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The emerging tribovoltaic nanogenerators (TVNGs) has garnered considerable attention in recent years owing to its higher power density, but it is still limited by unstable output, mismatched impedance, and lower charging speed. Herein, a power‐managed GaN‐based TVNG is first proposed and a self‐powered wireless temperature monitoring system (SWTMS) is developed. The energy backflow from transition capacitor to TVNG is effectively suppressed by applying a high‐voltage‐resistant diode. Benefiting from the combination of the maximum power point tracking (MPPT and the buck converter, an autonomous power management unit (PMU) is designed. The internal impedance of TVNG with PMU decreases by ten times and the charging speed of capacitor increases by 7.18 times compared to those without PMU. Moreover, 100 LEDs and six parallel thermohygrometers can be constantly powered. The wireless temperature monitoring in industrial environments without external power supply is demonstrated through the developed SWTMS. This work proposes an effective power management strategy for TVNG with high output voltage, which exhibits great potential to promote the development of self‐powered sensors and Industrial Internet of Things (IIoT). [ABSTRACT FROM AUTHOR]