Search

Coesite, a high-pressure silica polymorph (pressure 3--10 GPa, temperature <3000 K), is a diagnostic feature of shock metamorphism associated with impact cratering on quartz-bearing target rocks. It is preserved as a metastable phase in sedimentary target rocks that experienced peak pressures in excess of ~10 GPa, where it typically occurs as intergranular polycrystalline aggregates of microcrystals embedded in silica glass known as "symplectic regions." The presence of coesite in the symplectic regions of rocks experiencing shock conditions beyond the limits of the coesite stability field is a controversial issue. Through a combined scanning and transmission electron microscopy and Raman spectroscopy study of shocked quartzarenites from the 45-m-diameter Kamil Crater (southwest Egypt), we show that coesite in symplectic regions forms through direct subsolidus transformation from quartz, in contrast with the prevailing hypothesis for crystalline targets. The quartz-to-coesite transformation takes place during localized shock-wave reverberation at the beginning of the pore collapse process. Complete pore collapse generates the high temperature regimes responsible for the subsequent production of the embedding silica melts, in part at the expense of the previously formed coesite. This work documents the role of pore collapse in producing localized pressure-temperature-time gradients in shocked porous targets, as predicted by numerical models in the literature. [ABSTRACT FROM AUTHOR]

Introduction: Coesite is one of the most common and reliable indicator of shock metamorphism associated with impact cratering in quartz-bearing target rocks. For this reason, coesite is the subject of numerous studies aiming to better understand how silica polymorphs react under sudden and extreme P-T increases. In impact rocks, coesite is preserved as a metastable phase in crystalline rocks that experienced peak shock pressures above ~30-40 GPa [1] and in porous sedimentary rocks shocked at pressures as low as ~10 GPa [2]. Furthermore, impact-coesite generally forms aggregates of microcrystalline grains scattered within silica amorphous material known as "symplectic regiorns", and shows a characteristic polysynthetic twinning on (100) with the composition plane (010) [3]. There is a general consensus that the characteristic twinned impact-coesite is the result of crystallisation from a dense amorphous phase, either silica shock melt [1] or highly densified diaplectic silica glass [4], during shock unloading, when the pressure release path passes through the coesite stability field. In contrast to these models, the coesite transformation mechanism through a direct solid-state transition from quartz was suggested the first time by [5] studying shocked Coconino sandstones from the Barringer crater (Arizona, USA). Our recent FESEM-TEM study, performed on impact ejecta from Kamil crater in Egypt and the Australasian tektite strewn field, confirms that the impact coesite forms through direct quartz-coesite transformation [6,7,8]. Samples and Methods: Samples are from two different impact sites including a shocked porous sandstone from Kamil crater (Egypt) and two coesite-bearing quartz ejecta from the Australasian tektite/microtektite strewn field (ODP site 1144A and Sonne Core SO95-17957-2). All samples were investigated using field emission gun - scanning electron microscopy (FEG-SEM), and then 5 electron-transparent lamellae from the Kamil crater shocked sandstone and 3 lamellae from the Australasian coesite-bearing ejecta were exctracted using focused-ion beam (FIB). These lamellae were investigated by transmission electron microscopy (TEM) and 3D electron diffraction (3D ED) [9] for nano-petrographic and crystallographic analyses. Remarkably, both samples experienced relatively fast cooling, which preserved shock metamorphic mineralogies and textures only slightly altered by post-impact melting, (i.e., virtually unaffected by post-shock annealing and/or hydrothermal overprint). Results and discussion: In Kamil ejecta we found rounded single-crystal coesite domains of 200 nm or less. These domains are surrounded by shocked quartz, without any amorphous phase in-between. We also observed larger coesite domains. The larger the domains, the more they appear fragmented and progressively dispersed and resorbed in amorphous silica. Our observations suggest that coesite seeds nucleate and grow inside quartz during pressure uploading, probably favored by shock-wave reverberation. Later, when pressure is released and temperature is still high, coesite domains fragment and melt giving rise to the "symplectic regions" observed - for instance - at Barringer [5], Yilan [10], Lonar [11], Cheasapeak Bay [12]. In impact ejecta from the Australasian tektite strewn field, we again observe coesite crystals embedded in shocked quartz. Coesite crystals have well-developed euhedral habits, which grow at the expense of neighboring quartz and appear to postdate PDFs and other planar microstructures. In both ejecta, 3D electron diffraction reveals coesite grains displaying a recurrent crystallographic relation with quartz, with (010) coesite plane parallel to {10-11} or {-1011} of quartz. Such evidence suggests a topotactic relation between shocked quartz and impact coesite. The direct quartz to cosite subsolidus reaction is facilitated by the presence of preexisting and shock-induced discontinuities in the target. Shock wave reverberations can provide pressure and time conditions for coesite nucleation and growth. Because discontinuities occur in both porous and non-porous rocks and the coesite formation mechanism appears similar for small and large impacts, we infer that the proposed subsolidus transformation model is valid for all types of quartz-bearing target rocks. [ABSTRACT FROM AUTHOR]

We report the occurrence of microscopic inclusions of shocked quartz plus a Zr phase and trace of Fe oxide crystallites in Australasian microtektites recovered from deep-sea sediment cores within 2000 km of Indochina. The shocked quartz and the Zr phase are interpreted as relicts of the target rock. Furthermore, the internal homogeneity of Australasian microtektites in terms of abundance of relict mineral inclusions, vesicles, and schlieren increases with distance from Indochina. This finding strengthens the current hypothesis that the source crater of the largest and youngest tektite strewn field on Earth is located in the Indochina region, as internal heterogeneity characterizes normal impact glass found in or near the source crater. This finding also indicates that the Australasian microtektites with the longest trajectories underwent the highest temperatures or were heated longer. The definition of microtektites should include the possible occurrence of microscopic relict inclusions as an indication of proximity to the source crater. [ABSTRACT FROM AUTHOR]