26 results on '"Thi K"'
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2. Investigation of the Desalination Capacity of Activated Carbon Materials from Water Hyacinth (Eichhornia crassipes) Stems
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Van Phuoc Nguyen, Dinh Duy Duong, Thi Tuu Tran, Huynh Cang Mai, Thi Kim Ngan Tran, Van Tan Lam, and Long Giang Bach
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activated carbon ,desalination ,water hyacinth ,Chemistry ,QD1-999 - Abstract
To reduce the hazards brought by water hyacinth, many applications of water hyacinth have been studied and continuously expanded. The large biomass of water hyacinth is applied in many fields such as for wastewater treatment, wastewater purification, biological raw material sources, animal feed production, medicine, antioxidants, agriculture, and household appliances. This research investigates the desalination capacity of freshwater hyacinths, raw materials from water hyacinths, biochar, and activated carbon materials from water hyacinth stems. Results have shown that the suitable temperature for charring fresh water hyacinth is 420 °C. The activated carbon from the water hyacinth stems with a BET surface area of 200.4 ± 1.9 m²/g can be desalinated under the conditions of 0.4 g of activated carbon mass, 15 min of reaction time, 2.0 ppt of salt concentration, and at neutral pH. In contrast, raw materials from water hyacinths and biochar were unable to desalinate. This study evaluates the desalination ability of the activated carbon material of water hyacinth.
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- 2024
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3. Controllable Synthesis of Hollow Silica Nanoparticles Using Layered Double Hydroxide Templates and Application for Thermal Insulation Coating
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Minh Vuong Phan, Thi Kim Thoa Tran, Quynh Nhu Pham, Manh Huy Do, Thi Hong No Nguyen, Minh Ty Nguyen, Thanh Thao Phan, and Thi Xuan Hang To
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Chemistry ,QD1-999 - Published
- 2023
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4. Study on the functionalization of activated carbon and the effect of binder toward capacitive deionization application
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Thi Thom Nguyen, Thi Kieu Anh Vo, Thi Thu Trang Nguyen, Thu Phuong Nguyen, Thi Mai Thanh Dinh, Dang Le Hai, Lam Tran Dai, and Thi Nam Pham
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modified activated carbon ,carbon electrode ,desalination ,capacitive deionization ,Chemistry ,QD1-999 - Abstract
The wettability and CV of mAC/Gt/PVA-GA and mAC/Gt/PVDF electrodes in 200 ppm NaCl solution at a scan rate of 5 mV·s−1. The variation of desalination capacity during 50 cycles for mAC/Gt/PVA-GA/Ti electrode.
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- 2022
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5. Synthesis of Porous Carbon Nanomaterials from Vietnamese Coal: Fabrication and Energy Storage Investigations
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Tra Huong Do, Van Tu Nguyen, Thi Nga Nguyen, Xuan Linh Ha, Quoc Dung Nguyen, and Thi Kim Ngan Tran
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porous coke carbon ,nanomaterials ,specific capacitance ,charge-transfer resistor ,supercapacitor ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
The choice of precursor and simple synthesis techniques have decisive roles in the viable production and commercialization of carbon products. The intense demand for developing high-purity carbon nanomaterials through inexpensive techniques has promoted the usage of fossil derivatives as a feasible source of carbon. In this study, Vietnamese-coal-derived porous carbon (PC) was used to fabricate coal-derived porous carbon nanomaterials (CDPCs) using the modified Hummers method. The resulting porous carbon nanomaterials achieved a nanoscale structure with an average pore size ranging from 3 to 10 nm. The findings indicate that CDPC exhibits well-developed micropores and mesopores. The presence of macropores and mesopores not only facilitates the complete immersion of the material in the electrolyte but also effectively shortens the ion diffusion pathways. CDPC boasts a high carbon content, constituting 80.88% by weight. Electrochemical impedance spectroscopy (EIS) Nyquist plot of electrodes made from CDPC showed good conductivity value with low charge-transfer resistance. This electrode worked well and stably with capacitance retention of 74.7% after 1000 cycles. The CDPC specific capacitance reached 236 F/g under a current density of 0.1 A using the constant current discharge method and then decreased as the current density increased. Based on the results of the electrochemical properties of the materials, the energy storage capacity of the CDPC material was good and stable. This investigation presents an eco-friendly methodology for the judicious utilization of coal in energy storage applications, specifically as electrodes for supercapacitors and anodes for Li-ion batteries.
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- 2024
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6. Antiproliferative, Anti-Inflammatory Activities, and Molecular Docking Studies of Secondary Metabolites from Macrosolen tricolor
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Van Son Dang, Kieu Hung Le, Thi Hong Tuoi Do, Le Thanh Tuyen Nguyen, Thi Phuong Lan Vu, Thi Kim Chi Huynh, Thi Kim Dung Hoang, Quan Hien Nguyen, Trong Nghia Ngo, Diep Xuan Ky Nguyen, Nhat Minh Phan, Trong Dat Bui, Dinh Tri Mai, and Tan Phat Nguyen
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Chemistry ,QD1-999 - Abstract
In Vietnam, Macrosolen tricolor is used for the treatment of bloating, broken bones, cough, diarrhea, diuretic, rheumatism, and laxative effects. The study aimed to identify the in vitro antiproliferation and anti-inflammation of all fractions and purified compounds from the M. tricolor whole plants, as well as the in silico molecular docking of the potentially cytotoxic compounds. As the results, fractions (MTH.I, MTH.II, MTE.I, and MTE.II) strongly demonstrated antiproliferative properties against three tested cells, MDA-MB-231, RD, and HepG2 (IC50 values ranged from 4.00 ± 0.20 to 70.60 ± 1.44 μg/mL), as well as anti-inflammatory effects (IC50 values ranged from 4.45 ± 0.08 to 23.00 ± 1.18 μg/mL), whereas other fractions meaningfully evidenced selective cytotoxicity and/or anti-inflammation. Therefore, the phytochemical compositions of the active fractions were illuminated, leading to the characterization of eighteen compounds. Compounds (3–5) revealed the most cytotoxic effects towards all examined cells (IC50 values ranged from 6.88 ± 0.12 to 71.64 ± 1.17 μM) and the strongest anti-inflammatory properties (IC50 values of 16.30 ± 0.92, 7.31 ± 0.55, and 9.23 ± 0.60 μM, respectively). Compound 11 showed potential cytotoxicity against MDA-MB-231, RD, and HepG2 cells (IC50 values of 24.42 ± 0.28, 20.60 ± 0.25, and 3.20 ± 0.02 μM, respectively). Furthermore, compounds (4, 5, and 11) interacted with the active site of the apoptosis regulator Bcl-2 protein (PDB ID: 2O2F), were comparable to PAC, and were compatible with their anticancer activity. This project suggests that M. tricolor is a good source of natural antiproliferative and anti-inflammatory agents and contributes to understanding the biological activities of Macrosolen species in traditional Vietnamese medicine.
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- 2023
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7. Enhanced photocatalytic activity of ZnO nanoparticles by surface modification with KF using thermal shock method
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Tien Khoa Le, Thi Minh Tram Nguyen, Huu Thinh Pham Nguyen, Thi Kieu Loan Nguyen, Torben Lund, Huu Khanh Hung Nguyen, and Thi Kieu Xuan Huynh
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Chemistry ,QD1-999 - Abstract
ZnO nanoparticles were modified with KF using thermal shock method at various temperatures in order to improve the photocatalytic activity of ZnO under both UVA and visible light irradiation. The influences of KF-modification on the crystal structure, morphology, UV–visible absorption, specific surface area as well as surface structure of ZnO were respectively characterized by XRD, FE-SEM, UV–Visible diffuse reflectance, N2 adsorption and XPS spectroscopy. The photocatalytic activity was evaluated via the degradation of methylene blue under UVA irradiation. According to the results, the thermal shock process with KF did not modify the structure, the particle size and the optical properties of ZnO nanoparticles but successfully increase their UVA and visible light induced photocatalytic activity. This enhancement of activity may be attributed to the increase of surface hydroxyl groups and zinc vacancies of modified ZnO samples. Keywords: ZnO nanoparticles, Thermal shock, KF, Methylene blue, Photocatalytic activity
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- 2020
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8. Characterization and photocatalytic activity of new photocatalysts based on Ag, F-modified ZnO nanoparticles prepared by thermal shock method
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Huu Thinh Pham Nguyen, Thi Minh Tram Nguyen, Chau Ngoc Hoang, Tien Khoa Le, Torben Lund, Huu Khanh Hung Nguyen, and Thi Kieu Xuan Huynh
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Chemistry ,QD1-999 - Abstract
Ag-modified ZnO, F-modified ZnO and (Ag, F)-modified ZnO nanoparticles were prepared by thermal shock method in order to study the effects of doping agents on their crystal structure, morphology, optical properties, surface structure and photocatalytic activity. The catalysts were characterized by XRD, FE-SEM, TEM, FTIR, UV–Visible diffuse reflectance and XPS spectroscopy. The photocatalytic activity was evaluated via the degradation of methylene blue under UVA and visible light irradiation. According to the results, the thermal shock process with AgNO3 did not modify the morphology but successfully created silver species on the surface of ZnO, which induces the visible light absorption and then increases the photocatalytic activity. The enhanced phototcatalytic performance was also observed in F-modified ZnO sample owing to the increase of surface hydroxyl groups and the formation of zinc vacancies. Among three modified ZnO samples, (Ag, F)-modified ZnO was found to be the best sample with the photocatalytic activity enhanced by the factor of 3 under both UVA and visible light, which may be attributed to the synergic effects of AgNO3 and KF used in thermal shock process. Keywords: ZnO nanoparticles, Ag-doping, F-doping, Thermal shock method, Photocatalytic activity
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- 2020
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9. Enhanced NH3 Sensing Performance of Mo Cluster-MoS2 Nanocomposite Thin Films via the Sulfurization of Mo6 Cluster Iodides Precursor
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Meiqi Zhang, Fabien Grasset, Yuji Masubuchi, Toshihiro Shimada, Thi Kim Ngan Nguyen, Noée Dumait, Adèle Renaud, Stéphane Cordier, David Berthebaud, Jean-François Halet, and Tetsuo Uchikoshi
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molybdenum octahedral cluster ,molybdenum disulfide ,sulfurization process ,gas sensor ,Chemistry ,QD1-999 - Abstract
The high-performance defect-rich MoS2 dominated by sulfur vacancies as well as Mo-rich environments have been extensively studied in many fields, such as nitrogen reduction reactions, hydrogen evolution reactions, as well as sensing devices for NH3, which are attributed to the under-coordinated Mo atoms playing a significant role as catalytic sites in the defect area. In this study, the Mo cluster-MoS2 composite was creatively synthesized through a one-step sulfurization process via H2/H2S gas flow. The Mo6 cluster iodides (MIs) coated on the fluorine-doped tin oxide (FTO) glass substrate via the electrophoretic deposition method (i.e., MI@FTO) were used as a precursor to form a thin-film nanocomposite. Investigations into the structure, reaction mechanism, and NH3 gas sensing performance were carried out in detail. The results indicated that during the gas flowing, the decomposed Mo6 cluster iodides played the role of template and precursor, forming complicated Mo cluster compounds and eventually producing MoS2. These Mo cluster-MoS2 thin-film nanocomposites were fabricated and applied as gas sensors for the first time. It turns out that after the sulfurization process, the response of MI@FTO for NH3 gas increased three times while showing conversion from p-type to n-type semiconductor, which enhances their possibilities for future device applications.
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- 2023
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10. Moving Standardization of HPTLC to the Next Level
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Thi Kieu Tien Do and Eike Reich
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HPTLC ,System suitability test ,Universal HPTLC mix (UHM) ,Chemistry ,QD1-999 - Published
- 2021
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11. A Numerical Analysis of Active Flow Control Techniques for Aerodynamic Drag Reduction in the Square-Back Ahmed Model
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Thanh-Long Phan, Quoc Thai Pham, Thi Kim Loan Nguyen, and Tien Thua Nguyen
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active flow control ,steady blowing jet ,synthetic jet ,unsteady jet ,aerodynamic drag reduction ,square-back Ahmed model ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
Aerodynamic drag reduction is required with new stringent constraints on pollutant emissions and fuel efficiency of ground vehicles. In this context, active flow control is a promising approach to achieve this target. This study focuses on applying different flow control strategies on the square-back Ahmed model to reduce aerodynamic drag. A steady blowing jet, a synthetic jet and an unsteady jet are located at the back edges of the model as flow control devices. A numerical study based on the 3D WMLES simulation was performed to evaluate the drag reduction capabilities of these devices at different operating conditions. The results showed that a maximum aerodynamic drag reduction of 26.51% was achieved when using a steady blowing jet, and 17.27% with an unsteady jet. In contrast, the effect of the synthetic jet on the aerodynamic drag of the model is solely at high control frequencies.
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- 2022
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12. Hafnium Oxide Nanostructured Thin Films: Electrophoretic Deposition Process and DUV Photolithography Patterning
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Vanessa Proust, Quentin Kirscher, Thi Kim Ngan Nguyen, Lisa Obringer, Kento Ishii, Ludivine Rault, Valérie Demange, David Berthebaud, Naoki Ohashi, Tetsuo Uchikoshi, Dominique Berling, Olivier Soppera, and Fabien Grasset
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hafnium oxide ,nanoparticles ,thin films ,nanoarchitectonic ,hydrothermal ,electrophoretic deposition ,Chemistry ,QD1-999 - Abstract
In the frame of the nanoarchitectonic concept, the objective of this study was to develop simple and easy methods to ensure the preparation of polymorphic HfO2 thin film materials (2 thin films with micropatterns or continuous morphologies were synthesized by two different methods, i.e., the micropatterning of sol-gel solutions by deep ultraviolet (DUV) photolithography or the electrophoretic deposition (EPD) of HfO2 nanoparticles (HfO2-NPs). Amorphous and monoclinic HfO2 micropatterned nanostructured thin films (HfO2-DUV) were prepared by using a sol-gel solution precursor (HfO2-SG) and spin-coating process following by DUV photolithography, whereas continuous and dense monoclinic HfO2 nanostructured thin films (HfO2-EPD) were prepared by the direct EPD of HfO2-NPs. The HfO2-NPs were prepared by a hydrothermal route and studied through the changing aging temperature, pH and reaction time parameters to produce nanocrystalline particles. Subsequently, based on the colloidal stability study, suspensions of the monoclinic HfO2-NPs with morphologies near spherical, spindle- and rice-like shapes were used to prepare HfO2-EPD thin films on conductive indium-tin oxide-coated glass substrates. Morphology, composition and crystallinity of the HfO2-NPs and thin films were investigated by powder and grazing incidence X-ray diffraction, scanning electron microscopy, transmission electron microscopy and UV-visible spectrophotometry. The EPD and DUV photolithography performances were explored and, in this study, it was clearly demonstrated that these two complementary methods are suitable, simple and effective processes to prepare controllable and tunable HfO2 nanostructures as with homogeneous, dense or micropatterned structures.
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- 2022
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13. Preparation of Nickel Nanocatalysts and Application to the Hydrodechlorination of 3-Chlorophenol under Liquid Phase
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Thanh Thien Co, Thi Kim Anh Tran, Thi Huong Ly Doan, and Thi Duyen Diep
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Chemistry ,QD1-999 - Abstract
Nickel nanoparticles were successfully synthesized via the reduction of nickel salt using ethylene glycol (EG) and sodium borohydride (NaBH4) as reducing agents. These nickel nanoparticles were then loaded on the supports as Ni-X (X = vanadium phosphorus oxides (VPO), TiO2, and ZnO) in high loading yield. The optical properties of these catalysts were characterized by UV-vis spectroscopy, the structure of Ni-X was studied by powder X-ray diffraction (PXRD), the distribution of Ni particles in X was studied by transmission electron microscopy (TEM), and the specific surface area of Ni-X was evaluated by N2 adsorption isotherm analysis at 77 K. All results corroborated the loading process. Indeed, TEM image indicated that the nickel nanoparticles size is in the range of 14 ÷ 16 nm and fully loaded into X. The activities of these catalysts were performed on the hydrodechlorination of 3-chlorophenol in the presence of sodium hydroxide as base at atmospheric pressure and at RT. The results showed that Ni-X exhibited high activities up to 98% within 90 min in the case of Ni-ZnO catalyst.
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- 2021
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14. Assessment of Some Characteristics and Properties of Zirconium Dioxide Nanoparticles Modified with 3-(Trimethoxysilyl) Propyl Methacrylate Silane Coupling Agent
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Phi Hung Dao, Thuy Chinh Nguyen, Thi Lan Phung, Tien Dung Nguyen, Anh Hiep Nguyen, Thi Ngoc Lan Vu, Quoc Trung Vu, Dinh Hieu Vu, Thi Kim Ngan Tran, and Hoang Thai
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Chemistry ,QD1-999 - Abstract
This study presents the results of surface modification of zirconium dioxide (ZrO2) nanoparticles by 3-(trimethoxysilyl) propyl methacrylate silane coupling agent by assessing some characteristics and properties of modified ZrO2 nanoparticles by infrared spectroscopy, thermogravimetric analysis, size distribution, zeta potential, and field emission scanning electron microscopy methods. The modified and unmodified ZrO2 nanoparticles have been used as nanoadditives for organic coatings based on acrylic emulsion resin. The abrasion resistance of acrylic coating was evaluated according to ASTM E968-15. The obtained results show that ZrO2 nanoparticles were functionalized successfully with 3-(trimethoxysilyl) propyl methacrylate silane. The modified ZrO2 nanoparticles exhibit a positive effectiveness in the enhancement of the abrasion resistance of acrylic resin coating compared to unmodified ZrO2 nanoparticles.
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- 2021
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15. Solvent Etching Process for Graphitic Carbon Nitride Photocatalysts Containing Platinum Cocatalyst: Effects of Water Hydrolysis on Photocatalytic Properties and Hydrogen Evolution Behaviors
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Thi Van Anh Hoang, Thi Kim Anh Nguyen, Duc Quang Dao, Phuong Anh Nguyen, Dong Hwi Jeong, and Eun Woo Shin
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solvent etching ,Pt/g-C3N4 ,tri-s-triazine unit ,water content ,hydrolysis ,photocatalytic hydrogen evolution ,Chemistry ,QD1-999 - Abstract
In this study, we synthesized Pt/g-C3N4 photocatalysts modified by a solvent etching process where ethanol (Pt/CN0), water (Pt/CN100), and a 50:50 mixture (Pt/CN50) were used as a solvent, and investigated the optimal properties of g-C3N4 to prepare the best Pt/g-C3N4 for photocatalytic hydrogen evolution. From diverse characterizations, water was proven to be a stronger solvent agent, resulting in not only the introduction of more O-functional groups onto the g-C3N4 surface, but also the degradation of a regular array of tri-s-triazine units in the g-C3N4 structure. While the addition of O-functional groups positively influenced the oxidation state of the Pt cocatalyst and the hydrogen production rate, the changes to g-C3N4 structure retarded charge transfer on its surface, inducing negative effects such as fast recombination and less oxidized Pt species. Pt/CN50 that was synthesized with the 50:50 solvent mixture exhibited the highest hydrogen production rate of 590.9 µmol g−1h−1, while the hydrogen production rates of Pt/CN0 (with pure ethanol solvent) and Pt/CN100 (with pure water solvent) were 462.7, and 367.3 µmol g−1h−1, respectively.
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- 2022
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16. Preparation of Carbon-Supported Ternary Nanocatalysts Palladium-Vanadium-Cobalt for Alcohol Electrooxidation
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Thanh Thien Co, Thi Thanh Thao Pham, Thi Kieu Chinh Pham, Thi Duyen Diep, Le Thanh Nguyen Huynh, and Viet Hai Le
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Chemistry ,QD1-999 - Abstract
Carbon-supported nanocatalysts palladium-vanadium-cobalt (PdVCo) were synthesized via ethylene glycol (EG) reduction reaction and NaBH4-assisted reduction. The electrocatalytic performance for alcohol oxidation in alkaline solutions was investigated. The XRD and EDX results confirmed the incorporation of V and Co with Pd lattice to form the ternary nanocatalysts PdVCo in a single phase. The NaBH4-assisted EG reduction process exhibited highly dispersed nanoparticles with a uniform size, and the electrochemical surface area (ECSA) determined by cyclic voltammetry in 1 M KOH was also superior. In electrocatalysis performance, the cyclic voltammetry (CV) and chronoamperometry (CA) results presented an excellent electrocatalytic activity and stability of the PdVCo-20EG-20NaBH4 sample in the alcohol electrooxidation as compared to other synthesized samples with the steady current of 52 mA/cm2 and 21.9 mA/cm2 in methanol and ethanol, respectively.
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- 2020
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17. Ethanol Solvothermal Treatment on Graphitic Carbon Nitride Materials for Enhancing Photocatalytic Hydrogen Evolution Performance
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Phuong Anh Nguyen, Thi Kim Anh Nguyen, Duc Quang Dao, and Eun Woo Shin
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graphitic carbon nitride ,ethanol solvothermal ,Pt oxidation state ,charge separation ,Chemistry ,QD1-999 - Abstract
Recently, Pt-loaded graphic carbon nitride (g-C3N4) materials have attracted great attention as a photocatalyst for hydrogen evolution from water. The simple surface modification of g-C3N4 by hydrothermal methods improves photocatalytic performance. In this study, ethanol is used as a solvothermal solvent to modify the surface properties of g-C3N4 for the first time. The g-C3N4 is thermally treated in ethanol at different temperatures (T = 140 °C, 160 °C, 180 °C, and 220 °C), and the Pt co-catalyst is subsequently deposited on the g-C3N4 via a photodeposition method. Elemental analysis and XPS O 1s data confirm that the ethanol solvothermal treatment increased the contents of the oxygen-containing functional groups on the g-C3N4 and were proportional to the treatment temperatures. However, the XPS Pt 4f data show that the Pt2+/Pt0 value for the Pt/g-C3N4 treated at ethanol solvothermal temperature of 160 °C (Pt/CN-160) is the highest at 7.03, implying the highest hydrogen production rate of Pt/CN-160 is at 492.3 μmol g−1 h−1 because the PtO phase is favorable for the water adsorption and hydrogen desorption in the hydrogen evolution process. In addition, the electrochemical impedance spectroscopy data and the photoluminescence spectra emission peak intensify reflect that the Pt/CN-160 had a more efficient charge separation process that also enhanced the photocatalytic activity.
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- 2022
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18. Soluble Prokaryotic Overexpression and Purification of Human GM-CSF Using the Protein Disulfide Isomerase b′a′ Domain
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Thi Kieu Oanh Nguyen, Thi Luong Vu, Minh Quan Nguyen, Huynh Kim Khanh Ta, Kyoung Sun Park, Soo Hyeon Kim, Chong Jai Kim, Yeon Jin Jang, and Han Choe
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hGM-CSF ,MBP ,PDI ,ClearColi ,Biology (General) ,QH301-705.5 ,Chemistry ,QD1-999 - Abstract
Granulocyte-macrophage colony-stimulating factor (GM-CSF) is a member of the colony-stimulating factor (CSF) family, which functions to enhance the proliferation and differentiation of hematopoietic stem cells and other hematopoietic lineages such as neutrophils, dendritic cells, or macrophages. These proteins have thus generated considerable interest in clinical therapy research. A current obstacle to the prokaryotic production of human GM-CSF (hGM-CSF) is its low solubility when overexpressed and subsequent complex refolding processes. In our present study, the solubility of hGM-CSF was examined when combined with three N-terminal fusion tags in five E. coli strains at three different expression temperatures. In the five E. coli strains BL21 (DE3), ClearColi BL21 (DE3), LOBSTR, SHuffle T7 and Origami2 (DE3), the hexahistidine-tagged hGM-CSF showed the best expression but was insoluble in all cases at each examined temperature. Tagging with the maltose-binding protein (MBP) and the b′a′ domain of protein disulfide isomerase (PDIb′a′) greatly improved the soluble overexpression of hGM-CSF at 30 °C and 18 °C. The solubility was not improved using the Origami2 (DE3) and SHuffle T7 strains that have been engineered for disulfide bond formation. Two conventional chromatographic steps were used to purify hGM-CSF from the overexpressed PDIb′a′-hGM-CSF produced in ClearColi BL21 (DE3). In the experiment, 0.65 mg of hGM-CSF was isolated from a 0.5 L flask culture of these E. coli and showed a 98% purity by SDS-PAGE analysis and silver staining. The bioactivity of this purified hGM-CSF was measured at an EC50 of 16.4 ± 2 pM by a CCK8 assay in TF-1 human erythroleukemia cells.
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- 2021
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19. Synergistic Effect on Photocatalytic Activity of Co-Doped NiTiO3/g-C3N4 Composites under Visible Light Irradiation
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Duc Quang Dao, Thi Kim Anh Nguyen, Thanh-Truc Pham, and Eun Woo Shin
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NiTiO3 ,g-C3N4 ,composite photocatalyst ,recombination ,photodegradation ,charge separation efficiency ,Chemical technology ,TP1-1185 ,Chemistry ,QD1-999 - Abstract
Co-doped NiTiO3/g-C3N4 composite photocatalysts were prepared by a modified Pechini method to improve their photocatalytic activity toward methylene blue photodegradation under visible light irradiation. The combination of Co-doped NiTiO3 and g-C3N4 and Co-doping into the NiTiO3 lattice synergistically enhanced the photocatalytic performance of the composite photocatalysts. X-ray photoelectron spectroscopy results for the Co-doped NiTiO3/g-C3N4 composite photocatalysts confirmed Ti-N linkages between the Co-doped NiTiO3 and g-C3N4. In addition, characteristic X-ray diffraction peaks for the NiTiO3 lattice structure clearly indicated substitution of Co into the NiTiO3 lattice structure. The composite structure and Co-doping of the C-x composite photocatalysts (x wt % Co-doped NiTiO3/g-C3N4) not only decreased the emission intensity of the photoluminescence spectra but also the semicircle radius of the Nyquist plot in electrochemical impedance spectroscopy, giving the highest kapp value (7.15 × 10−3 min−1) for the C-1 composite photocatalyst.
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- 2020
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20. Effect of Wing Corrugation on the Aerodynamic Efficiency of Two-Dimensional Flapping Wings
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Thanh Tien Dao, Thi Kim Loan Au, Soo Hyung Park, and Hoon Cheol Park
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computational fluid dynamics ,flapping wings ,curved wing ,corrugated wing ,angle of attack ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
Many previous studies have shown that wing corrugation of an insect wing is only structurally beneficial in enhancing the wing’s bending stiffness and does not much help to improve the aerodynamic performance of flapping wings. This study uses two-dimensional computational fluid dynamics (CFD) in aiming to identify a proper wing corrugation that can enhance the aerodynamic performance of the KUBeetle, an insect-like flapping-wing micro air vehicle (MAV), which operates at a Reynolds number of less than 13,000. For this purpose, various two-dimensional corrugated wings were numerically investigated. The two-dimensional flapping wing motion was extracted from the measured three-dimensional wing kinematics of the KUBeetle at spanwise locations of r = (0.375 and 0.75)R. The CFD analysis showed that at both spanwise locations, the corrugations placed over the entire wing were not beneficial for improving aerodynamic efficiency. However, for the two-dimensional flapping wing at the spanwise location of r = 0.375R, where the wing experiences relatively high angles of attack, three specially designed wings with leading-edge corrugation showed higher aerodynamic performance than that of the non-corrugated smooth wing. The improvement is closely related to the flow patterns formed around the wings. Therefore, the proposed leading-edge corrugation is suggested for the inboard wing of the KUBeetle to enhance aerodynamic performance. The corrugation in the inboard wing may also be structurally beneficial.
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- 2020
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21. Identification of Genes Associated with Sensitivity to Ultraviolet A (UVA) Irradiation by Transposon Mutagenesis of Vibrio parahaemolyticus
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Miki Maetani-Yasui, Kazuaki Mawatari, Airi Honjo, Thi Kim Ngan Bui, Takaaki Shimohata, Takashi Uebanso, Mutsumi Aihara, Takahiro Emoto, Masatake Akutagawa, Yohsuke Kinouchi, and Akira Takahashi
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light-emitting diode ,ultraviolet A ,Vibrio parahaemolyticus ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
Ultraviolet (UV) irradiation is used to disinfect water and food and can be classified as UVA (detected at wavelengths 320–400 nm), UVB (280–320 nm), and UVC (Vibrio parahaemolyticus and selected six mutants with high sensitivity to UVA irradiation. Genes associated with this phenotype include F-type H+-transporting ATPases (atp), as well as those involved in general secretion (gsp), and ubiquinone and terpenoid-quinone biosynthesis (ubi). Gene complementation resulted in decreased sensitivity to UVA-LED. The atp mutants had lower intracellular adenosine triphosphate (ATP) concentrations than the wild-type treatment, with 20 mM L-serine resulting in elevated ATP concentrations and decreased sensitivity to UVA-LED. The gsp mutants exhibited high levels of extracellular protein transport and the ubi mutants exhibited significantly different intracellular concentrations of ubiquinone-8. Taken together, our results suggest that the protein products of the atp, gsp, and ubi genes may regulate sensitivity to UVA irradiation.
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- 2020
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22. Type 3 Diabetes and Its Role Implications in Alzheimer’s Disease
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Thuy Trang Nguyen, Qui Thanh Hoai Ta, Thi Kim Oanh Nguyen, Thi Thuy Dung Nguyen, and Vo Van Giau
- Subjects
Alzheimer’s disease ,hypometabolism ,type 2 diabetes ,type 3 diabetes ,insulin resistance ,Biology (General) ,QH301-705.5 ,Chemistry ,QD1-999 - Abstract
The exact connection between Alzheimer’s disease (AD) and type 2 diabetes is still in debate. However, poorly controlled blood sugar may increase the risk of developing Alzheimer’s. This relationship is so strong that some have called Alzheimer’s “diabetes of the brain” or “type 3 diabetes (T3D)”. Given more recent studies continue to indicate evidence linking T3D with AD, this review aims to demonstrate the relationship between T3D and AD based on the fact that both the processing of amyloid-β (Aβ) precursor protein toxicity and the clearance of Aβ are attributed to impaired insulin signaling, and that insulin resistance mediates the dysregulation of bioenergetics and progress to AD. Furthermore, insulin-related therapeutic strategies are suggested to succeed in the development of therapies for AD by slowing down their progressive nature or even halting their future complications.
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- 2020
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23. Cancer Stem Cell Target Labeling and Efficient Growth Inhibition of CD133 and PD-L1 Monoclonal Antibodies Double Conjugated with Luminescent Rare-Earth Tb3+ Nanorods
- Author
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Thi Thao Do, Nhat Minh Le, Trong Nhan Vo, Thi Nga Nguyen, Thu Huong Tran, and Thi Kim Hue Phung
- Subjects
cancer stem cells ,cd133 mab ,ion tb3+ ,nanorod ,ntera-2 ,pd-l1 ,tmc ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
Rare-earth nanomaterials are being widely applied in medicine as cytotoxicity agents, in radiation and photodynamic therapy, as drug carriers, and in biosensing and bioimaging technology. Terbium (Tb), a rare-earth element belonging to the lanthanides, has a long luminescent lifetime, large stock displacement, narrow spectral width, and biofriendly probes. In cancer therapy, cancer stem cell (CSC)-targeted treatment is receiving considerable attention due to these cells’ harmful characteristics. However, CSCs remain barely understood. Therefore, to effectively label and inhibit the growth of CSCs, we produced a nanocomplex in which TbPO4·H2O nanorods were double conjugated with CD133 and PD-L1 monoclonal antibodies. The Tb3+ nanomaterials were created in the presence of a soft template (polyethylene glycol 2000). The obtained nanomaterial TbPO4·H2O was hexagonal crystal and nanorod in shape, 40−80 nm in diameter, and 300−800 nm in length. The nanorods were further surfaced through tetraethyl orthosilicate hydrolysis and functionalized with amino silane. Finally, the glutaraldehyde-activated Tb3+ nanorods were conjugated with CD133 monoclonal antibody and PD-L1 monoclonal antibody on the surface to obtain the nanocomplex TbPO4·H2O@silica-NH2+mAb^CD133+mAb^PD-L1 (TMC). The formed nanocomplex was able to efficiently and specifically label NTERA-2 cells, a highly expressed CD133 and PD-L1 CSC cell line. The conjugate also demonstrated promising anti-CSC activity by significant inhibition (58.50%) of the growth of 3D tumor spheres of NTERA-2 cells (p < 0.05).
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- 2020
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24. Current Transport Mechanism in Palladium Schottky Contact on Si-Based Freestanding GaN
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Moonsang Lee, Chang Wan Ahn, Thi Kim Oanh Vu, Hyun Uk Lee, Yesul Jeong, Myung Gwan Hahm, Eun Kyu Kim, and Sungsoo Park
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freestanding gan ,hvpe ,schottky diodes ,silicon ,transport mechanism ,Chemistry ,QD1-999 - Abstract
In this study, the charge transport mechanism of Pd/Si-based FS-GaN Schottky diodes was investigated. A temperature-dependent current−voltage analysis revealed that the I-V characteristics of the diodes show a good rectifying behavior with a large ratio of 103−105 at the forward to reverse current at ±1 V. The interface states and non-interacting point defect complex between the Pd metal and FS-GaN crystals induced the inhomogeneity of the barrier height and large ideality factors. Furthermore, we revealed that the electronic conduction of the devices prefers the thermionic field emission (TFE) transport, not the thermionic emission (TE) model, over the entire measurement conditions. The investigation on deep level transient spectroscopy (DLTS) suggests that non-interacting point-defect-driven tunneling influences the charge transport. This investigation about charge transport paves the way to achieving next-generation optoelectronic applications using Si-based FS-GaN Schottky diodes.
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- 2020
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25. Multiple Feature Integration for Classification of Thoracic Disease in Chest Radiography
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Thi Kieu Khanh Ho and Jeonghwan Gwak
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chestx-ray14 ,multiple feature integration ,shallow features ,deep features ,convolutional neural network ,pretrained model ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
The accurate localization and classification of lung abnormalities from radiological images are important for clinical diagnosis and treatment strategies. However, multilabel classification, wherein medical images are interpreted to point out multiple existing or suspected pathologies, presents practical constraints. Building a highly precise classification model typically requires a huge number of images manually annotated with labels and finding masks that are expensive to acquire in practice. To address this intrinsically weakly supervised learning problem, we present the integration of different features extracted from shallow handcrafted techniques and a pretrained deep CNN model. The model consists of two main approaches: a localization approach that concentrates adaptively on the pathologically abnormal regions utilizing pretrained DenseNet-121 and a classification approach that integrates four types of local and deep features extracted respectively from SIFT, GIST, LBP, and HOG, and convolutional CNN features. We demonstrate that our approaches efficiently leverage interdependencies among target annotations and establish the state of the art classification results of 14 thoracic diseases in comparison with current reference baselines on the publicly available ChestX-ray14 dataset.
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- 2019
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26. Electronic Transport Mechanism for Schottky Diodes Formed by Au/HVPE a-Plane GaN Templates Grown via In Situ GaN Nanodot Formation
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Moonsang Lee, Thi Kim Oanh Vu, Kyoung Su Lee, Eun Kyu Kim, and Sungsoo Park
- Subjects
nanodot ,a-plane GaN ,HVPE ,Schottky diodes ,Chemistry ,QD1-999 - Abstract
We investigate the electrical characteristics of Schottky contacts for an Au/hydride vapor phase epitaxy (HVPE) a-plane GaN template grown via in situ GaN nanodot formation. Although the Schottky diodes present excellent rectifying characteristics, their Schottky barrier height and ideality factor are highly dependent upon temperature variation. The relationship between the barrier height, ideality factor, and conventional Richardson plot reveals that the Schottky diodes exhibit an inhomogeneous barrier height, attributed to the interface states between the metal and a-plane GaN film and to point defects within the a-plane GaN layers grown via in situ nanodot formation. Also, we confirm that the current transport mechanism of HVPE a-plane GaN Schottky diodes grown via in situ nanodot formation prefers a thermionic field emission model rather than a thermionic emission (TE) one, implying that Poole–Frenkel emission dominates the conduction mechanism over the entire range of measured temperatures. The deep-level transient spectroscopy (DLTS) results prove the presence of noninteracting point-defect-assisted tunneling, which plays an important role in the transport mechanism. These electrical characteristics indicate that this method possesses a great throughput advantage for various applications, compared with Schottky contact to a-plane GaN grown using other methods. We expect that HVPE a-plane GaN Schottky diodes supported by in situ nanodot formation will open further opportunities for the development of nonpolar GaN-based high-performance devices.
- Published
- 2018
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