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Nanocomposite films of BiFeO3-Bi2Fe4O9 were fabricated on a sapphire substrate Al2O3 using the method of gas discharge high-frequency cathodic sputtering of a ceramic target with a stoichiometric composition in an oxygen atmosphere. The results of the film analysis using X-ray structural analysis, Raman scattering, XPS, and atomic force microscopy are presented. The lattice parameters, surface topography, chemical composition of the films, concentration, and average sizes of the crystallites for each phase were determined. It was shown that the ratio of the BiFeO3 to Bi2Fe4O9 phases in the obtained film is approximately 1:2. The sizes of the crystallites range from 15 to 17 nm. The optical and magnetic properties of the nanocomposite layers were studied, and the band gap width and magnetization hysteresis characteristic of ferromagnetic behavior were observed. The band gap width was found to be 1.9 eV for the indirect and 2.6 eV for the direct interband transitions. The magnetic properties are characterized by a hysteresis loop resembling a "wasp-waist" shape, indicating the presence of magnetic anisotropy. [ABSTRACT FROM AUTHOR]

The paper presents the results of characterization of the crystal structure, microstructure, dielectric and piezoelectric properties of PbFe 0.5 Nb 0.5 O 3 ceramics modified at the stage of synthesis by lithium carbonate. Due to a detailed analysis of relaxation processes and piezoelectric activity in the region of the ferroelectric to paraelectric state transition, conclusions are drawn about the optimal concentration of the modifier as well as, from the standpoint of mass production technology, the prospects for using such ceramics as targets for producing single-phase thin films of lead ferroniobate on Si substrates as part of a one-stage method of high-frequency cathodic deposition in O 2 atmosphere are shown. The features of the formation of C (U) dependences and the fatigue effect, which are manifested during cyclic field action on the obtained heterostructures, were studied. Image 1 • The Vogel-Fulcher type dielectric relaxation with a half a degree width was detected. • Piezoelectric activity of PFNL ceramics is retained above T C. • Single-phase polycrystalline textured PFN films on Si substrates were obtained. • The fatigue effects of the PFN film began to appear only after 107 switching cycles. [ABSTRACT FROM AUTHOR]