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Conventional information processors freely convert information between different physical carriers to process, store, or transmit information. It seems plausible that quantum information will also be held by different physical carriers in applications such as tests of fundamental physics, quantum-enhanced sensors, and quantum information processing. Quantum-controlled molecules in particular could transduce quantum information across a wide range of quantum-bit (qubit) frequencies, from a few kHz for transitions within the same rotational manifold, a few GHz for hyperfine transitions, up to a few THz for rotational transitions, to hundreds of THz for fundamental and overtone vibrational and electronic transitions, possibly all within the same molecule. Here, we report the first demonstration of entanglement between states of the rotation of a $\rm^{40}CaH^+$ molecular ion and internal states of a $\rm^{40}Ca^+$ atomic ion. The qubit addressed in the molecule has a frequency of either 13.4 kHz or 855 GHz, highlighting the versatility of molecular qubits. This work demonstrates how molecules can transduce quantum information between qubits with different frequencies to enable hybrid quantum systems. We anticipate that quantum control and measurement of molecules as demonstrated here will create opportunities for quantum information science, quantum sensors, fundamental and applied physics, and controlled quantum chemistry., Comment: 19 pages, 3 figures

Laser cooling and trapping of atoms and atomic ions has led to numerous advances including the observation of exotic phases of matter, development of exquisite sensors and state-of-the-art atomic clocks. The same level of control in molecules could also lead to profound developments such as controlled chemical reactions and sensitive probes of fundamental theories, but the vibrational and rotational degrees of freedom in molecules pose a formidable challenge for controlling their quantum mechanical states. Here, we use quantum-logic spectroscopy (QLS) for preparation and nondestructive detection of quantum mechanical states in molecular ions. We develop a general technique to enable optical pumping and preparation of the molecule into a pure initial state. This allows for the observation of high-resolution spectra in a single ion (here CaH+) and coherent phenomena such as Rabi flopping and Ramsey fringes. The protocol requires a single, far-off resonant laser, which is not specific to the molecule, so that many other molecular ions, including polyatomic species, could be treated with the same methods in the same apparatus by changing the molecular source. Combined with long interrogation times afforded by ion traps, a broad range of molecular ions could be studied with unprecedented control and precision, representing a critical step towards proposed applications, such as precision molecular spectroscopy, stringent tests of fundamental physics, quantum computing, and precision control of molecular dynamics., Comment: 38 pages in preprint format, 9 figures, 3 tables; added references

One of the outstanding challenges for ion trap quantum information processing is to accurately detect the states of many ions in a scalable fashion. In the particular case of surface traps, geometric constraints make imaging perpendicular to the surface appealing for light collection at multiple locations with minimal cross-talk. In this report we describe an experiment integrating Diffractive Optic Elements (DOE's) with surface electrode traps, connected through in-vacuum multi-mode fibers. The square DOE's reported here were all designed with solid angle collection efficiencies of 3.58%; with all losses included a detection efficiency of 0.388% (1.02% excluding the PMT loss) was measured with a single Ca+ ion. The presence of the DOE had minimal effect on the stability of the ion, both in temporal variation of stray electric fields and in motional heating rates., 6 pages, 8 figures

We demonstrate a general method for state detection of trapped ions that can be applied to a large class of atomic and molecular species. We couple a "spectroscopy" ion (Al+) to a "control" ion (Mg+) in the same trap and perform state detection through off-resonant laser excitation of the spectroscopy ion that induces coherent motion. The motional amplitude, dependent on the spectroscopy ion state, is measured either by time-resolved photon counting, or by resolved sideband excitations on the control ion. The first method provides a simplified way to distinguish "clock" states in Al+, which avoids ground state cooling and sideband transitions. The second method reduces spontaneous emission and optical pumping on the spectroscopy ion, which we demonstrate by nondestructively distinguishing Zeeman sublevels in the 1S0 ground state of Al+., Comment: 5 pages, 3 figures. Replaced with published version

We place two atoms in quantum superposition states and observe coherent phase evolution for 3.4x10^15 cycles. Correlation signals from the two atoms yield information about their relative phase even after the probe radiation has decohered. This technique was applied to a frequency comparison of two Al+ ions, where a fractional uncertainty of 3.7+1.0-0.8x10^-16/\sqrt{\tau/s} was observed. Two measures of the Q-factor are reported: The Q-factor derived from quantum coherence is 3.4+2.4-1.1x10^16, and the spectroscopic Q-factor for a Ramsey time of 3 s is 6.7x10^15. As part of this experiment, we demonstrate a method to detect the individual quantum states of two Al+ ions in a Mg+-Al+-Al+ linear ion chain without spatially resolving the ions., Comment: 4 pages, 4 figures

We have constructed an optical clock with a fractional frequency inaccuracy of 8.6e-18, based on quantum logic spectroscopy of an Al+ ion. A simultaneously trapped Mg+ ion serves to sympathetically laser-cool the Al+ ion and detect its quantum state. The frequency of the 1S0->3P0 clock transition is compared to that of a previously constructed Al+ optical clock with a statistical measurement uncertainty of 7.0e-18. The two clocks exhibit a relative stability of 2.8e-15/ sqrt(tau), and a fractional frequency difference of -1.8e-17, consistent with the accuracy limit of the older clock., 4 pages, 2 tables, 3 figures

We have investigated theoretically and experimentally a method for preparing Dicke states in trapped atomic ions. We consider a linear chain of $N$ ion qubits that is prepared in a particular Fock state of motion, $|m>$. The $m$ phonons are removed by applying a laser pulse globally to the $N$ qubits, and converting the motional excitation to $m$ flipped spins. The global nature of this pulse ensures that the $m$ flipped spins are shared by all the target ions in a state that is a close approximation to the Dicke state $\D{N}{m}$. We calculate numerically the fidelity limits of the protocol and find small deviations from the ideal state for $m = 1$ and $m = 2$. We have demonstrated the basic features of this protocol by preparing the state $\D{2}{1}$ in two $^{25}$Mg$^+$ target ions trapped simultaneously with an $^{27}$Al$^+$ ancillary ion., 5 pages, 2 figures

We demonstrate entanglement distribution between two remote quantum nodes located 3 meters apart. This distribution involves the asynchronous preparation of two pairs of atomic memories and the coherent mapping of stored atomic states into light fields in an effective state of near maximum polarization entanglement. Entanglement is verified by way of the measured violation of a Bell inequality, and can be used for communication protocols such as quantum cryptography. The demonstrated quantum nodes and channels can be used as segments of a quantum repeater, providing an essential tool for robust long-distance quantum communication., 10 pages, 7 figures. Text revised, additional information included in Appendix. Published online in Science Express, 5 April, 2007

We report significant improvements in the retrieval efficiency of a single excitation stored in an atomic ensemble and in the subsequent generation of strongly correlated pairs of photons. A 50% probability of transforming the stored excitation into one photon in a well-defined spatio-temporal mode at the output of the ensemble is demonstrated. These improvements are illustrated by the generation of high-quality heralded single photons with a suppression of the two-photon component below 1% of the value for a coherent state. A broad characterization of our system is performed for different parameters in order to provide input for the future design of realistic quantum networks.

Conditioned upon a photoelectric event, entanglement is created between two atomic ensembles separated by 2.8 m. The joint atomic state is transferred to two light modes and entanglement verified by quantum state tomography.