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Herein, zinc sodium borate glasses containing samarium ions were fabricated using the traditional melt-quenching approach and explored using several spectroscopic and structural methods. The XRD data corroborated the host glass specimen's non-crystalline nature. Scanning electron microscopy and the energy dispersive X-ray spectroscopy method were utilized to study the morphological and homogenous attributes. The UV–Vis–NIR wavelengths of absorption showed a total of seventeen distinct Sm3+ ion peaks. The three transitions 4G 5/2 → 6H 9/2 , 6H 7/2 , and 6H 5/2 are evident in the PL data at wavelengths of 644, 597, and 561 nm, respectively, in the red, reddish-orange, and greenish-yellow zones. The luminescence intensity of the investigated glass specimens increases up to 0.4 mol% Sm3+ ion content thereafter reducing because of the non-radiative transfer of energy. The estimated JO intensity parameters exhibit a trend of Ω 2 >Ω 4 >Ω 6. The trend of the assessed radiative parameters also demonstrated that they are sensitive to changes in the glass network. The Futchbauer-Ladenburgh theory was used to compute the emission cross-section of various transitions utilizing the radiative parameters. The 1931 CIE chromaticity coordinates assessments corroborate the reddish-orange luminescence from the fabricated glasses. The outcomes have proven that obtained BNZSm x glasses doped with low concentrations of trivalent samarium ions are well suited for reddish-orange solid-state lighting systems. [Display omitted] • The efficacy of low-concentration Sm3+ ions on spectroscopic features of alkali zinc borate glasses has been studied. • Electronic structure and morphological features were ascertained for the studied glass specimens. • Judd-Ofelt attributes were investigated for 0.4 mol% doped ZnNaB glass. • The results revealed that the 0.4 mol% of Sm3+ doped ZnNaB glasses are beneficial for solid state lighting devices. [ABSTRACT FROM AUTHOR]