration of Competing Interest This study does not contain any studies with human participants and subjects or animals performed by any of the authors., (Copyright © 2024 Elsevier Inc. All rights reserved.)

This study investigated the bonding performance of two different types of resin cements to computer-aided design/computer-aided manufacturing (CAD/CAM) composite blocks based on the shear bond strength (SBS) test. A silane-containing self-adhesive resin cement (Panavia SA Cement Universal) and resin luting cement (Block HC Cem) with a primer, were used. Specimens were fabricated from three different types of CAD/CAM composite blocks, and their surfaces were blasted with alumina. Resin cements were bonded to the specimens, and their SBSs were measured after 15 min, 24 h, and after being subjected to thermal cycling for 10,000 and 30,000 cycles. Three-way ANOVA for bond strength revealed that CAD/CAM composite block, resin cement and storage time significantly influenced the SBS values, and the three-way interactions between the evaluated factors, and all the interactions were significant. It was concluded that the bonding performance of resin cements to CAD/CAM composite blocks were material and storage period dependent.

The purpose of this study was to evaluate the bonding and wear properties of self-adhesive flowable restorative materials. Five self-adhesive flowable restorative materials were used. The study parameters were: (i) shear bond strengths; (ii) microleakage; (iii) occlusal wear; and (iv) qualitative evaluation of the bonding interface. The range of shear bond strengths of the materials was as follows: 7.4-12.2 MPa to ground enamel, 22.5-32.5 MPa to etched enamel, and 1.3-4.2 MPa to dentin. The microleakage scores of the materials did not show any statistically significant differences regardless of the presence or absence of etching. The wear facets on the materials showed 0.099-0.447 mm 3 of volume loss and 148.6-365.3 µm maximum depth, with statistically significant differences between materials. Scanning electron microscopic images of the interfaces of the materials showed good adaptation regardless of substrate. The bonding and wear properties of self-adhesive flowable restorative materials were still limited and showed lower values than previously reported results for nanofilled composites with an adhesive system. Selective enamel etching can improve the bonding performance of these materials., (© 2021 European Journal of Oral Sciences.)

The aim of this study was to determine the influence of different surface treatments of CAD/CAM composite blocks on bonding effectiveness of resin cements, based on the shear bond strength test and the surface science examination. Specimens were fabricated from two types of CAD/CAM composite blocks (Cerasmart and VITA Enamic), and the specimen surfaces were alumina sandblasted. Specimen surfaces were treated with i) silane, ii) primer, and iii) silane+primer, then two types of cements (Block HC Cem and Super Bond) were bonded. After 24 h storage, bond strengths were measured. Surface free energy measurements were performed of the treated CAD/CAM composite blocks surfaces. The groups ii) and iii) showed significantly higher bond strengths than the group i), apart from VITA Enamic with Block HC Cem. Although the total surface free energy showed different trends in different surface treatments, a similar trend was found in both CAD/CAM composite blocks.

The purpose of this study was to examine the shear fatigue strengths of a resin composite bonded to dentin. Three adhesive systems - a two-step self-etch adhesive (OptiBond XTR; Kerr) and two universal adhesives [Scotchbond Universal (3M ESPE) and G-Premio Bond (GC)] - were used in self-etch mode to bond a resin composite to dentin at a physiologic frequency of 2 Hz over 50,000, 100,000, and 1,000,000 cycles. A staircase method of fatigue testing was used. Twenty specimens were used for each test condition. There was no significant difference in shear fatigue strength across the cycling periods for the three individual adhesives. Differences in shear fatigue strength were found among the three adhesives within each cycling period. Regardless of the adhesive used in self-etch mode for bonding a resin composite to dentin, shear fatigue strength was not influenced by the number of cycles used for testing., (© 2018 Eur J Oral Sci.)

In this study, we investigated the effect of light irradiation and primer/adhesive application on the polymerization reaction and elastic modulus (E) of self-adhesive resin cement (SAC) through ultrasonic velocity (V) measurements. The V values of longitudinal and shear waves were determined based on the transit time through the specimens and specimen thicknesses, and were used to calculate the E values. Analysis of variance and Tukey tests revealed that V increased rapidly, reaching a plateau at 2,700-2,900 m/s, when the SACs were light-irradiated. However, the increasing rate of V was retarded for the non-irradiated SACs. In addition, when the primer/adhesive was applied, higher E values were obtained after 24 h. Finally, the polymerization behavior of the SACs was affected by light irradiation and primer application, and the use of prime/adhesive might improve mechanical properties. In clinical situations, use of primer/adhesive is recommended for getting proper adhesion.

Objectives: The purpose of this study was to examine the enamel bond durability of universal adhesives in the self-etch mode under 2-year water storage and thermal cycling conditions., Materials and Methods: Three commercially available universal adhesives and a gold standard two-step self-etch adhesive were used. Ten specimens of bovine enamel were prepared per test group, and shear bond strength (SBS) was measured to determine the bonding durability after thermal cycling (TC) or long-term water storage (WS). The bonded specimens were divided into three groups: (1) specimens subjected to TC, where the bonded specimens were stored in 37 °C distilled water for 24 h before being subjected to 3000, 10,000, 20,000 or 30,000 TC; (2) specimens stored in 37 °C distilled water for 3 months, 6 months, 1 year or 2 year; and (3) specimens stored in 37 °C distilled water for 24 h, serving as a baseline., Results: The two-step self-etch adhesive showed significantly higher SBS than the universal adhesives tested, regardless of the type of degradation method. All universal adhesives showed no significant enamel SBS reductions in TC and WS, when compared to baseline and the other degradation conditions., Conclusions: Compared to the bond strengths obtained with the two-step self-etch adhesive, significantly lower bond strengths were obtained with universal adhesives. However, the enamel bond durability of universal adhesives was relatively stable under both degradation conditions tested., Clinical Relevance: The present data indicate that the enamel bond durability of universal adhesives in the self-etch mode might be sufficient for clinical use.

The effect of phosphoric acid pre-etching on enamel bond fatigue durability of universal adhesives and two-step self-etch adhesives was investigated. Four universal adhesives and three two-step self-etch adhesives were used. The initial shear bond strengths and shear fatigue strengths to enamel with and without phosphoric acid pre-etching using the adhesives were determined. SEM observations were also conducted. Phosphoric acid pre-etching of enamel was found to increase the bond fatigue durability of universal adhesives, but its effect on two-step self-etch adhesives was material-dependent. In addition, some universal adhesives with phosphoric acid pre-etching showed similar bond fatigue durability to the two-step self-etch adhesives, although the bond fatigue durability of universal adhesives in self-etch mode was lower than that of the two-step self-etch adhesives. Phosphoric acid pre-etching enhances enamel bond fatigue durability of universal adhesives, but the effect of phosphoric acid pre-etching on the bond fatigue durability of two-step self-etch adhesives was material-dependent.

Objective: The purpose of this study was to determine the influence of different smear layers on enamel and dentin bond durability of various types of self-etch adhesives., Methods: Two universal adhesives, Scotchbond Universal (SU) and Prime & Bond elect (PE); a conventional single-step self-etch adhesive, G-ænial Bond (GB); and two two-step self-etch adhesives, Optibond XTR (OX) and Clearfil SE Bond (SE) were used in this study. Shear bond strengths (SBS) and shear fatigue strengths (SFS) to human enamel and dentin were determined with different smear layer conditions. The prepared specimens were divided into three groups. The bonding surfaces were prepared by grinding with either (1) #180, (2) #600, or (3) #4000-SiC papers before making the bonded assemblies. For each group, 15 specimens were prepared for the SBS and 30 specimens for the SFS., Results: The two-step self-etch adhesives showed significantly higher SFS values than the single-step self-etch adhesives, regardless of the smear layer condition or substrate. Although most of the tested adhesives showed no significant differences in enamel SFS values among the smear layer groups, SU, GB, and SE showed significantly lower SFS values in the #180 in dentin groups than the #600 and #4000 groups., Conclusion: The influence of different smear layer conditions on bond durability was adhesive dependent. Furthermore, the smear layers generated on different substrates also influenced the bond quality of the self-etch adhesives., Significance: Smear layer conditions of enamel and dentin influence the bond durability of universal adhesives and conventional single and two-step self-etch adhesives., (Copyright © 2017 The Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.)

Objectives: The aim of this study was to determine the effect of double-layer application of universal adhesives on the bond quality and compare to other adhesive systems., Methods: Two universal adhesives used were in this study: Scotchbond Universal (SU), [3M ESPE] and Prime & Bond elect (PE), [Dentsply Caulk]. The conventional single-step self-etch adhesives G-ӕnial Bond (GB), [GC Corporation.] and BeautiBond (BB), [Shofu Inc.], and a two-step self-etch adhesive, Optibond XTR (OX), [Kerr Corporation], were used as comparison adhesives. Shear bond strengths (SBS) and shear fatigue strengths (SFS) to human enamel and dentin were measured in single application mode and double application mode. For each test condition, 15 specimens were prepared for SBS testing and 30 specimens for SFS testing., Results: Enamel and dentin SBS of the universal adhesives in the double application mode were significantly higher than those of the single application mode. In addition, the universal adhesives in the double application mode had significantly higher dentin SFS values than those of the single application mode. The two-step self-etch adhesive OX tended to have lower bond strengths in the double application mode, regardless of the test method or adherent substrate., Conclusion: The double application mode is effective in enhancing SBS and SFS of universal adhesives, but not conventional two-step self-etch adhesives., Significance: These results suggest that, although the double application mode may enhance the bonding quality of a universal adhesive, it may be counter-productive for two-step self-etch adhesives in clinical use., (Copyright © 2017 Elsevier Ltd. All rights reserved.)

The aim of the present study was to determine the influence of different adhesive application methods and etching modes on enamel bond effectiveness of universal adhesives using shear bond strength (SBS) testing and surface free-energy (SFE) measurements. The adhesives Scotchbond Universal, All-Bond Universal, Adhese Universal, and G-Premio Bond were used. Prepared bovine enamel specimens were divided into four groups, based on type of adhesive, and subjected to the following surface treatments: (i) total-etch mode with active application; (ii) total-etch mode with inactive application; (iii) self-etch mode with active application; and (iv) self-etch mode with inactive application. Bonded specimens were subjected to SBS testing. The SFE of the enamel surfaces with adhesive was measured after rinsing with acetone and water. The SBS values in total-etch mode were significantly higher than those in self-etch mode. In total-etch mode, significantly lower SBS values were observed with active application compared with inactive application; in contrast, in self-etch mode there were no significant differences in SBS between active and inactive applications. A reduction in total SFE was observed for active application compared with inactive application. The interaction between etching mode and application method was statistically significant, and the application method significantly affected enamel bond strength in total-etch mode., (© 2017 Eur J Oral Sci.)

Purpose: To evaluate the effects of oxygen inhibition of universal adhesive on dentin bond durability and interfacial characteristics., Methods: The three universal adhesives used were Scotchbond Universal Adhesive, Prime & Bond Elect, and G-Premio Bond. Shear bond strength (SBS) and shear fatigue strength (SFS) of resin composite bonded to adhesive with and without an oxygen inhibited layer (OIL) on dentin using total-etch and self-etch modes were determined. Surface free energy (SFE) and SFE parameters of cured adhesive with and without an OIL on dentin using total-etch and self-etch modes were also measured by the sessile drop method., Results: The presence of an OIL in universal adhesives promoted higher SBS and SFS regardless of etching mode. In addition, regardless of adhesive type and etching modes, the specimens with an OIL showed a higher ratio of SFS/SBS than those without an OIL. Further, the SFEs, especially total SFE, polarity force and hydrogen bonding force, of cured adhesives with an OIL were significantly higher than those without an OIL., Clinical Significance: The present findings indicated that the oxygen inhibition of universal adhesive did not impair the dentin bond durability and interfacial characteristics of the adhesive., Competing Interests: The authors declared no conflict of interest.

The purpose of this study was to determine the relationship between mechanical properties and bond durability of short fiber-reinforced resin composite with universal adhesive. As controls, micro-hybrid and nano-hybrid resin composites were tested. The universal adhesives used were Scotchbond Universal, Adhese Universal, and G-Premio Bond. The fracture toughness and flexural properties of resin composites, and shear bond strength and shear fatigue strength of universal adhesive with resin composite using both total-etch and self-etch modes were determined. In the results, short fiber-reinforced resin composite showed significantly higher fracture toughness than did micro-hybrid and nano-hybrid resin composites. The flexural strength and modulus of short fiber-reinforced and nano-hybrid resin composites were significantly lower than were those of micro-hybrid resin composites. Regardless of etching mode, the shear bond strength of universal adhesives with short fiber-reinforced resin composite did not show any significant differences from micro-hybrid and nano-hybrid resin composites. The shear fatigue strength of universal adhesives with short fiber-reinforced resin composite and micro-hybrid resin composites were significantly higher than that of nano-hybrid resin composites. The results of this study suggest that the mechanical properties of short fiber-reinforced resin composite improve their bond durability with universal adhesive., (© 2016 Eur J Oral Sci.)

Objectives: The purpose of this study was to determine the influence of different frequency rates on of bond durability of self-etch adhesives to enamel using shear fatigue strength (SFS) testing., Methods: A two-step self-etch adhesive (OX, OptiBond XTR), and two single step self-etch adhesives (GB, G-ӕnial Bond and SU, Scotchbond Universal) were used in this study. The shear fatigue strength (SFS) to enamel was obtained. A staircase method was used to determine the SFS values with 50,000 cycles or until failure occurred. Fatigue testing was performed at frequencies of 5Hz, 10Hz, and 20Hz. For each test condition, 30 specimens were prepared for the SFS testing., Results: Regardless of the bond strength test method, OX showed significantly higher SFS values than the two single-step self-etch adhesives. For each of the three individual self-etch adhesives, there was no significant difference in SFS depending on the frequency rate, although 20Hz results tended to be higher., Conclusions: Regardless of the self-etch adhesive system, frequencies of 5Hz, 10Hz, and 20Hz produced similar results in fatigue strength of resin composite bonded to enamel using 50,000 cycles or until bond failure., Significance: Accelerated fatigue testing provides valuable information regarding the long term durability of resin composite to enamel bonding using self-etch adhesive system., (Copyright © 2016 Elsevier Ltd. All rights reserved.)

The purpose of this study was to evaluate the influence of duration of phosphoric acid pre-etching on the bond durability of universal adhesives and the surface free-energy characteristics of enamel. Three universal adhesives and extracted human molars were used. Two no-pre-etching groups were prepared: ground enamel; and enamel after ultrasonic cleaning with distilled water for 30 s to remove the smear layer. Four pre-etching groups were prepared: enamel pre-etched with phosphoric acid for 3, 5, 10, and 15 s. Shear bond strength (SBS) values of universal adhesive after no thermal cycling and after 30,000 or 60,000 thermal cycles, and surface free-energy values of enamel surfaces, calculated from contact angle measurements, were determined. The specimens that had been pre-etched showed significantly higher SBS and surface free-energy values than the specimens that had not been pre-etched, regardless of the aging condition and adhesive type. The SBS and surface free-energy values did not increase for pre-etching times of longer than 3 s. There were no significant differences in SBS values and surface free-energy characteristics between the specimens with and without a smear layer. The results of this study suggest that phosphoric acid pre-etching of enamel improves the bond durability of universal adhesives and the surface free-energy characteristics of enamel, but these bonding properties do not increase for phosphoric acid pre-etching times of longer than 3 s., (© 2016 Eur J Oral Sci.)

The purpose of this study was to investigate the shear bond strength (SBS) and surface free-energy (SFE) of short fiber-reinforced resin composite (SFRC), using different adhesive systems, in comparison with other composite restoratives. The resin composites used were everX Posterior (EP), Clearfil AP-X (CA), and Filtek Supreme Ultra Universal Restorative (FS). The adhesive systems used were Scotchbond Multi-Purpose (SM), Clearfil SE Bond (CS), and G-Premio Bond (GB). Resin composite was bonded to dentin, and SBS was determined after 24 h of storage in distilled water and after 10,000 thermal cycles (TCs). The SFEs of the resin composites and the adhesives were determined by measuring the contact angles of three test liquids. The SFE values and SFE characteristics were not influenced by the type of resin composite, but were influenced by the type of adhesive system. The results of this study suggest that the bonding performance and interfacial characteristics of SFRC are the same as for other composite restoratives, but that these parameters are affected by the type of adhesive system. The bonding performance of SFRC was enhanced by thermal cycling in a manner similar to that for other composite restoratives., (© 2016 Eur J Oral Sci.)

Purpose: To examine the influence of the oxygen inhibited layer (OIL) on shear bond strength (SBS) to dentin and surface free energy (SFE) characteristics of different adhesive systems., Materials and Methods: Three adhesive systems were used: Scotchbond Multipurpose (SM), Clearfil SE Bond (CS), and Scotchbond Universal (SU). Resin composite was bonded to dentin surfaces to determine SBS with and without OIL of adhesives. The SFE, dispersion force (γSd), polarity force (γSp), and hydrogen bonding force (γSh) of cured adhesives with and without an OIL were measured. Two-way ANOVA and Tukey's honestly significant difference (HSD) test were used for analysis of SBS data, and one-way ANOVA and Tukey's HSD test were used for the SFE and contact angle data., Results: The SBS of SM and CS showed no significant differences between specimens with and without the OIL. However, the SBS of SU with the OIL was significantly higher than without the OIL. The SFE, γSp, and γSh of cured adhesives with an OIL were significantly higher than those of cured adhesives without an OIL. The SFE, γSp, and γSh of SM and CS with an OIL were significantly higher than those of SU with an OIL., Conclusion: The results of this study indicate that the presence of an OIL with a single-step self-etching adhesive promotes higher SBS to dentin, unlike in the other types of adhesive systems. The SFE characteristics of the OIL of dental adhesives differed depending on the type of adhesive system.

Purpose: To use shear bond strength (SBS) and shear fatigue strength (SFS) testing to determine the influence of phosphoric acid pre-etching times prior to application of self-etch adhesives on enamel bonding., Materials and Methods: Two single-step self-etch universal adhesives (Prime&Bond Elect and Scotchbond Universal), a conventional single-step self-etch adhesive (G-ӕnial Bond), and a conventional two-step self-etch adhesive (OptiBond XTR) were used. The SBS and SFS were obtained with phosphoric acid pre-etching for 3, 10, or 15 s prior to application of the adhesives, and without pre-etching (0 s) as a control. A staircase method was used to determine the SFS with 10 Hz frequency for 50,000 cycles or until failure occurred. The mean demineralization depth for each treated enamel surface was also measured using a profilometer., Results: For all the adhesives, the groups with pre-etching showed significantly higher SBS and SFS than groups without pre-etching. However, there was no significant difference in SBS and SFS among groups with > 3 s of preetching. In addition, although the groups with pre-etching showed significantly deeper demineralization depths than groups without pre-etching, there was no significant difference in depth among groups with > 3 s of pre-etching., Conclusion: Three seconds of phosphoric acid pre-etching prior to application of self-etch adhesive can enhance enamel bonding effectiveness.

In this clinical study, we evaluated the 3-year clinical performance of a resin composite containing a surface-prereacted glass ionomer (S-PRG) filler (Beautifil II; Shofu Inc., Kyoto, Japan) placed with a single-step self-etch adhesive (BeautiBond; Shofu Inc.) in posterior restorations. Using modified US Public Health Service criteria, two experienced investigators performed clinical evaluations at the baseline, 6 months, 18 months, and 3 years. Color match, marginal adaptation, anatomical form, surface roughness, marginal discoloration, postoperative sensitivity, and secondary caries were evaluated. After 3 years, 26 patients attended the recall and 31 restorations were evaluated. No postoperative sensitivity or secondary caries was observed at any time point, and no restorations failed during the follow-up period. However, surface roughness, marginal adaptation, and marginal discoloration showed deterioration after 3 years. In conclusion, although some clinical changes were observed, resin composite containing S-PRG filler placed with self-etch adhesive exhibited acceptable clinical behavior in posterior restorations.

The influence of methyl mercaptan on the repair bond strength of composites fabricated using self-etch adhesives was investigated. The surface free-energies were determined by measuring the contact angles of test liquids placed on composites that had been immersed in different concentrations of methyl mercaptan (0.01, 0.1, and 1.0 M). To determine the repair bond strength, self-etch adhesives were applied to the aged composite, and then newly added composites were condensed. Ten samples of each specimen were subjected to shear testing at a crosshead speed of 1.0 mm min(-1). Samples were analyzed using two-way ANOVA followed by Tukey's honestly significant difference (HSD) test. Although the dispersion force of the composites remained relatively constant, their polar force increased slightly as the concentration of methyl mercaptan increased. The hydrogen-bonding forces were significantly higher after immersion in 1.0 M methyl mercaptan, leading to higher surface-free energies. However, the repair bond strengths for the repair restorations prepared from composites immersed in 1.0 M methyl mercaptan were significantly lower than for those immersed in 0.01 and 0.10 M methyl mercaptan. Considering the results of this study, it can be concluded that the repair bond strengths of both the aged and newly added composites were affected by immersion in methyl mercaptan solutions., (© 2014 Eur J Oral Sci.)

Influences of contamination and cleaning methods on the bonding of resin cement to zirconia ceramics were examined. Airborne particle-abraded zirconia (IPS e.max ZirCAD) specimens were contaminated with saliva and cleaned with tap water (SC) or by application of 37% phosphoric acid (PA), Ivoclean (IC), or additional airborne particle abrasion (AB). Specimens without contamination served as controls. After application of Monobond Plus to the surface of the specimens, resin cement was mixed and inserted into a mold. Surface free energies of the specimens were determined by measuring contact angles. Surface treatment and storage conditions significantly influenced bond strength, while there was no significant interaction between the two factors. Surface free energies of the SC and IC groups were significantly lower than those of the other groups. Additional AB of saliva-contaminated zirconia increased the strength of bonding with the resin cement as well as increased surface free energy.

Purpose: To evaluate the effects of a surface pre-reacted glass-ionomer (S-PRG) filled coating material to arrest artificial enamel lesions in primary teeth., Methods: Buccal and lingual enamel was demineralized in 0.1 M lactic acid buffer solution (pH 4.75) for 5 days and then divided in the PRG-applied and non-PRG areas. Proximal surfaces were used as a control area without demineralization and coating application. Teeth were divided into three groups (n = 4) according to the 1-week immersion in different solutions: Group 1 (distilled water), Group 2 (demineralizing solution) and Group 3 (artificial saliva). Hardness and Young's modulus by nano-indentation test, and elemental contents and ultrastructure by SEM/EDX analysis were obtained. Data were statistically analyzed using ANOVA and Fisher's PLSD at alpha = 0.05., Results: Only for the non-PRG area in Group 1, the hardness and Young's modulus of the demineralized surface enamel were significantly lower than those of the enamel 30-60 microm beneath the surface. Demineralized enamel of non-PRG and PRG-applied areas showed similar SEM views. Only for the non-PRG area in Group 2 and control area in Group 3, the Ca/P of the surface enamel was significantly higher than that of the enamel 5-10 microm beneath the surface. There was no significant difference of the Ca/P among the measuring points from the surface to 10 microm depth of enamel for the PRG applied area in Group 2.

We examined the effect of warm air-drying on the enamel bond strengths and the surface free-energy of three single-step self-etch adhesives. Bovine mandibular incisors were mounted in self-curing resin and then wet ground with #600 silicon carbide (SiC) paper. The adhesives were applied according to the instructions of the respective manufacturers and then dried in a stream of normal (23°C) or warm (37°C) air for 5, 10, and 20 s. After visible-light irradiation of the adhesives, resin composites were condensed into a mold and polymerized. Ten samples per test group were stored in distilled water at 37°C for 24 h and then the bond strengths were measured. The surface free-energies were determined by measuring the contact angles of three test liquids placed on the cured adhesives. The enamel bond strengths varied according to the air-drying time and ranged from 15.8 to 19.1 MPa. The trends for the bond strengths were different among the materials. The value of the γS⁺ component increased slightly when drying was performed with a stream of warm air, whereas that of the γS⁻ component decreased significantly. These data suggest that warm air-drying is essential to obtain adequate enamel bond strengths, although increasing the drying time did not significantly influence the bond strength., (© 2013 Eur J Oral Sci.)

Objective: To use ultrasonic measurements to monitor the effects of adhesive application and power density on the polymerization behavior of dual-cured core build-up resins., Methods: Ultrasonic measurements were carried out using a pulser-receiver, transducers and an oscilloscope. The core build-up resins were mixed, inserted into a transparent mold and then placed onto a sample stage with or without self-etch adhesive. Power densities of 0 (no light irradiation), 200 and 600 mW/cm(2) were used for curing. The transit time through the core build-up resin disk was divided by the specimen thickness to obtain the longitudinal sound velocity (V)., Results: Light irradiation of the core build-up resins at a power density of 600 mW/cm(2) caused V values to rise to an initial plateau of 1550-1650 m/s, then to rise rapidly to a second plateau of 2800-3200 m/s. The rate of V increase was slower when the resin cements were light-irradiated and became faster when irradiated at a higher power density. There were no significant differences between the groups with or without adhesive., Conclusions: The polymerization behavior of the core build-up resins was affected by the power density of the curing unit. The influence of adhesive application differed among the core build-up resins tested.

Objectives: The surface free energy and dentine bond strength of self-adhesive cements were examined after the removal of temporary cements., Methods: The labial dentine surfaces of bovine mandibular incisors were wet ground with #600-grit SiC paper. Acrylic resin blocks were luted to the prepared dentine surfaces using HY Bond Temporary Cement Hard (HY), IP Temp Cement (IP), Fuji TEMP (FT) or Freegenol Temporary Cement (TC), and stored for 1 week. After removal of the temporary cements with an ultrasonic tip, the contact angle values of five specimens per test group were determined for the three test liquids, and the surface-energy parameters of the dentine surfaces were calculated. The dentine bond strengths of the self-adhesive cements were measured after removal of the temporary cements in a shear mode at a crosshead speed of 1.0mm/min. The data were subjected to one-way analysis of variance (ANOVA) followed by Tukey's HSD test., Results: For all surfaces, the value of the estimated surface tension component γ(S)(d) (dispersion) was relatively constant at 41.7-43.3 mJm(-2). After removal of the temporary cements, the value of the γ(S)(h) (hydrogen-bonding) component decreased, particularly with FT and TC. The dentine bond strength of the self-adhesive cements was significantly higher for those without temporary cement contamination (8.2-10.6 MPa) than for those with temporary cement contamination (4.3-7.1 MPa)., Conclusions: The γ(S) values decreased due to the decrease of γ(S)(h) values for the temporary cement-contaminated dentine. Contamination with temporary cements led to lower dentine bond strength., Clinical Significance: The presence of temporary cement interferes with the bonding performance of self-adhesive cements to dentine. Care should be taken in the methods of removal of temporary cement when using self-adhesive cements., (Copyright © 2011 Elsevier Ltd. All rights reserved.)

The effect of warm air-drying on the dentin bond strengths of the single-step self-etch adhesives was determined. The adhesives were applied to bovine dentin followed by drying in a stream of warm air for 5, 10, and 15 s at 37°C. Resin composites were condensed into a mold and polymerized. Specimens were stored in distilled water at 37°C for 24 h, then shear tested. The surface free-energies were determined by measuring the contact angles of three test liquids placed on the cured adhesives. The dentin bond strengths varied according to the air-drying time. The value of the acid component increased slightly when drying was performed with a stream of warm air, whereas that of the base component decreased significantly. These data suggested that warm air-drying was essential to obtain adequate bond strengths, although increasing the drying time did not significantly influence the bond strength.

Purpose: Single-step self-etching adhesives have been developed as a bonding material that adheres to the tooth surface. The adhesives contain acidic resin monomers that penetrate the dentin but can be neutralized to stop the reaction. This study aimed to improve understanding of the pH changes that occur when self-etching adhesives are mixed with dentin powder., Materials and Methods: Dentin disks obtained from extracted bovine incisors were milled and pulverized into a fine powder. The powder was mixed with diluted self-etching adhesives, and pH changes were measured by a solid-state pH sensor connected to a pH meter at various time points after the start of mixing. Data were analyzed by Tukey's Honestly Significant Difference (HSD) test and Dunnett's test at a significance level of 0.05. Precipitates from the adhesive/ dentin powder mixture were observed by scanning electron microscopy (SEM)., Results: The baseline pH values of the self-etching adhesives ranged from 0.97 to 2.83. After mixing with the dentin powder, the pH values significantly increased, ranging from 6.30 to 7.11 at 180 s after mixing. SEM observation revealed products of the reaction between dentin powder and self-etching adhesive which indicate a chemical reaction between the functional monomer and dentin., Conclusion: Dentin has a strong modulation effect against the acidity of self-etching adhesives.

This study examined the surface free-energy of dentin treated with the single-step self-etching adhesives Bond Force, Clearfil tri-S Bond, and G-Bond Plus. The labial dentin surfaces of bovine mandibular incisors were wet ground with #180-, #600-, and #2,000-grit silicon carbide paper. The adhesives were applied to the ground dentin, and then rinsed with acetone and distilled water. The surface free-energies were determined by measuring the contact angles of three test liquids placed on the adhesive-treated dentin. The surface free-energies of the samples treated with the G-Bond Plus and Clearfil tri-S Bond adhesives increased as the surface roughness decreased. No significant differences in the surface free-energy were found for the samples treated with the Bond Force adhesive, regardless of the surface roughness. These results indicated that dentin surfaces treated with adhesives did not promote a higher surface-energy state, and that differences in the components of surface energy were apparent for the adhesives tested., (© 2010 Eur J Oral Sci.)

We used ultrasonic measurements to monitor the influence of power density and primer application on the polymerization reaction of dual-cured resin cements. The ultrasonic equipment comprised a pulser-receiver, transducers, and an oscilloscope. Resin cements were mixed and inserted into a transparent mould, and specimens were placed on the sample stage, onto which the primer, if used, was also applied. Power densities of 0 (no irradiation), 200, or 600 mW cm(-2) were used for curing. The transit time through the cement disk was divided by the specimen thickness to obtain the longitudinal sound velocity. When resin cements were light-irradiated, each curve displayed an initial plateau of approximately 1,500 m s(-1), which rapidly increased to a second plateau of 2,300-2,900 m s(-1). The rate of sound velocity increase was retarded when the cements were light-irradiated at lower power densities, and increased when the primer was applied. The polymerization behaviour of dual-cured resin cements was therefore shown to be affected by the power density of the curing unit and the application of self-etching primer., ((c) 2010 The Authors. Journal compilation (c) 2010 Eur J Oral Sci.)

This study examined the relationship between the adhesive application time and enamel bond strength of several single-step self-etch adhesive systems. The adhesives used were: Bond Force (BF, Tokuyama Dental Corporation, Tokyo, Japan), Clearfil tri-S Bond (CT, Kuraray Medical Inc, Tokyo, Japan), iBond Self-Etch (IB, Heraeus Kulzer, Armonk, NY) and OptiBond All-in-One (OB, sds Kerr). Bovine mandibular incisors were mounted in self-curing resin and wet ground with #600-grit silicon carbide paper to expose labial enamel. Adhesives were applied for 10, 20 or 40 seconds and the resin composites were condensed into a mold (phi4 x 2 mm) on the enamel and light irradiated. Ten samples per test group were stored in 37 degrees C water for 24 hours, then shear tested at a crosshead speed of 1.0 mm/minute. One-way ANOVA and the Tukey HSD test (alpha = 0.05) were performed within each adhesive system. The enamel surfaces after adhesive application were also observed in a Field Emission Electron Probe Surface Roughness Analyzer and the Ra value was calculated. The enamel bond strength ranged from 13.6 to 17.8 MPa for BF, 13.6 to 15.9 MPa for CT, 14.3 to 16.2 MPa for IB and 13.4 to 19.8 MPa for OB. Significant increases in bond strength were found for the 40-second application groups, except for IB. No changes in Ra value were found for BF and IB, while significant decreases in Ra value were recorded with 40-second application for CT and OB. The data suggested that the duration of the single-step self-etch adhesive application was a crucial factor for determining the enamel bond strengths of some of the single-step self-etch adhesives employed in the current study.

The purpose of this study was to investigate the effect of previous phosphoric acid etching on the dentin bond strength of single-step self-etch adhesive systems. Facial surfaces of bovine teeth were wet ground with #600 SiC paper. Adhesives were applied with and without previous phosphoric acid etching, and light irradiated. Resin composite was bonded to the adherend surface, followed by light irradiation and storage in water at 37 degrees C. Four groups (n = 10) were made per adhesive system: with and without previous acid etching and with and without thermal cycling between 5 degrees C and 55 degrees C for 10,000 cycles. Specimens were tested in a shear mode at a crosshead speed of 1.0 mm/min. Two-way ANOVA and Tukey HSD test at a level of 0.05 were performed. The changes in dentin bond strengths were different among the adhesive systems tested. In all experimental conditions of this study, the dentin bond strength decreased or remained unchanged with previous acid etching. From the results of this study, previous acid etching might not be acceptable for increasing dentin bond strength of the single-step self-etch adhesive systems.

The purpose of this study was to investigate the development of shear bond strength of resin composites using self-etching primer systems. Four different types of self-etching primer systems with different combinations of their recommended resin composites were used. Bovine incisors were mounted in self-curing resin and the facial surfaces were wet ground on #600-SiC paper to expose the dentin. The shear bond strengths of ten samples per test group were measured at a crosshead speed of 1.0 mm/min after storage for 5, 10, and 60 min, and 24 h in distilled water at 37 degrees C. One-way ANOVA followed by Dunnett's test (alpha = 0.05) was used to examine the significance of differences between the mean bond strength at 24 h and each of the other storage periods. The dentin bond strengths of all the materials tested increased with prolonged storage time. Such differences in the changes in bond strength might have clinical implications if a restoration is subjected to high stress immediately after it has been placed. It is important to consider the development of dentin bond strength to allow the materials sufficient maturation time prior to functional loading or application of other forms of external stress.

This study investigated the effect of phosphoric acid etching on the dentin bond strength of five single-step self-etch adhesive systems; Absolute, Clearfil tri-S Bond, Fluoro Bond Shake One, G-Bond and One-Up Bond F Plus. Bovine mandibular incisors were mounted in self-curing resin and the facial surfaces were wet ground with #600 SiC paper. Adhesives were applied on the prepared dentin surfaces with and without prior phosphoric acid etching and light irradiated. Resin composite was condensed into a mold (ø4x2 mm), light irradiated and stored in water at 37 degrees C. Four groups (n=10) were made per adhesive system: with and without prior acid etching and with and without thermal cycling between 5 degrees C and 55 degrees C for 10,000 cycles. The specimens were tested in a shear mode at a crosshead speed of 1.0 mm/minute. Two-way ANOVA, Student t-test and Tukey HSD test at a level of 0.05 were done. For specimens without prior acid etching, the mean bond strengths to bovine dentin ranged from 12.8 to 17.1 MPa and ranged from 6.7 to 13.3 MPa for specimens with prior acid etching after 24 hours storage in water. When the specimens were subjected to thermal cycling, the mean bond strengths ranged from 10.7 to 24.8 MPa for the specimens without prior acid etching and 4.6 to 13.9 MPa for the specimens with prior acid etching. The changes in dentin bond strength were different among the adhesive systems tested. Failure modes were commonly adhesive failure associated with mixed failure for specimens with prior acid etching. For specimens without prior acid etching, failures in composite and dentin were increased. From the results of this in vitro study, prior acid etching might be not acceptable for increasing the dentin bond strengths of single-step self-etch adhesive systems.

The influence of temperature and relative humidity (RH) on the bond strength of orthodontic adhesives was investigated. Two self-etching/composite type, one acid-etching/composite type, and one acid-etching/PMMA type of adhesives were examined under different temperature and RH conditions. Orthodontic brackets were bonded to bovine enamel, and shear bond strength test was performed at a crosshead speed of 1.0 mm/min after 24-hour storage in 37 degrees C water. Data were analyzed by Tukey's HSD test. Each specimen was assigned an ARI score. All the materials tested exhibited their highest bond strength under room conditions at a range of 10.4-17.0 MPa. Conversely, when under a lower RH condition, bond strength for all the systems ranked the lowest within a range of 6.8-12.0 MPa, with bond failure at the bracket-adhesive interface. These results demonstrated that care should be exercised when using orthodontic adhesive systems in the oral environment.

The purpose of this study was to examine the microtensile bond strength of a single-step self-etch adhesive system (Clearfil tri-S Bond and One-Up Bond F Plus) to bovine dentin. Adhesive was applied to a flat dentin surface, and resin composite was bonded according to the manufacturers' instructions. After 24 h storage in distilled water at 37 degrees C, hourglass-shaped specimens were produced. These were subjected to microtensile bond strength testing at a cross-head speed of 1.0 mm/min. The results were analyzed using Student's t-test at a significance level of 0.05. Field-emission scanning electron microscopy (FE-SEM) observations of the fractured specimens and the adhesive-treated dentin surfaces were also conducted. The bond strength of Clearfil tri-S Bond was not significantly different from that of One-Up Bond F Plus, 41.1 +/- 10.1 versus 42.3 +/- 6.0 MPa. Mode of failure analysis for Clearfil tri-S Bond revealed an equal distribution between the three types of failure, and the predominant mode of failure was adhesive for One-Up Bond F Plus. FE-SEM observations of dentin to which adhesive had been applied revealed that the smear layer had been removed and the collagen fibers exposed.

The purpose of this study was to determine ultrasonically the changes in elastic modulus of demineralized adhesive-infiltrated dentin. Dentin disks were obtained from bovine incisors and shaped into a rectangular form. The specimens were immersed in single-step self-etch adhesives, then stored in distilled water and run through thermal cycles between 5 and 60 degrees C. The longitudinal and shear wave sound velocities and the elastic modulus were determined using ultrasonic equipment composed of a pulser-receiver, transducers, and an oscilloscope. After 24 h of storage, the elastic modulus of mineralized dentin was 16.9 GPa and that of demineralized dentin was 2.1 GPa. The immersion of demineralized dentin in adhesives significantly increased the elastic modulus to 3.3-5.9 GPa. After 30,000 thermal cycles, the elastic modulus of dentin was 32.4 GPa, whereas that of demineralized adhesive infiltrated dentin was 3.1-4.1 GPa. Thermal stresses did not cause adhesive-infiltrated demineralized dentin to deteriorate, as measured by elastic modulus.

This study evaluated the clinical performance of five single-step self-etch adhesive systems over a one-year follow-up period in 98 restorations. Independent evaluations were performed at baseline (one week), after three months, six months, and one year, by two trained examiners using the modified US Public Health Service rating criteria. Color match, marginal integrity, anatomical form, surface roughness, marginal or interfacial staining, postoperative sensitivity, and secondary caries were evaluated. Results were analyzed using the Kruskal-Wallis test at a significance level of p<0.05. After one year, the restorations were re-evaluated and 100% retention rate was recorded. No caries were detected in association with any of the restorations. Marginal adaptation was the only measure that showed a slight deterioration over time, and there were no significant differences in this factor among the adhesive systems tested (p=0.464).

Introduction: Tests of bond strength between orthodontic brackets and enamel are generally conducted after at least 24 hours storage in water. However, debonding might occur soon after bracket placement during orthodontic treatment. We investigated the rate of bond strength development for orthodontic adhesives in bracket bonding., Methods: Four orthodontic adhesive systems were examined. Bovine incisors were mounted in self-curing acrylic resin, and the facial surfaces were wet-ground to expose flat enamel. Orthodontic brackets were bonded according to the manufacturers' instructions. Shear bond strengths were measured after storage in water for 5, 10, and 60 minutes, and 24 hours. Differences between bond strengths at 24 hours and the other test periods were statistically analyzed., Results: All materials tested had the highest bond strengths at 24 hours, and bond strength increased with storage time. The earliest time point at which there was no significant difference in bond strength compared with that at 24 hours was defined as the initial stable time. Differences in this value might have clinical implications for the assessment of orthodontic adhesives, which can incur high stresses immediately after placement., Conclusions: The rate of development of enamel bond strength must be considered to ensure sufficient maturation of orthodontic adhesives before functional loading.

This study was conducted to clarify the influence of dentin surface moisture on bond strength of single-step self-etch adhesive systems. The adhesive systems used were Adper Prompt L-Pop (AP), Clearfil tri-S Bond (CT), Fluoro Bond Shake One (FB), G-Bond (GB), and One-Up Bond F Plus (OF). Bovine mandibular incisors were wet-ground with #600 SiC to expose the labial dentin. After rinsing with tap water, the dentin surface was dried with air for 10 sec (Dry condition) or blotted (Wet condition). Adhesives were applied according to each manufacturer's instructions, followed by resin composite polymerization. Ten samples per test group were stored in distilled water at 37 degrees C for 24 h, then shear tested at a crosshead speed of 1.0 mm/min. The data were analyzed by Student's t test and Tukey HSD test at a probability level of 0.05. The mean bond strengths for Dry condition ranged from 13.9 MPa to 18.2 MPa, and those for Wet condition ranged from 7.1 MPa to 18.4 MPa. Significantly lower bond strengths were obtained for the Wet condition for GB, FB, and OF. Failure after the test was commonly due to adhesive breakdown associated with partial cohesive failure in the dentin. These data suggest that air-drying of the dentin surface is appropriate for the adhesive systems tested.

Purpose: To investigate the influence of utilizing films with different oxygen transmission rates (O2-GTR) on Knoop hardness and toothbrush abrasion of resin cements for luting., Methods: Four dual-activated, composite-type resin cements, and a chemically activated PMMA-type resin cement, were used. Three different types of barrier films (Techbarrier HI, Harden Film N130, and Lix-2) were used. Resin cement was mixed and inserted into a cylindrical mold (4 mm in diameter, 3 mm in height), then chemically activated. The specimens were stored in the dark at 37 +/- 1 degrees C, 90 +/- 5%RH conditions for 1 hour. Knoop hardness on the top surface of the resin cement was measured with a microhardness tester. The top surface of specimens (8 mm in diameter, 3 mm in height) polymerized under the same conditions were used for toothbrush abrasion testing. One-way ANOVA followed by Tukey HSD test (P< 0.05) were done., Results: When the cement surface was covered by low O2-GTR film, a significant increase in Knoop hardness and resistance to toothbrush abrasion was observed for the dual activated, composite-type resin cements, but not for the chemically activated PMMA type resin cement. From the results of this study, the use of low O2-GTR matrix barrier films for the dual activated, composite-type resin cements could be effective in eliminating the oxygen inhibited layer on the cement surface.

The purpose of this study was to clarify the effect of thermal cycling on dentin bond strengths of single-step self-etch adhesives. Five commercially available single-step self-etch systems were used. The adhesives were applied to the dentin surfaces of bovine incisors, and then light-irradiated. Resin composites were condensed into a mold and light-irradiated. Bonded specimens were divided into two groups and stored in water at 37 degrees C for 24 h without thermal cycling, or in water at 37 degrees C for 24 h followed by 10,000 thermal cycles between 5 degrees C and 60 degrees C. Ten samples per group were tested for shear strength at a crosshead speed of 1.0 mm/min. The data were analyzed by Student's t test and Tukey HSD test at a probability level of 0.05. After 24 h of storage in water, the mean dentin bond strengths ranged from 9.3 MPa to 14.0 MPa. After 10,000 thermal cycles, the mean bond strengths remained unchanged. Failure after the test was commonly due to adhesive breakdown associated with partial cohesive failure of the resin. The present results suggest that the benefit of using single-step self-etch systems, in terms of simplifying the clinical procedure, might be acceptable even after thermal stresses.

Objectives: The purpose of this study was to determine the influence of crosshead speed on the micro-tensile bond strength of two separate adhesive systems to dentin., Methods: The systems used were the Clearfil SE Bond (Kuraray Medical) and the Single Bond (3M ESPE) combined with a resin composite Clearfil AP-X (Kuraray Medical). Dentin surfaces of bovine madibular incisors were primed with self-etching primer followed by air blowing for Clearfil SE Bond, or etched with phosphoric acid followed by rinsing with distilled water for Single Bond, and adhesive was applied. The resin composite was then built up in three layers and light activated. After 24 h storage in water, specimens were sectioned and trimmed to a cross-sectional area of 1 mm(2) and subjected to a micro-tensile bond-strength test. Ten samples per test group were tested at crosshead speeds of 0.5, 1.0, 5.0 and 10.0 mm/min. Micro-tensile bond-strength values (in MPa) were calculated from the peak load at failure divided by the specimen surface area. Two-way ANOVA was performed at the 0.05 probability level., Results: The mean dentin bond strength at different crosshead speeds ranged from 34.6 to 37.1MPa for Clearfil SE Bond and from 44.3 to 50.4 MPa for Single Bond. There was no significant difference among the same adhesive systems with the different crosshead speeds tested., Significance: The influence of the crosshead speed might be negligible when measuring micro-tensile bond strengths.

The purpose of this study was to investigate the influence of light intensity on dentin bond strengths of four self-etch adhesive systems. The light intensities used to polymerize specimens were controlled at levels of 150, 300, 600, and 900 mW/cm2. The two-step self-etch adhesive systems Imperva Fluoro Bond and Mac Bond II, and the one-step self-etch systems Fluoro Bond Shake-One and One-Up Bond F Plus were used with their corresponding light-cured resins. Labial surfaces of lower bovine incisors were ground with #600 grit SiC paper to expose the dentin. The dentin surfaces were treated according to each manufacturer's instructions and bonded with resin composites. A shear bond strength test was performed and the data were analyzed by one-way ANOVA followed by Newman-Keuls multiple comparison at a level of 0.05. Statistical analysis of the data indicated that light intensity affected the dentin bond strengths of the adhesive systems tested. Significantly lower bond strengths were obtained by exposure to 150 mW/cm2, and there were no differences between the bond strengths obtained at 600 and 900 mW/cm2 for all the adhesive systems used. Further research will be required to clarify the irradiance-dependent properties of light-cured resin adhesive systems.

This study examined the relationship between delay in composite placement over cured adhesives and the dentin bond strength of several single-application self-etch adhesive systems. The adhesive system/resin composite combinations used were: Adper Prompt L-Pop/Filtek Z250 (AP), AQ Bond Plus/Metafil C (AQ), Fluoro Bond Shake One/Beautifil (FB), G-Bond/Solare (GB), One-Up Bond F Plus/Palfique Estelite (OF), Xeno IICF Bond/Xeno CF (XE). Bovine mandibular incisors were mounted in self-curing resin and wet ground with #600 SiC to expose labial dentin. The adhesives were applied according to each manufacturer's instructions, and resin pastes were condensed into a mold (ø4x2 mm) immediately, and 1, 2, 5 and 10 minutes after light irradiation of the adhesives. Ten samples per test group were stored in 37 degrees C water for 24 hours, then shear tested at a crosshead speed of 1.0 mm/minute. One-way ANOVA followed by Tukey's HSD test (alpha = 0.05) was done. SEM observations of the dentin surface after the tests were also conducted. Dentin bond strength ranged from 9.5 +/- 2.2 to 14.0 +/- 2.4 MPa for AP, 7.3 +/- 2.2 to 12.2 +/- 3.1 MPa for AQ, 10.0 +/- 3.5 to 16.3 +/- 2.4 MPa for FB, 11.4 +/- 1.5 to 16.3 +/- 1.2 MPa for GB, 14.2 +/- 3.4 to 15.1 +/- 3.0 MPa for OF and 11.5 +/- 2.4 to 15.9 +/- 2.2 MPa for XE. Except for OF, no significant differences were found among the 2 to 10 minute delayed placement groups for the systems used. Significant lower bond strengths were obtained for the immediate placement groups except for OF. From SEM observations, cohesive failure of the dentin surface was more pronounced with the longer delay in placement. The data suggest that delayed composite placement over the cured adhesives are suggested for optimum dentin bond strength of single-application self-etch adhesive systems.

This study aimed to determine the influence of metal conditioners on the polymerization behavior of bonding agents. Bonding agents of two-step self-etching primer systems and metal conditioners for adhesion of dental metal alloys were used. Double bond conversion was determined by Fourier transform-ation infrared spectroscopy. The percentage of residual double bonds, including pendant and monomeric double bonds, was calculated by comparing the obtained ratio with that of the uncured bonding agent. The degree of conversion of the bonding agents was obtained by subtracting the remaining double bonds from 100%. ANOVA followed by a Tukey HDS test was performed. Degree of conversion of the bonding agents ranged from 86.0 to 87.8%. When the bonding agents were mixed with metal conditioners or solvents of the metal conditioners, double bond conversion of the bonding agents tended to decrease. Within the limitations of this study, which was far removed from clinical situations, the presence of metal conditioners and remaining solvents had adverse effects on the polymerization reaction of bonding agents. Clinicians should be cognizant of the various factors that can influence bond strength of restorative resins to dentin.

The purpose of this study was to determine the elastic moduli of the components at resin-dentin interface with the use of an ultrasonic device. Dentin plates were obtained from freshly extracted bovine incisors with a shape in rectangular form. Resin composites and bonding agents were polymerized and trimmed in the same shape as the dentin specimens. The ultrasonic equipment employed in this study was comprised of a Pulser-Receiver, transducers, and an oscilloscope. Each elastic modulus was determined by measuring the longitudinal and shear wave sound velocities. The mean elastic modulus of mineralized dentin was 17.4 GPa, while that of demineralized dentin was 1.4 GPa. When the demineralized dentin was immersed in bonding agents, the elastic modulus changed to 3.7-4.7 GPa, and these values were significantly higher than those of demineralized dentin. A gradient in elastic modulus was detected as the analysis shifted from the dentin side to the resin composite.

This study determined the influence of interchanging adhesive resins and self-etching primers on the mechanical properties of adhesive resins. Four commercially available two-step self-etching primer systems were used. To measure microtensile strength, 0.5-mm thick dumbbell-shaped slabs of each combination of adhesive resin and self-etching primer were prepared. After 24 hours storage in 37 degrees C distilled water, these specimens were subjected to microtensile testing at a crosshead speed of 1.0 mm/minute. Fourier transformation infrared spectroscopy was used to determine the degree of conversion. The percentage of residual double bonds, including pendant and monomeric double bonds, was calculated by comparing the obtained ratio against uncured adhesive resin. The degree of conversion of the adhesive resins was obtained by subtracting the %C=C from 100%. Two-way ANOVAs, followed by Tukey tests, were done. The microtensile strengths and degree of conversion varied with different combinations of self-etching primer and adhesive resin. Numerically, the highest microtensile strengths were obtained when the primer/adhesive resin combinations from the same manufacturer were used. When the different combinations of self-etching primers and adhesive resins were mixed, the microtensile strength and degree of conversion of the adhesive resins tended to decrease for some combinations. Within the limitations of this study, which was far removed from clinical situations, the role of the self-etching primers on the mechanical properties of adhesive resins should be considered to create an authentic resin-dentin interface.

Purpose: Though reduction in bond strength after tooth whitening has been reported, little is known about it's effect on enamel bond strength of two-step bonding systems that exclude phosphoric acid etching prior to bonding agent application. The purpose of this study was to determine the effect of whitening procedure using an in-office whitening agent on enamel bond strength of self-etching primer systems., Methods: Three self-etching primer systems, Imperva Fluoro Bond, Mac Bond II, Clearfil SE Bond, and a one-bottle adhesive system Single Bond as a control material, were used. Bovine mandibular incisors were mounted in self-curing resin and the facial enamel or dentin surfaces were ground wet on 600-grit SiC paper. An in-office whitening agent, Hi-Lite was applied on the tooth surface according to the manufacturer's instruction. Bonding procedures were done soon after rinsing off the whitening agent or after 24 hours storage in distilled water. Specimens without whitening procedure were prepared as controls. Fifteen specimens per test group were stored in 37 degrees C distilled water for 24 hours, then shear tested at a crosshead speed of 1.0 mm/minute. One-way ANOVA followed by Duncan multiple range test were used for statistical analysis of the results., Results: For the specimens made soon after rinsing off the whitening agent, a significant decrease in enamel bond strength was observed for all the bonding systems used. For the specimens made after 24 hours storage in water, a small decrease in enamel bond strength was observed and no significant differences were found compared to those of controls (without whitening). From the results of this study, enamel bond strengths of the self-etching primer systems might be affected to a lesser degree after rinsing with water followed by 24 hours storage in water.