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This paper investigates how atmospheric vertical profiles of pressure, temperature, and concentration affect molecular absorption calculation. This sensitivity analysis is performed in preparation to the upcoming TRUTHS mission, anticipated to provide hyperspectral TOA BRF records with a radiometric accuracy better than 1%. Two methods for characterizing the atmospheric vertical profile are compared: rescaling the H2O and O3 concentrations of an AFGL U.S. Standard vertical profile, and using customized profiles based on CAMS data. The study investigates the effects of those methods on multi-spectral observations in key spectral regions affected, respectively, by water vapour, ozone and methane, as well as on hyperspectral observations covering the visible to SWIR region. Results show that when molecular transmittance exceeds 97%, the choice of method has minimal impact, with less than 1% uncertainty. When the molecular transmittance decreases from 97% to 75%, the corresponding uncertainty on the TOA BRF simulation increases from 1% up to 5%. For transmittance below 75%, using CAMS data for vertical profile characterization is recommended. The study also highlights how pressure and temperature profiles influence Rayleigh optical thickness estimation, particularly affecting TOA BRF in the blue spectral region. [ABSTRACT FROM AUTHOR]

Physically based models simulating the spectral transmittance of solar radiation through forest canopies are useful tools for examining the connections between the shortwave radiation environment and the productivity and biodiversity of the forest floor. We report a comprehensive evaluation of two approaches simulating forest canopy spectral transmittance.The approaches were (i) three‐dimensional radiative transfer modelling in canopies composed of individual trees filled with turbid media and (ii) photon recollision probability theory (p‐theory), and were implemented using DART‐FT and PARAS models, respectively. The simulations were evaluated against mean and standard deviation of canopy transmittance spectra measured under clear‐sky conditions in forest plots across central and Northern Europe.In general, both models agreed well with the in situ measurements. They performed equally in conifer forests, while PARAS had a slightly lower accuracy than DART‐FT in broadleaved forests.We conclude that both approaches produce realistic simulations of canopy spectral transmittance at the spatial scale tested in this study, and that p‐theory constitutes a computationally efficient and easy‐to‐parameterize alternative to three‐dimensional radiative transfer. [ABSTRACT FROM AUTHOR]

Abstract Physically based models simulating the spectral transmittance of solar radiation through forest canopies are useful tools for examining the connections between the shortwave radiation environment and the productivity and biodiversity of the forest floor. We report a comprehensive evaluation of two approaches simulating forest canopy spectral transmittance. The approaches were (i) three‐dimensional radiative transfer modelling in canopies composed of individual trees filled with turbid media and (ii) photon recollision probability theory (p‐theory), and were implemented using DART‐FT and PARAS models, respectively. The simulations were evaluated against mean and standard deviation of canopy transmittance spectra measured under clear‐sky conditions in forest plots across central and Northern Europe. In general, both models agreed well with the in situ measurements. They performed equally in conifer forests, while PARAS had a slightly lower accuracy than DART‐FT in broadleaved forests. We conclude that both approaches produce realistic simulations of canopy spectral transmittance at the spatial scale tested in this study, and that p‐theory constitutes a computationally efficient and easy‐to‐parameterize alternative to three‐dimensional radiative transfer.

Optical remote sensing of water quality has been problematic due to contamination of remote sensing observations by the sea-bottom effect over complex shallow or very clear waters. This has resulted in providing misleading information on the estimation of Water Constituent Concentrations (WCCs) retrieved from satellite images. In this research, we used Radiative Transfer (RT) Modelling to develop a simple and innovative index named the Sea-Bottom Effect Index (SEBEI) to readily determine water pixels contaminated by the sea-bottom effect, (hereafter named Optically Shallow Waters, (OSWs)) from remote sensing observations. To define the SEBEI, we initially assessed the influence of the sea-bottom on simulated water-leaving reflectance (Rrs) using RT Water-Sea-Bottom (WSB) modelling. This evaluation encompassed a range of water depths, seabed albedos, and WCCs (i.e. Chlorophyll-a (Chla) and Suspended Particulate Matter (SPM)). Next, we detected the most sensitive wavelengths (i.e. 750 nm, 810 nm, and 900 nm) to the seabed contribution on the simulated Rrs spectra at the water surface level and developed the SEBEI. We validated the accuracy of the proposed SEBEI over a time series of MEdium Resolution Imaging Spectrometer (MERIS) and Ocean and Land Colour Instrument (OLCI) images captured during low and high tidal phases over shallow waters of the Dutch Wadden Sea, the Netherlands. The results indicate that the SEBEI effectively distinguishes between OSWs and Optically Deep Waters (ODWs) using satellite images (with an R2 value of ≥ 0.97 and a Root Mean Square Error (RMSE) of ≤ 0.65). The SEBEI can serve as an intermediate solution for detecting OSWs in multispectral and hyperspectral satellite images worldwide. It eliminates the need for ancillary datasets like bathymetry maps and significantly enhances the reliability of WCC maps produced over complex shallow coastal waters. [ABSTRACT FROM AUTHOR]

This paper investigates how atmospheric vertical profiles of pressure, temperature, and concentration affect molecular absorption calculation. This sensitivity analysis is performed in preparation to the upcoming TRUTHS mission, anticipated to provide hyperspectral TOA BRF records with a radiometric accuracy better than 1%. Two methods for characterizing the atmospheric vertical profile are compared: rescaling the H2O and O3 concentrations of an AFGL U.S. Standard vertical profile, and using customized profiles based on CAMS data. The study investigates the effects of those methods on multi-spectral observations in key spectral regions affected, respectively, by water vapour, ozone and methane, as well as on hyperspectral observations covering the visible to SWIR region. Results show that when molecular transmittance exceeds 97%, the choice of method has minimal impact, with less than 1% uncertainty. When the molecular transmittance decreases from 97% to 75%, the corresponding uncertainty on the TOA BRF simulation increases from 1% up to 5%. For transmittance below 75%, using CAMS data for vertical profile characterization is recommended. The study also highlights how pressure and temperature profiles influence Rayleigh optical thickness estimation, particularly affecting TOA BRF in the blue spectral region.

"Sargassum" is a pelagic species of algae that drifts and aggregates in the tropical Atlantic Ocean. The number of Sargassum aggregations increased in the Caribbean Sea during the last decade. The aggregations eventually wash up on shores thus leading to a socio-economic issue for the population and the coastal ecosystem. Satellite ocean color data, such as those provided by the Sentinel-3/OLCI satellite sensor (Copernicus), can be used to detect the occurrences of Sargassum and to estimate their abundance per pixel using the Maximum Chlorophyll Index (noted MCI). Such an index is, however, ineffective if the algae are located beneath the sea surface, which frequently happens, considering the rough Caribbean oceanic waters. The objective of this study is to propose a relevant methodology that enables the detection of underwater Sargassum aggregations. The methodology relies on the inversion of the radiative transfer equation in the water column. The inverted model provides the immersion depth of the Sargassum aggregations (per pixel) and their fractional coverage from the above water reflectances. The overall methodology has been applied to Sentinel-3/OLCI data. The comparison with the MCI method, which is solely devoted to the sea surface retrieval of Sargassum aggregations, shows that the proposed methodology allows retrieving about twice more Sargassum aggregation occurrences than the MCI estimates. A relative increase of 31% of the fractional coverage over the entire study area is observed when using the proposed method in comparison to MCI method. For the satellite scenes considered here, the rate of Sargassum aggregations immersed between 2 m and 5 m depth ranges between 30% and 51% over the total amount (i.e., surface + in-water), which clearly demonstrates the importance of considering the retrieval of in-water aggregations to gain understanding on Sargassum spatial variability in the oceanic and coastal ecosystems. [ABSTRACT FROM AUTHOR]

We conducted a theoretical analysis of the relationship between red-to-blue (RBR) color intensities and aerosol optical properties. RBR values are obtained by radiative transfer simulations of diffuse sky radiances. Changes in atmospheric aerosol concentration (parametrized by aerosol optical depth, AOD), particle’s size distribution (parametrized by Ångström exponent, AE) and aerosols’ scattering (parametrized by single scattering albedo—SSA) lead to variability in sky radiances and, thus, affect the RBR ratio. RBR is highly sensitive to AOD as high aerosol load in the atmosphere causes high RBR. AE seems to strongly affect the RBR, while SSA effect the RBR, but not to such a great extent.

Separation of soil effects from top-of-canopy (TOC) reflectance is crucial for quantitative remote sensing of vegetation. Soil affects TOC reflectance via the soil-vegetation interaction and the direct reflection by soil. Various vegetation indices have been developed semi-empirically to mitigate the interferences caused by soil for specific applications, such estimating biomass and monitoring vegetation phenology. However, a practical approach to separate soil effects from the entire TOC spectral reflectance is still lacking. In this study, we investigate the radiative transfer process in a vegetation canopy with soil contamination and develop three methods to estimate the contribution of soil's direct reflection to TOC reflectance. Theoretical analysis reveals that the soil's direct reflection can be quantified and separated from TOC reflectance due to the distinct spectral characteristics of soil and vegetation. We identify three key features: a) Bands in the visible region where the reflectance of soil-uncontaminated green vegetation approaches zero due to strong pigment absorption. b) Two bands in the visible region where the vegetation reflectance is similar, but soil reflectance is distinguishable. c) Soil reflectance within the range of 400 nm to 1000 nm exhibits a near-linear dependence on wavelength. Using these features, we develop three methods to quantify the contribution of soil's direct reflection to TOC reflectance. For given soil reflectance, feature a) or b) alone allows estimating the fraction of soil that directly contributes to TOC reflectance, and thus the soil's direct reflection. Using all three features enables estimation of the soil's direct reflection without knowing soil reflectance. The proposed methods, along with certain assumptions made during their development, are tested and evaluated using field and synthetic datasets of soil, leaf, and canopy. The evaluation of the three methods demonstrates that the estimation of the soil's direct reflection can be achieved through: i) Using TOC reflectance at approximately 675 nm and soil spectral reflectance, termed the red-band-based method (Method-RBB). ii) Using TOC reflectance at approximately 675 nm and 438 nm, along with soil spectral reflectance, termed as the two-band-based method (Method-TBB). iii) Using TOC reflectance at approximately 675 nm and 438 nm, assuming linear dependence of soil reflectance on wavelength in the visible and near-infrared region, termed as the linear-assumption-based method (Method-LAB). Our evaluation indicates that the linearity from 400 nm to 1000 nm holds true for a wide range of soil types. The conditions outlined in features a) and b) are valid for green vegetation with moderate to high leaf chlorophyll content: when leaf chlorophyll content exceeds 20 μg cm−2, the leaf albedo at 675 nm is generally below 0.15, and the difference in leaf albedo at 675 nm and 438 nm is sufficiently small. The results reveal that when leaf albedo at 675 nm is less than 0.15 and NDVI is less than 0.8, all three methods perform satisfactorily, exhibiting an R2 value of approximately 0.9 between the true and estimated contribution of soil's direct reflection. The R2 values are 0.92 for both Method-RBB and Method-LAB, while Method-TBB has an R2 of 0.95. The performance of Method-RBB is particularly sensitive to leaf albedo at the red band, which correlates with leaf chlorophyll content. Canopies exhibiting higher red-band leaf albedo usually indicate lower chlorophyll content and less resemblance to typical green vegetation. The accuracy of Method-TBB diminishes as the differences in leaf albedo between the selected two bands increase. Similarly, deviations from the linear dependence of soil reflectance on wavelength negatively impact the accuracy of Method-LAB. Overall, these proposed methods work reasonably well for sparse canopies and healthy vegetation. Method-TBB exhibits the highest level of accuracy, followed by Method-RBB, while Method-LAB is more convenient to use as it does not require prior knowledge of soil reflectance. The proposed methods offer practical ways to estimate the contribution of soil's direct reflection to TOC reflectance. Utilizing TOC reflectance after the soil adjustment facilitates more direct monitoring of canopy structural characteristics, and biochemical and physiological information of leaves. • Using spectral features to estimate soil contribution to TOC reflectance. • Evaluating the performance of the methods using simulations and measurements. • Three proposed methods achieve R2 ∼ 0.9 for green vegetation. • The soil-adjusted canopy reflectance better represents 'pure' vegetation. [ABSTRACT FROM AUTHOR]

Snow covers are very sensitive to contamination from soot agglomerates derived from vehicles. A spectroradiometric system covering a wavelength from 300 to 2500 nm with variable resolution (from 2.2 to 7.0 nm) was used to characterize the effect of soot derived from a diesel vehicle whose exhaust stream was oriented towards a limited snowed area. The vehicle was previously tested in a rolling test bench where particle number emissions and size distributions were measured, and fractal analysis of particle microscopic images was made after collecting individual agglomerates by means of an electrostatizing sampler. Finally, the experimental results were compared to modelled results of contaminated snow spectral albedo obtained with a snow radiative transfer model developed by our research group (OptiPar) and with other models. Both experimental and modelled results show that increasingly accumulated soot mass reduces the snow albedo with a constant rate of around 0.03 units per mg/kg, with a predominant effect on the UV-VIS range. Based on the small size of the primary particles (around 25 nm), the Rayleigh-Debye-Gans approximation, further corrected to account for the effect of multiple scattering within the agglomerates, was revealed as an appropriate technique in the model. [ABSTRACT FROM AUTHOR]

Radiative transfer models (RTM) provide universally applicable, highly accurate prospects for plant parameter retrieval. Due to the ill-posed nature of radiative transfer theory, however, the retrieval of plant parameters requires sophisticated strategies for model inversion. We argue that object-based image analysis (OBIA) works as an effective regularization measure to cope with this ill-posedness. Despite similar findings reported in the literature, OBIA and RTM are rarely used in a combined manner. Additionally, there is a clear lack of software solutions ready for operational usage. Therefore, we propose OBIA4RTM as an approach to combine OBIA and RTM using Python and PostgreSQL/PostGIS spatial databases in a fully Open Geospatial Consortium (OGC) compliant way. First results obtained in agricultural regions in southern Germany and Austria using Sentinel-2 data during the 2017 and 2018 growing season show root mean squared errors (RMSE) in the leaf area index (LAI) of 1.47 m²/m² in the case of silage maize and 1.31 m²/m² in the case of winter cereals. Issues of integrating space and time as well as defining appropriate validation strategies, however, require further research.

“Sargassum” is a pelagic species of algae that drifts and aggregates in the tropical Atlantic Ocean. The number of Sargassum aggregations increased in the Caribbean Sea during the last decade. The aggregations eventually wash up on shores thus leading to a socio-economic issue for the population and the coastal ecosystem. Satellite ocean color data, such as those provided by the Sentinel-3/OLCI satellite sensor (Copernicus), can be used to detect the occurrences of Sargassum and to estimate their abundance per pixel using the Maximum Chlorophyll Index (noted MCI). Such an index is, however, ineffective if the algae are located beneath the sea surface, which frequently happens, considering the rough Caribbean oceanic waters. The objective of this study is to propose a relevant methodology that enables the detection of underwater Sargassum aggregations. The methodology relies on the inversion of the radiative transfer equation in the water column. The inverted model provides the immersion depth of the Sargassum aggregations (per pixel) and their fractional coverage from the above water reflectances. The overall methodology has been applied to Sentinel-3/OLCI data. The comparison with the MCI method, which is solely devoted to the sea surface retrieval of Sargassum aggregations, shows that the proposed methodology allows retrieving about twice more Sargassum aggregation occurrences than the MCI estimates. A relative increase of 31% of the fractional coverage over the entire study area is observed when using the proposed method in comparison to MCI method. For the satellite scenes considered here, the rate of Sargassum aggregations immersed between 2 m and 5 m depth ranges between 30% and 51% over the total amount (i.e., surface + in-water), which clearly demonstrates the importance of considering the retrieval of in-water aggregations to gain understanding on Sargassum spatial variability in the oceanic and coastal ecosystems.

Snow covers are very sensitive to contamination from soot agglomerates derived from vehicles. A spectroradiometric system covering a wavelength from 300 to 2500 nm with variable resolution (from 2.2 to 7.0 nm) was used to characterize the effect of soot derived from a diesel vehicle whose exhaust stream was oriented towards a limited snowed area. The vehicle was previously tested in a rolling test bench where particle number emissions and size distributions were measured, and fractal analysis of particle microscopic images was made after collecting individual agglomerates by means of an electrostatizing sampler. Finally, the experimental results were compared to modelled results of contaminated snow spectral albedo obtained with a snow radiative transfer model developed by our research group (OptiPar) and with other models. Both experimental and modelled results show that increasingly accumulated soot mass reduces the snow albedo with a constant rate of around 0.03 units per mg/kg, with a predominant effect on the UV-VIS range. Based on the small size of the primary particles (around 25 nm), the Rayleigh-Debye-Gans approximation, further corrected to account for the effect of multiple scattering within the agglomerates, was revealed as an appropriate technique in the model.

Radiative transfer models (RTM) provide universally applicable, highly accurate prospects for plant parameter retrieval. Due to the ill-posed nature of radiative transfer theory, however, the retrieval of plant parameters requires sophisticated strategies for model inversion. We argue that object-based image analysis (OBIA) works as an effective regularization measure to cope with this ill-posedness. Despite similar findings reported in the literature, OBIA and RTM are rarely used in a combined manner. Additionally, there is a clear lack of software solutions ready for operational usage. Therefore, we propose OBIA4RTM as an approach to combine OBIA and RTM using Python and PostgreSQL/PostGIS spatial databases in a fully Open Geospatial Consortium (OGC) compliant way. First results obtained in agricultural regions in southern Germany and Austria using Sentinel-2 data during the 2017 and 2018 growing season show root mean squared errors (RMSE) in the leaf area index (LAI) of 1.47 m²/m² in the case of silage maize and 1.31 m²/m² in the case of winter cereals. Issues of integrating space and time as well as defining appropriate validation strategies, however, require further research. [ABSTRACT FROM AUTHOR]

Abiotic ecosystem properties together with plant species interaction create differences in structural and physiological traits among plant species. Certain plant traits cause a spatial and temporal variation in canopy reflectance that enables the differentiation of plant functional types, using earth observation data. However, it often remains unclear which traits drive the differences in reflectance between plant functional types, since the spectral regions in which electromagnetic radiation is influenced by certain plant traits are often overlapping. The present study aims to assess the relative (statistical) contributions of plant traits to the separability of plant functional groups using their reflectance. We apply the radiative transfer model PROSAIL to simulate optical canopy reflectance of 38 herbaceous plant species based on field‐measured traits such as leaf area index, leaf inclination distribution, chlorophyll content, carotenoid content, water and dry matter content. These traits of the selected grassland species were measured in an outdoor plant experiment. The 38 species differed in growth form and strategy types according to Grime′s CSR model and hence represented a broad range of plant functioning. We determined the relative (statistical) contribution of each plant trait for separating plant functional groups via reflectance. Therein we used a separation into growth forms, that is graminoids and herbs, and into CSR strategy types. Our results show that the relative contribution of plant traits to differentiate between the examined plant functional types (PFT) groups using canopy reflectance depends on the PFT scheme applied. Plant traits describing the canopy structure were more important in this regard than leaf traits. Accordingly, leaf area index (LAI) and leaf inclination showed consistently high importance for separating the examined PFT groups. This indicates that the role of canopy structure for spectrally differentiating PFT might have been underestimated. Optical earth observation data is considered an important instrument for the mapping and monitoring of plant functioning. Here, the contribution of plant traits for differentiating plant functional groups is investigated using in‐situ trait measurements and radiative transfer models (PROSAIL). The results indicate that traits describing the canopy structure play an important role in differentiating plant functioning and might have been underestimated in the past. We found important spectral information for the separation of plant functional groups in varying and narrow wavelength regions. This outcome underlines the high potential of hyperspectral earth observation data to monitor plant functioning. [ABSTRACT FROM AUTHOR]

This study investigates the spatial and temporal variability of chromophoric-dissolved organic matter (CDOM) in the Mediterranean Sea. The analysis is carried out using a state-of-the-art 3D biogeochemical model. The model describes the plankton dynamics, the cycles of the most important limiting nutrients, and the particulate and dissolved pools of carbon. The source of CDOM is directly correlated to the dynamics of dissolved organic carbon (DOC) by a fixed production quota. Then CDOM degrades by photobleaching and remineralization. The main innovation of the system is the inclusion of a bio-optical radiative transfer model that computes surface upwelling irradiance, and therefore simulates remotely sensed reflectance (Rrs). Simulation results of three model configurations are evaluated using satellite Rrs, particularly at 412 nm, 443 nm, and 490 nm. All simulations show a winter minimum in Rrs for the considered bands. However, different parameterizations of DOC-release induce a different accumulation of CDOM, especially in the eastern Mediterranean, and a different Rrs signature: a more active microbial loop during summer implies a decrease of Rrs at 412 nm. We demonstrate how the usage of a bio-optical model allows us to corroborate hypotheses on CDOM-cycling based on blue–violet Rrs data, supporting the importance of this complementary data stream with respect to satellite-derived chlorophyll.

The broadband surface albedo of snow can greatly be reduced by the deposition of light-absorbing impurities, such as black carbon on or near its surface. Such a reduction increases the absorption of solar radiation and may initiate or accelerate snowmelt and snow albedo feedback. Coincident measurements of both black carbon concentration and broadband snow albedo may be difficult to obtain in field studies; however, using the relationship developed in this simple model sensitivity study, black carbon mass densities deposited can be estimated from changes in measured broadband snow albedo, and vice versa. Here, the relationship between the areal mass density of black carbon found near the snow surface to the amount of albedo reduction was investigated using the popular snow radiative transfer model Snow, Ice, and Aerosol Radiation (SNICAR). We found this relationship to be linear for realistic amounts of black carbon mass concentrations, such as those found in snow at remote locations. We applied this relationship to measurements of broadband albedo in the Chilean Andes to estimate how vehicular emissions contributed to black carbon (BC) deposition that was previously unquantified.

Abstract Fire radiative power (FRP) retrievals are now routinely made from polar and geostationary instruments, providing a means to estimate fuel consumption and trace gas and aerosol emissions directly from remotely sensed observations. This study presents the first investigation of the impact of vegetation canopy structure (percentage canopy cover and leaf area index, LAI) on FRP retrievals, based on 3D radiative transfer model simulations. The Discrete Anisotropic Radiative Transfer (DART) model is used to simulate above-canopy observations made through 3D vegetation canopies with different structural arrangements, under which a centrally positioned uniform landscape fire is burning. The vegetation canopy is modelled in two ways, as an opaque structure and as a hybrid turbid medium. The percentage canopy cover in each simulated scene is varied between 5 and 95%, and the FRP retrieved above the canopy is found to decrease in proportion to percentage canopy cover when the canopy is opaque, a finding that is in agreement with a series of small scale outdoor measurements conducted to evaluate the realism of the simulations. However, when the canopy is modelled as a turbid medium, which is in some ways a more realistic representation of a real 'gappy' vegetation canopy, the degree of FRP interception occurring at any particular canopy cover decreases by ~ 14%, due to some fire emitted thermal energy being transmitted through the canopy gaps. The simulations also reveal the impact of canopy LAI on above-canopy FRP retrievals, reducing these by 6% when both canopy cover and LAI are low (5% and < 1.0 respectively), but by up to 92% when canopy cover and scene LAI are high (95% and ~8 respectively). We use the derived relationships between FRP interception and canopy structure, along with MODIS LAI and percentage tree cover data, to adjust 2004–2012 fire radiative energy (FRE) estimates calculated from FRP data collected by the geostationary Meteosat Spinning Enhanced Visible and Infrared Imager (SEVIRI) instrument. The adjusted annual FRE is on average 15% greater than estimated, and is characterized by low inter-annual variability as result of the majority of fire activity occurring in areas where percentage tree cover remains below 40%. Landscape burning occurs more frequently in areas of higher tree cover in southern hemisphere rather than northern hemisphere Africa, leading to a larger annual FRE adjustment (18.5% compared to 16.3%). This study illustrates the impact that canopy interception has on FRP for the first time at the satellite scale, and over Africa demonstrates a large but temporally consistent underestimation which can be accounted for using LAI and percentage tree cover metrics when estimating fuel consumption and atmospheric emissions from the FRP retrievals. Highlights • First analysis of canopy structure impact on FRP using a radiative transfer model • FRP decreases in proportion to % canopy cover when the canopy is opaque. • When modelled as a turbid medium FRP interception decreases by 14% • Sensor measured FRP is reduced by up to 92% at very high LAI and %cover. • SEVIRI FRE increases by ~15% annually when corrected for canopy interception. [ABSTRACT FROM AUTHOR]

Remote sensing studies of vegetation phenology increasingly benefit from freely available satellite imagery acquired with high temporal frequency at fine spatial resolution. Particularly for heterogeneous landscapes this is good news, given the drawback of medium-resolution sensors commonly used for phenology retrieval (e.g., MODIS) to properly represent the fine-scale spatial variability of vegetation types. The Sentinel-2 mission acquires spectral data globally at 10 to 60 m resolution every five days. To illustrate the mission's potential for studying vegetation phenology, we retrieved phenological parameters for the Dutch barrier island Schiermonnikoog for a full season of Sentinel-2A observations in 2016. Overlapping orbits resulted in two acquisitions per 10 days, similar to what is achieved globally since the launch of Sentinel-2B. For eight locations on the island's salt marsh we compared greenness chromatic coordinate (GCC) series derived from digital repeat RGB-cameras with vegetation index series derived from Sentinel-2 (NDVI and GCC). For each series, a double hyperbolic tangent model was fitted and thresholds were applied to the modelled data to estimate start-, peak-, and end-of-season (SOS/PS/EOS). Variability in Sentinel-2 derived SOS, when taken as the midpoint between minimum and peak NDVI, was well-explained by camera GCC-based SOS (R 2  = 0.74, MSD = 8.0 days, RMSD = 13.0 days). However, EOS estimates from camera GCC series were on average almost two months before NDVI-based estimates. This could partially be explained by the observed exponential relationship between GCC and NDVI, as well as by the combined effect of viewing angle differences and the presence of non-photosynthetic elements in the vegetation canopy. A two-layer canopy radiative transfer model incorporating reduced chlorophyll levels in the upper layer provided a physically-based explanation of the viewing angle effect. Finally, we applied the phenology retrieval approach to NDVI series for all pixels of the island in order to map spatial patterns of phenology at fine resolution. Our results demonstrate the potential of the Sentinel-2 mission for providing spatially-detailed retrievals of phenology. [ABSTRACT FROM AUTHOR]

This paper presents the algorithm developed in LSA-SAF (Satellite Application Facility for Land Surface Analysis) for the derivation of global vegetation parameters from the AVHRR (Advanced Very High Resolution Radiometer) sensor on board MetOp (Meteorological–Operational) satellites forming the EUMETSAT (European Organization for the Exploitation of Meteorological Satellites) Polar System (EPS). The suite of LSA-SAF EPS vegetation products includes the leaf area index (LAI), the fractional vegetation cover (FVC), and the fraction of absorbed photosynthetically active radiation (FAPAR). LAI, FAPAR, and FVC characterize the structure and the functioning of vegetation and are key parameters for a wide range of land–biosphere applications. The algorithm is based on a hybrid approach that blends the generalization capabilities offered by physical radiative transfer models with the accuracy and computational efficiency of machine learning methods. One major feature is the implementation of multi-output retrieval methods able to jointly and more consistently estimate all the biophysical parameters at the same time. We propose a multi-output Gaussian process regression (GPR multi ), which outperforms other considered methods over PROSAIL (coupling of PROSPECT and SAIL (Scattering by Arbitrary Inclined Leaves) radiative transfer models) EPS simulations. The global EPS products include uncertainty estimates taking into account the uncertainty captured by the retrieval method and input errors propagation. A sensitivity analysis is performed to assess several sources of uncertainties in retrievals and maximize the positive impact of modeling the noise in training simulations. The paper discusses initial validation studies and provides details about the characteristics and overall quality of the products, which can be of interest to assist the successful use of the data by a broad user’s community. The consistent generation and distribution of the EPS vegetation products will constitute a valuable tool for monitoring of earth surface dynamic processes. [ABSTRACT FROM AUTHOR]

The first airborne hyperspectral campaign in the Antarctic Peninsula region was carried out by the British Antarctic Survey and partners in February 2011. This paper presents an insight into the applicability of currently available radiative transfer modelling and atmospheric correction techniques for processing airborne hyperspectral data in this unique coastal Antarctic environment. Results from the Atmospheric and Topographic Correction version 4 (ATCOR-4) package reveal absolute reflectance values somewhat in line with laboratory measured spectra, with Root Mean Square Error (RMSE) values of 5% in the visible near infrared (0.4–1 µm) and 8% in the shortwave infrared (1–2.5 µm). Residual noise remains present due to the absorption by atmospheric gases and aerosols, but certain parts of the spectrum match laboratory measured features very well. This study demonstrates that commercially available packages for carrying out atmospheric correction are capable of correcting airborne hyperspectral data in the challenging environment present in Antarctica. However, it is anticipated that future results from atmospheric correction could be improved by measuring in situ atmospheric data to generate atmospheric profiles and aerosol models, or with the use of multiple ground targets for calibration and validation.

Different types of methods have been developed to retrieve vegetation attributes from remote sensing data, including conventional empirical regressions (i.e., linear regression (LR)), advanced empirical regressions (e.g., multivariable linear regression (MLR), partial least square regression (PLSR)), machine learning (e.g., random forest regression (RFR), decision tree regression (DTR)), and radiative transfer modelling (RTM, e.g., PROSAIL). Given that each algorithm has its own strengths and weaknesses, it is essential to compare them and evaluate their effectiveness. Previous studies have mainly used single-date multispectral imagery or ground-based hyperspectral reflectance data for evaluating the models, while multi-seasonal hyperspectral images have been rarely used. Extensive spectral and spatial information in hyperspectral images, as well as temporal variations of landscapes, potentially influence the model performance. In this research, LR, PLSR, RFR, and PROSAIL, representing different types of methods, were evaluated for estimating vegetation chlorophyll content from bi-seasonal hyperspectral images (i.e., a middle- and a late-growing season image, respectively). Results show that the PLSR and RFR generally performed better than LR and PROSAIL. RFR achieved the highest accuracy for both images. This research provides insights on the effectiveness of different models for estimating vegetation chlorophyll content using hyperspectral images, aiming to support future vegetation monitoring research.

Progress in advanced radiative transfer models (RTMs) led to an improved understanding of reflectance (R) and sun-induced chlorophyll fluorescence (SIF) emission throughout the leaf and canopy. Among advanced canopy RTMs that have been recently modified to deliver SIF spectral outputs are the energy balance model SCOPE and the 3D models DART and FLIGHT. The downside of these RTMs is that they are computationally expensive, which makes them impractical in routine processing, such as scene generation and retrieval applications. To bypass their computational burden, a computationally effective technique has been proposed by only using a limited number of model runs, called emulation. The idea of emulation is approximating the original RTM by a surrogate machine learning model with low computation time. However, a concern is whether the emulator reaches sufficient accuracy. To this end, we analyzed key aspects of emulator development that may impact the precision of emulating SCOPE-like R and SIF spectra, being: (1) type of machine learning, (2) type of dimensionality reduction (DR) method, and (3) number of components and lookup table (LUT) size. The machine learning family of Gaussian processes regression and neural networks were found best suited to function as emulators. The classical principal component analysis (PCA) remains a robust DR method, but the number of components needs to be optimized depending on the complexity of the spectral data. Based on a small Latin hypercube sampling LUT of 500 samples (70% used for training) covering a selection of SCOPE input variables, the best-performing emulators can reconstruct any combination for the selected SCOPE input variables with relative errors along the spectral range below 2% for R and 4% for SIF. That is sufficient for a precise reconstruction for the large majority of possible combinations, and errors can be further reduced when increasing LUT size for training. As a proof of concept, we imported the best-performing emulators into a newly developed Automated Scene Generator Module (A-SGM) to generate a R and SIF synthetic scene of a vegetated surface. Using emulators as alternative of SCOPE reduced the processing time from the order of days to the order of minutes while preserving sufficient accuracy. [ABSTRACT FROM AUTHOR]

Canopy density measures such as the Leaf Area Index (LAI) have become standardized mapping products derived from airborne and terrestrial Light Detection And Ranging (aLiDAR and tLiDAR, respectively) data. A specific application of LiDAR point clouds is their integration into radiative transfer models (RTM) of varying complexity. Using, e.g., ray tracing, this allows flexible simulations of sub-canopy light condition and the simulation of various sensors such as virtual hemispherical images or waveform LiDAR on a virtual forest plot. However, the direct use of LiDAR data in RTMs shows some limitations in the handling of noise, the derivation of surface areas per LiDAR point and the discrimination of solid and porous canopy elements. In order to address these issues, a strategy upgrading tLiDAR and Digital Hemispherical Photographs (DHP) into plausible 3D architectural canopy models is suggested. The presented reconstruction workflow creates an almost unbiased virtual 3D representation of branch and leaf surface distributions, minimizing systematic errors due to the object–sensor relationship. The models are calibrated and validated using DHPs. Using the 3D models for simulations, their capabilities for the description of leaf density distributions and the simulation of aLiDAR and DHP signatures are shown. At an experimental test site, the suitability of the models, in order to systematically simulate and evaluate aLiDAR based LAI predictions under various scan settings is proven. This strategy makes it possible to show the importance of laser point sampling density, but also the diversity of scan angles and their quantitative effect onto error margins. [ABSTRACT FROM AUTHOR]

Meteosat First-Generation satellites have acquired more than 30 years of observations that could potentially be used for the generation of a Climate Data Record. The availability of harmonized and accurate a Fundamental Climate Data Record is a prerequisite to such generation. Meteosat Visible and Infrared Imager radiometers suffer from inaccurate pre-launch spectral function characterization and spectral ageing constitutes a serious limitation to achieve such prerequisite. A new method was developed for the retrieval of the pre-launch instrument spectral function and its ageing. This recovery method relies on accurately simulated top-of-atmosphere spectral radiances matching observed digital count values. This paper describes how these spectral radiances are simulated over pseudo-invariant targets such as open ocean, deep convective clouds and bright desert surface. The radiative properties of these targets are described with a limited number of parameters of known uncertainty. Typically, a single top-of-atmosphere radiance spectrum can be simulated with an estimated uncertainty of about 5%. The independent evaluation of the simulated radiance accuracy is also addressed in this paper. It includes two aspects: the comparison with narrow-band well-calibrated radiometers and a spectral consistency analysis using SEVIRI/HRVIS band on board Meteosat Second Generation which was accurately characterized pre-launch. On average, the accuracy of these simulated spectral radiances is estimated to be about ±2%.

In this study we evaluated various spectral inputs for retrieval of forest chlorophyll content (Cab) and leaf area index (LAI) from high spectral and spatial resolution airborne imaging spectroscopy data collected for two forest study sites in the Czech Republic (beech forest at Štítná nad Vláří and spruce forest at Bílý Kříž). The retrieval algorithm was based on a machine learning method - support vector regression (SVR). Performance of the four spectral inputs used to train SVR was evaluated: a) all available hyperspectral bands, b) continuum removal (CR) 645 - 710 nm, c) CR 705 - 780 nm, and d) CR 680 - 800 nm. Spectral inputs and corresponding SVR models were first assessed at the level of spectral databases simulated by combined leaf-canopy radiative transfer models PROSPECT and DART. At this stage, SVR models using all spectral inputs provided good performance (RMSE for Cab < 10 μg cm-2 and for LAI < 1.5), with consistently better performance for beech over spruce site. Since application of trained SVRs on airborne hyperspectral images of the spruce site produced unacceptably overestimated values, only the beech site results were analysed. The best performance for the Cab estimation was found for CR bands in range of 645 - 710 nm, whereas CR bands in range of 680 - 800 nm were the most suitable for LAI retrieval. The CR transformation reduced the across-track bidirectional reflectance effect present in airborne images due to large sensor field of view. [ABSTRACT FROM AUTHOR]

Progress in advanced radiative transfer models (RTMs) led to an improved understanding of reflectance (R) and sun-induced chlorophyll fluorescence (SIF) emission throughout the leaf and canopy. Among advanced canopy RTMs that have been recently modified to deliver SIF spectral outputs are the energy balance model SCOPE and the 3D models DART and FLIGHT. The downside of these RTMs is that they are computationally expensive, which makes them impractical in routine processing, such as scene generation and retrieval applications. To bypass their computational burden, a computationally effective technique has been proposed by only using a limited number of model runs, called emulation. The idea of emulation is approximating the original RTM by a surrogate machine learning model with low computation time. However, a concern is whether the emulator reaches sufficient accuracy. To this end, we analyzed key aspects of emulator development that may impact the precision of emulating SCOPE-like R and SIF spectra, being: (1) type of machine learning, (2) type of dimensionality reduction (DR) method, and (3) number of components and lookup table (LUT) size. The machine learning family of Gaussian processes regression and neural networks were found best suited to function as emulators. The classical principal component analysis (PCA) remains a robust DR method, but the number of components needs to be optimized depending on the complexity of the spectral data. Based on a small Latin hypercube sampling LUT of 500 samples (70% used for training) covering a selection of SCOPE input variables, the best-performing emulators can reconstruct any combination for the selected SCOPE input variables with relative errors along the spectral range below 2% for R and 4% for SIF. That is sufficient for a precise reconstruction for the large majority of possible combinations, and errors can be further reduced when increasing LUT size for training. As a proof of concept, we imported the best-performing emulators into a newly developed Automated Scene Generator Module (A-SGM) to generate a R and SIF synthetic scene of a vegetated surface. Using emulators as alternative of SCOPE reduced the processing time from the order of days to the order of minutes while preserving sufficient accuracy.

Canopy density measures such as the Leaf Area Index (LAI) have become standardized mapping products derived from airborne and terrestrial Light Detection And Ranging (aLiDAR and tLiDAR, respectively) data. A specific application of LiDAR point clouds is their integration into radiative transfer models (RTM) of varying complexity. Using, e.g., ray tracing, this allows flexible simulations of sub-canopy light condition and the simulation of various sensors such as virtual hemispherical images or waveform LiDAR on a virtual forest plot. However, the direct use of LiDAR data in RTMs shows some limitations in the handling of noise, the derivation of surface areas per LiDAR point and the discrimination of solid and porous canopy elements. In order to address these issues, a strategy upgrading tLiDAR and Digital Hemispherical Photographs (DHP) into plausible 3D architectural canopy models is suggested. The presented reconstruction workflow creates an almost unbiased virtual 3D representation of branch and leaf surface distributions, minimizing systematic errors due to the object–sensor relationship. The models are calibrated and validated using DHPs. Using the 3D models for simulations, their capabilities for the description of leaf density distributions and the simulation of aLiDAR and DHP signatures are shown. At an experimental test site, the suitability of the models, in order to systematically simulate and evaluate aLiDAR based LAI predictions under various scan settings is proven. This strategy makes it possible to show the importance of laser point sampling density, but also the diversity of scan angles and their quantitative effect onto error margins.

Monitoring biophysical and biochemical vegetation variables in space and time is key to understand the earth system. Operational approaches using remote sensing imagery rely on the inversion of radiative transfer models, which describe the interactions between light and vegetation canopies. The inversion required to estimate vegetation variables is, however, an ill-posed problem because of variable compensation effects that can cause different combinations of soil and canopy variables to yield extremely similar spectral responses. In this contribution, we present a novel approach to visualise the ill-posed problem using self-organizing maps (SOM), which are a type of unsupervised neural network. The approach is demonstrated with simulations for Sentinel-2 data (13 bands) made with the Soil-Leaf-Canopy (SLC) radiative transfer model. A look-up table of 100,000 entries was built by randomly sampling 14 SLC model input variables between their minimum and maximum allowed values while using both a dark and a bright soil. The Sentinel-2 spectral simulations were used to train a SOM of 200 × 125 neurons. The training projected similar spectral signatures onto either the same, or contiguous, neuron(s). Tracing back the inputs that generated each spectral signature, we created a 200 × 125 map for each of the SLC variables. The lack of spatial patterns and the variability in these maps indicate ill-posed situations, where similar spectral signatures correspond to different canopy variables. For Sentinel-2, our results showed that leaf area index, crown cover and leaf chlorophyll, water and brown pigment content are less confused in the inversion than variables with noisier maps like fraction of brown canopy area, leaf dry matter content and the PROSPECT mesophyll parameter. This study supports both educational and on-going research activities on inversion algorithms and might be useful to evaluate the uncertainties of retrieved canopy biophysical and biochemical state variables. [ABSTRACT FROM AUTHOR]

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Photochemical reflectance index (PRI) is an intriguing avenue for monitoring photosynthetic light use efficiency (LUE), which is a crucial physiological variable and the primary source of uncertainty in gross primary production (GPP) prediction. The correlations between PRI and LUE induced by the energy-dependent xanthophyll cycle are overall convincing at the leaf scale. However, their relationship becomes complicated and less reliable at the canopy scale due to several confounding factors, such as soil background, canopy structure and sun-observer geometry. A fundamental understanding of the interrelated effects of these factors is still missing. In this study, the roles of soil reflectance, canopy structure and sun-observer geometry were examined by investigating radiative transfer processes that determine canopy PRI. Theoretical analysis shows that the deviation between canopy- and leaf-level PRI is mainly attributed to soil background, namely the fraction of sunlit soil in the scene and the discrepancy between leaf and soil reflectance. Canopy structure and sun-observer geometry are not the direct drivers of variations in canopy PRI. They affect canopy PRI by altering the contribution of soil to canopy reflectance. Furthermore, several numerical experiments based on 1D and 3D radiative transfer models, which compare PRI of canopies with black soil (i.e., soil reflectance is zero) and non-black background, were conducted to confirm and validate the decisive role of soil background in explaining the deviation between canopy and leaf PRI. Multi-angular canopy PRI from PROBA-CHRIS data was employed to examine the angular dependency of canopy PRI changing with vegetation coverage. The numerical experiments demonstrate that canpy PRI differs from leaf PRI as large as 150% when canopy leaf area index (LAI) or the fraction of vegetation coverage is small. Canopy PRI is almost identical to soil PRI (i.e., PRI computed from soil reflectance) when the contribution of soil background to canopy reflectance is large. In contrast, when the soil reflectance is zero or LAI is greater than four, canopy PRI is almost identical to leaf PRI and independent of canopy structure and sun-observer geometry. Nonetheless, when leaf and soil reflectance are similar, canopy PRI is always close to leaf PRI regardless canopy structure and sun-observer geometry. The analysis of multi-angular PRI reveals that the angular dependency decreases with vegetation coverage due to weaker soil background effect. This study narrows down the causes of variation in canopy PRI to the fraction of observed soil background and soil reflectance. It suggests that estimating and accounting for the soil contribution to canopy PRI are necessary to mitigate angular and canopy structural effects on canopy PRI and eventually extract leaf physiological information from canopy PRI. • Interrelated effects of soil, structure and angles on canopy PRI are examined. • Structure and sun-observer geometry impact canopy PRI by altering soil fraction. • Canopy PRI differs from leaf PRI mainly due to soil background. • If soil background effect is removed, canopy PRI is almost identical to leaf PRI. [ABSTRACT FROM AUTHOR]

The first airborne hyperspectral campaign in the Antarctic Peninsula region was carried out by the British Antarctic Survey and partners in February 2011. This paper presents an insight into the applicability of currently available radiative transfer modelling and atmospheric correction techniques for processing airborne hyperspectral data in this unique coastal Antarctic environment. Results from the Atmospheric and Topographic Correction version 4 (ATCOR-4) package reveal absolute reflectance values somewhat in line with laboratory measured spectra, with Root Mean Square Error (RMSE) values of 5% in the visible near infrared (0.4-1 µm) and 8% in the shortwave infrared (1-2.5 µm). Residual noise remains present due to the absorption by atmospheric gases and aerosols, but certain parts of the spectrum match laboratory measured features very well. This study demonstrates that commercially available packages for carrying out atmospheric correction are capable of correcting airborne hyperspectral data in the challenging environment present in Antarctica. However, it is anticipated that future results from atmospheric correction could be improved by measuring in situ atmospheric data to generate atmospheric profiles and aerosol models, or with the use of multiple ground targets for calibration and validation. [ABSTRACT FROM AUTHOR]