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In this paper we study the dynamics of an ensemble of nitrogen-vacancy centers in diamond when its photoluminescence is detected by means of a widefield imaging system. We develop a seven-level model and use it to simulate the widefield detection of nitrogen-vacancy centers Rabi oscillations. The simulation results are compared with experimental measurements showing a good agreement. In particular, we use the model to explain the asymmetric shape of the detected Rabi oscillations due to an incomplete repolarization of the nitrogen-vacancy center during the pulse sequence implemented for the detection of Rabi oscillations., Comment: 14 pages, 7 figures

Engineering a layer of nitrogen-vacancy (NV) centers on the tip of a diamond anvil creates a multipurpose quantum sensors array for high pressure measurements, especially for probing magnetic and superconducting properties of materials. Expanding this concept above 100 GPa appears to be a substantial challenge. We observe that deviatoric stress on the anvil tip sets a limit at 40-50 GPa for practical magnetic measurements based on optically detected magnetic resonance (ODMR) of NV centers under pressure. We show that this limit can be circumvented up to at least 130 GPa by machining a micropillar on the anvil tip to create a quasi-hydrostatic stress environment for the NV centers. This is quantified using the pressure dependence of the diamond Raman shift, the NV ODMR dependence on applied magnetic field, and NV photoluminescence spectral shift. This paves the way for direct and reliable detection of the Meissner effect in superconductors above 100 GPa, such as super-hydrides., Comment: 5 pages, 4 figures

The spin readout of an ensemble of nitrogen-vacancy (NV) centers in diamond can be realized by a photoconductive detection that is a complementary method to the optical detection of the NV electron spin magnetic resonance. Here, we implement the photoconductive detection through graphitic planar electrodes that collect the photocurrent. Graphitic electrodes are patterned using a xenon Focused-Ion Beam on an Optical-Grade quality diamond crystal containing a nitrogen concentration of ~1 ppm and a NV concentration of a few ppb. Resistance and current-voltage characteristics of the NV-doped diamond junction are investigated tuning the 532 nm pump beam intensity. The junction has an ohmic behavior and under a strong bias field, we observe velocity saturation of the optically-induced carriers in the diamond junction. We perform the photoconductive detection in continuous-wave regime of the magnetic resonance of the NV centers ensemble for a magnetic field applied along the <100> and the <111> direction with a magnitude above 100 mT. This technique enables the realization of all-carbon diamond quantum sensors integrating graphitic microstructures for the electrical readout., Comment: 11 pages, 3 figures, the following article has been submitted to Applied Physics Letters

We investigate the optical properties of silicon-vacancy (SiV) and germanium-vacancy (GeV) color centers in nanodiamonds under hydrostatic pressure up to 180 GPa. The nanodiamonds were synthetized by Si or Ge-doped plasma assisted chemical vapor deposition and, for our experiment, pressurized in a diamond anvil cell. Under hydrostatic pressure we observe blue-shifts of the SiV and GeV zero-phonon lines by 17 THz (70 meV) and 78 THz (320 meV), respectively. These measured pressure induced shifts are in good agreement with ab initio calculations that take into account the lattice compression based on the equation of state of diamond and that are extended to the case of the tin-vacancy (SnV) center. This work provides guidance on the use of group-IV-vacancy centers as quantum sensors under extreme pressures that will exploit their specific optical and spin properties induced by their intrinsic inversion-symmetric structure., Comment: 7 pages, 4 figures

The fast development of radio-frequency (RF) technologies increases the need for compact, low consumption and broadband real-time RF spectral analyser. To overcome the electronic bottleneck encountered by electronic solutions, which limits the real time bandwidth to hundreds of MHz, we propose a new approach exploiting the quantum properties of the nitrogen-vacancy (NV) center in diamond. Here we describe a Quantum Diamond Signal Analyser (Q-DiSA) platform and characterize its performances. We successfully detect RF signals over a large tunable frequency range (25 GHz), a wide instantaneous bandwidth (up to 4 GHz), a MHz frequency resolution (down to 1 MHz), a ms temporal resolution and a large dynamic range (40 dB).

The Brownian motion of a particle hotter than its environment is an iconic out-of-equilibrium system. Its study provides valuable insights into nanoscale thermal effects. Notably, it supplies an excellent diagnosis of thermal effects in optically levitated particles, a promising platform for force sensing and quantum physics tests. Thus, understanding the relevant parameters in this effect is critical. In this context, we test the role of particles' shape and material, using optically levitated nanodiamonds hosting NV centers to measure the particles' internal temperature and center-of-mass dynamics. We present a model to assess the nanodiamond internal temperature from its dynamics, adaptable to other particles. We also demonstrate that other mechanisms affect the nanodiamond dynamics and its stability in the trap. Finally, our work, by showing levitating nanodiamonds as an excellent tool for studying nano-thermal effects, opens prospects for increasing the trapping stability of optically levitated particles., Comment: 14 pages with supporting information

Scanning diamond magnetometers based on the optically detected magnetic resonance of the nitrogen-vacancy centre offer very high sensitivity and non-invasive imaging capabilities when the stray fields emanating from ultrathin magnetic materials are sufficiently low (< 10 mT). Beyond this low-field regime, the optical signal quenches and a quantitative measurement is challenging. While the field-dependent NV photoluminescence can still provide qualitative information on magnetic morphology, this operation regime remains unexplored particularly for surface magnetisation larger than $\sim$ 3 mA. Here, we introduce a multi-angle reconstruction technique (MARe) that captures the full nanoscale domain morphology in all magnetic-field regimes leading to NV photoluminescence quench. To demonstrate this, we use [Ir/Co/Pt]$_{14}$ multilayer films with surface magnetisation an order of magnitude larger than previous reports. Our approach brings non-invasive nanoscale magnetic field imaging capability to the study of a wider pool of magnetic materials and phenomena.

We report the possibility to simultaneously perform wide-field nitrogen-vacancy (NV) diamond magnetic microscopy and synchrotron X-ray diffraction (XRD) measurements at high pressure. NV color centers are created on the culet of a diamond anvil which is integrated in a diamond anvil cell for static compression of the sample. The optically detected spin resonance of the NV centers is used to map the stray magnetic field produced by the sample magnetization. Using this combined scheme, the magnetic and structural behaviors can be simultaneously measured. As a proof-of-principle, we record the correlated {\alpha}-Fe to {\epsilon}-Fe structural and magnetic transitions of iron that occur here between 15 and 20 GPa at 300 K., Comment: 12 pages, 4 figures

We propose an hybrid laser system consisting of a semiconductor external cavity laser associated to an intra-cavity diamond etalon doped with nitrogen-vacancy color centers. We consider laser emission tuned to the infrared absorption line that is enhanced under the magnetic field dependent nitrogen-vacancy electron spin resonance and show that this architecture leads to a compact solid-state magnetometer that can be operated at room-temperature. The sensitivity to the magnetic field limited by the photon shot-noise of the output laser beam is estimated to be around $250~\mathrm{fT/\sqrt{Hz}}$. Unlike usual NV center infrared magnetometry, this method would not require an external frequency stabilized laser. Since the proposed system relies on the competition between the laser threshold and an intracavity absorption, such laser-based optical sensor could be easily adapted to a broad variety of physical systems.

We present both theoretical and experimental results on fluorescence of single defect centers in diamond nanocrystals embedded in a planar dielectric microcavity. From a theoretical point of view, we show that the overall fluorescence collection efficiency using moderate numerical aperture microscope objective can be enhanced by using a low quality factor microcavity. This could be used in particular for low temperature applications where the numerical aperture of collection microscope objectives is limited due to the experimental constraints. We experimentally investigate the control of the fluorescence spectrum of the emitted light from a single center. We show the simultaneous narrowing of the room temperature broadband emission spectrum and the increase of the fluorescence spectral density., Comment: 22 pages, 10 figures

We investigate the electron spin resonance of an ensemble of Nitrogen-Vacancy (NV) color centers in a bulk diamond crystal. The four possible orientations of the NV-center in the lattice lead to different dependences on the magnitude and the orientation of an external static magnetic field. Experimental results obtained with a continuous microwave excitation are in good agreement with simulations. In addition, we observe that the average radiative lifetime of the NV color center is also modified when the external magnetic field is applied. This variation is explained by the mixing between mS = 0 and mS = $\pm$1 spin states of the NV-center with different radiative lifetimes, due to magnetic coupling. These results are of interest for a broad range of applications, such as spin-resonance-based magnetometry with a high-density ensemble of NV-centers, Comment: 14 pages, published on Applied Physics Letters journal

We report an experimental test of complementarity using clock-triggered single-photon pulses emitted by an individual N-V color center in a diamond nanocrystal. The single photons are sent into a Mach-Zehnder interferometer with an output beamsplitter of adjustable reflection coefficient R. In addition, the choice of introducing or removing this beamsplitter is random and relativistically space-like separated from the entering of the photon inside the interferometer, as required for the Wheeler's delayed-choice regime. Each set value of R allows us to observe interference with visibility V and to obtain incomplete which-path information characterized by the distinguishability D. The measured values of V and D are found to obey the complementarity relation V^2 + D^2 =< 1.

Wheeler has strikingly illustrated the wave-particle duality by the delayed-choice thought experiment, in which the configuration of a 2-path interferometer is chosen after a single-photon light-pulsed has entered it. We present a quantitative theoretical analysis of an experimental realization of Wheeler's proposal.

We report the realization of a solid-state triggered single-photon source with narrow emission in the near infrared at room temperature. It is based on the photoluminescence of a single nickel-nitrogen NE8 colour centre in a chemical vapour deposited diamond nanocrystal. Stable single-photon emission has been observed in the photoluminescence under both continuous-wave and pulsed excitations. The realization of this source represents a step forward in the application of diamond-based single-photon sources to Quantum Key Distribution (QKD) under practical operating conditions., Comment: 10 pages

We report an optical technique that yields an enhancement of single-molecule photostability, by greatly suppressing photobleaching pathways which involve photoexcitation from the triplet state. This is accomplished by dynamically switching off the excitation laser when a quantum-jump of the molecule to the triplet state is optically detected. This procedure leads to a lengthened single-molecule observation time and an increased total number of detected photons. The resulting improvement in photostability unambiguously confirms the importance of photoexcitation from the triplet state in photobleaching dynamics, and may allow the investigation of new phenomena at the single-molecule level.

The quantum "mystery which cannot go away" (in Feynman's words) of wave-particle duality is illustrated in a striking way by Wheeler's delayed-choice GedankenExperiment. In this experiment, the configuration of a two-path interferometer is chosen after a single-photon pulse has entered it : either the interferometer is \textit{closed} (\textit{i.e.} the two paths are recombined) and the interference is observed, or the interferometer remains \textit{open} and the path followed by the photon is measured. We report an almost ideal realization of that GedankenExperiment, where the light pulses are true single photons, allowing unambiguous which-way measurements, and the interferometer, which has two spatially separated paths, produces high visibility interference. The choice between measuring either the 'open' or 'closed' configuration is made by a quantum random number generator, and is space-like separated -- in the relativistic sense -- from the entering of the photon into the interferometer. Measurements in the closed configuration show interference with a visibility of 94%, while measurements in the open configuration allow us to determine the followed path with an error probability lower than 1%.

We report on the observation of single colour centers in natural diamond samples emitting in the near infrared region when optically excited. Photoluminescence of these single emitters have several striking features, such as a narrow-band fully polarized emission (FWHM 2 nm) around 780 nm, a short excited-state lifetime of about 2 ns, and perfect photostability at room temperature under our excitation conditions. We present a detailed study of their photophysical properties. Development of a triggered single-photon source relying on this single colour centre is discussed in the prospect of its application to quantum key distribution., Comment: 9 pages

We present a full implementation of a quantum key distribution (QKD) system with a single photon source, operating at night in open air. The single photon source at the heart of the functional and reliable setup relies on the pulsed excitation of a single nitrogen-vacancy color center in diamond nanocrystal. We tested the effect of attenuation on the polarized encoded photons for inferring longer distance performance of our system. For strong attenuation, the use of pure single photon states gives measurable advantage over systems relying on weak attenuated laser pulses. The results are in good agreement with theoretical models developed to assess QKD security.

n a recent experiment, we reported the time-domain intensity noise measurement of a single photon source relying on single molecule fluorescence control. In this article we present data processing, starting from photocount timestamps. The theoretical analytical expression of the time-dependent Mandel parameter Q(T) of an intermittent single photon source is derived from ON<->OFF dynamics . Finally, source intensity noise analysis using the Mandel parameter is quantitatively compared to the usual approach relying on the time autocorrelation function, both methods yielding the same molecular dynamical parameters., Comment: 22 pages, 7 figures