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Plutonium (Pu) has been used as a mid-twentieth century time-marker in various geological archives as a result of atmospheric nuclear tests mainly conducted in 1950s. Advancement of analytical techniques allows us to measure 239Pu and 240Pu more accurately and can thereby reconstruct the Pacific Pu signal that originated from the former Pacific Proving Grounds (PPG) in the Marshall Islands. Here, we propose a novel method that couples annual banded reef building corals and nearshore anoxic marine sediments to provide a marker to precisely determine the start of the nuclear era which is known as a part of the Anthropocene. We demonstrate the efficacy of the methods using sediment obtained from Beppu Bay, Japan, and a coral from Ishigaki Island, Japan. The sedimentary records show a clear Pu increase from 1950, peaking during the 1960s, and then showing a sharp decline during the 1970s. However, a constantly higher isotope ratio between 239Pu and 240Pu suggest an additional contribution other than global fallout via ocean currents. Furthermore, single elevations in 240Pu/239Pu provide supportive evidence of close-in-fallout similar to previous studies. Coral skeletal radiocarbon displays a clear timing with the signatures supporting the reliability of the Beppu Bay sediments as archives and demonstrates the strength of this method to capture potential Anthropocene signatures. [ABSTRACT FROM AUTHOR]

The Huancané II moraines deposited by the Quelccaya Ice Cap in southern Peru were selected by the CRONUS-Earth Project as a primary site for evaluating cosmogenic-nuclide scaling methods and for calibrating production rates. The CRONUS-Earth Project is an effort to improve the state of the art for applications of cosmogenic nuclides to earth-surface chronology and processes. The Huancané II moraines are situated in the southern Peruvian Andes at about 4850 m and ∼13.9°S, 70.9°W. They are favorable for cosmogenic-nuclide calibration because of their low-latitude and high-elevation setting, because their age is very well constrained to 12.3 ± 0.1 ka by 34 radiocarbon ages on peat bracketing the moraines, and because boulder coverage by snow or soil is thought to be very unlikely. However, boulder-surface erosion by granular disintegration is observed and a ∼4% correction was applied to measured concentrations to compensate. Samples from 10 boulders were analyzed for 10 Be, 26 Al, and 36 Cl. Interlaboratory bias at the ∼5% level was the largest contributor to variability of the 10 Be samples, which were prepared by three laboratories (the other two nuclides were only prepared by one laboratory). Other than this issue, variability for all three nuclides was very low, with standard deviations of the analyses only slightly larger than the analytical uncertainties. The site production rates (corrected for topographic shielding, erosion, and radionuclide decay) at the mean site elevation of 4857 m were 45.5 ± 1.6 atoms 10 Be (g quartz) −1 yr −1 , 303 ± 15 atoms 26 Al (g quartz) −1 yr −1 , and 1690 ± 100 atoms 36 Cl (g K) −1 yr −1 . The nuclide data from this site, along with data from other primary sites, were used to calibrate the production rates of these three nuclides using seven global scaling methods. The traditional Lal formulation and the new Lifton-Sato-Dunai calibrations yield average ages for the Huancané samples that are in excellent-to-good agreement with the radiocarbon age control (within 0.7% for 10 Be and 36 Cl and 6% for 26 Al). However, all of the neutron-monitor-based methods yielded ages that were too young by about 20%. The nuclide production ratios at this site are 6.74 ± 0.34 for 26 Al/ 10 Be in quartz and 37.8 ± 2.3 (atoms 36 Cl (g K) −1 ) (atom 10 Be (g SiO 2 ) −1 ) −1 for 36 Cl/ 10 Be, in sanidine and quartz, respectively. [ABSTRACT FROM AUTHOR]

Abstract: Sediment core chronologies of optical dates on single-grains/very small aliquots of sand-sized quartz are compared with Accelerator Mass Spectrometry (AMS) radiocarbon (14C) chronologies from ostracod carbonate, mixed carbonates, sedimentary organic matter and charcoal in order to establish the age of laminated Holocene sediments in maar crater lakes Keilambete and Gnotuk, Victoria, Australia. Samples for optical and AMS 14C dating were taken from the same Mackereth cores, allowing a direct comparison of the two techniques from two laminated sedimentary sequences. Additional AMS 14C samples were taken from water in Lake Keilambete and from groundwater discharging into Lake Keilambete from the crater wall, with equivalent reservoir ages of 150 ± 30 and 1940 ± 30 years respectively. AMS 14C dating of modern ostracod carbonate in Lake Keilambete demonstrates a reservoir age of 670 ± 175 years. Optical dating of ‘single-grain/very small aliquots’ of sand-sized-quartz indicate the presence of a radiocarbon reservoir in Lake Keilambete that is consistent with that measured on modern ostracods, and also demonstrate that there is no 14C reservoir in Lake Gnotuk during the Holocene. The chronology presented here supports the premise that previously published bulk conventional 14C dates from Lake Keilambete were affected by old carbon, meaning that past chronologies require revision. Limitations on the use of optical dating of single-grain/very small aliquots include the relative paucity of sand-sized quartz, which decreases the precision of the sample equivalent dose (D e), and is further confounded by low environmental dose rates and resultant large uncertainties on the final age assessment. Nevertheless, evidence for partial bleaching confirms that single-grain quartz dating is the most appropriate luminescence technique, and may prove a useful alternative in situations where 14C dating is unsuitable or an alternative chronometer is required. [Copyright &y& Elsevier]

Abstract: The latter part of the Last Glacial Interval (LGI; 60,000 to 11,700 years ago) experienced a range of climatic and environment extremes. To elucidate the mechanisms of these changes requires records of past variability that are precisely dated and correlated on the same absolute timescale. However, despite decades of research, it is still not possible to align most marine and terrestrial records of past change with ice-core records, largely because of ongoing uncertainties over the conversion of pre-Holocene 14C ages on to a calendar timescale and uncertainties with in ice-core chronologies. As a result, it is equivocal whether climate changes in both hemispheres during the LGI led, lagged or were synchronous with one another. A decadally-resolved radiocarbon calibration is urgently required to test these models of the Earth system. Here we report radiocarbon measurements obtained from subfossil New Zealand kauri (Agathis australis) spanning a collective 3500 years dated between 25,000 and 45,000 years ago. The results are compared to the recently published international calibration curve IntCal09 and to the marine Cariaco Basin datasets. We show that kauri have considerable potential for development of a Southern Hemisphere component of a unified global calibration curve suite, and that tree-ring sequences can be superposed on other radiocarbon records to constrain atmospheric–marine offsets and precisely test the synchronicity of abrupt climate change. [ABSTRACT FROM AUTHOR]

Abstract: Silicon-32, with a half-life of approximately 140 years, has the potential to fill the dating gap that lies between those chronologies based on the shorter-lived isotopes of 3H and 210Pb, and those based on the longer-lived 14C. Silicon-32 is produced in the atmosphere by cosmic ray bombardment of argon, and falls out on the Earth''s surface in precipitation. Silicon-32 methods may be used to date siliceous sediments and sponges, groundwater and glacier ice. Measurement of 32Si concentrations in these archives is, however, not straightforward. Two methods are available: radioactive-decay counting of the activity of the daughter nucleus, 32P, and accelerator mass spectrometry, but in both cases the detection of 32Si pushes the boundaries of the technique. Even the half-life of 32Si is not known to a precision of better than ±10%. In this paper, we review efforts to determine the isotope''s half-life, survey the detection methods and discuss the applications of 32Si chronology. We show that at least some of the chronometric potential of this radioisotope is close to being realised as a result of recent improvements in methods of measurement. [Copyright &y& Elsevier]

Radiocarbon dating of seven drill cores from both the windward Lizard Island fringing reef and the windward and leeward margins of MacGillivray platform reef, Northern Great Barrier Reef Province, reveal the Holocene evolution of these two mid shelf coral reefs. The windward margin at Lizard Island started growing approximately 6,700 calendar years before present (cal yr BP) directly on an assumed granite basement and approached present day sea level approximately 4,000 cal yr BP. Growth of the windward margin at MacGillivray Reef was initiated by 7,600 cal yr BP and approached present day sea level by approximately 5,600 cal yr BP. The leeward margin at MacGillivray was initiated by 8,200 cal yr BP also directly on an assumed granite basement, but only approached sea level relatively recently, between 260 and 80 cal yr BP. None of the cores penetrated the Holocene-Pleistocene unconformity. The absence of Pleistocene reefal deposits, at 15 m depth in the cores from MacGillivray Reef, raises the possibility that the shelf in this region has subsided relative to modern day sea level by at least 15 m since the last interglacial [125,000 years ago (ka)]. [ABSTRACT FROM AUTHOR]

Abstract: The Mt Giluwe shield volcano was the largest area glaciated in Papua New Guinea during the Pleistocene. Despite minimal cooling of the sea surface during the last glacial maximum, glaciers reached elevations as low as 3200 m. To investigate changes in the extent of ice through time we have re-mapped evidence for glaciation on the southwest flank of Mt Giluwe. We find that an ice cap has formed on the flanks of the mountain on at least three, and probably four, separate occasions. To constrain the ages of these glaciations we present 39 new cosmogenic 36Cl exposure ages complemented by new radiocarbon dates. Direct dating of the moraines identifies that the maximum extent of glaciation on the mountain was not during the last glacial maximum as previously thought. In conjunction with existing potassium/argon and radiocarbon dating, we recognise four distinct glacial periods between 293–306 ka (Gogon Glaciation), 136–158 ka (Mengane Glaciation), centred at 62 ka (Komia Glaciation) and from >20.3–11.5 ka (Tongo Glaciation). The temperature difference relative to the present during the Tongo Glaciation is likely to be of the order of at least 5 °C which is a minimum difference for the previous glaciations. During the Tongo Glaciation, ice was briefly at its maximum for less than 1000 years, but stayed near maximum levels for nearly 4000 years, until about 15.4 ka. Over the next 4000 years there was more rapid retreat with ice free conditions by the early Holocene. [Copyright &y& Elsevier]