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Nature presents the collective behavior of living organisms aiming to accomplish complex tasks, inspiring the development of cooperative micro/nanorobots. Herein, the spontaneous assembly of hematite-based microrobots with different shapes is presented. Autonomous motile light-driven hematite/Pt microrobots with cubic and walnut-like shapes are prepared by hydrothermal synthesis, followed by the deposition of a Pt layer to design Janus structures. Both microrobots show a fuel-free motion ability under light irradiation. Because of the asymmetric orientation of the magnetic dipole moment in the crystal, cubic hematite/Pt microrobots can self-assemble into ordered microchains, contrary to the random aggregation observed for walnut-like microrobots. The microchains exhibit different synchronized motions under light irradiation depending on the mutual orientation of the individual microrobots during the assembly, which allows them to accomplish multiple tasks, including capturing, picking up, and transporting microscale objects, such as yeast cells and suspended matter in water extracted from personal care products, as well as degrading polymeric materials. Such light-powered self-assembled microchains demonstrate an innovative cooperative behavior for small-scale multitasking artificial robotic systems, holding great potential toward cargo capture, transport, and delivery, and wastewater remediation.

Inspired by the increasing desire to mimic the perfection of nature, micro- and nanorobots are triggering increasing interest among the scientific community. The development of such tiny machines that can autonomously perform specific and various tasks at a small scale has reached a high-level of complexity over the last 15 years although the transition from hard to soft self-propelled architectures has had the most profound impact. The use of organic components, such as polymers, is of particular interest to fulfill the lack of biocompatibility and biodegradability of inorganic-based microrobots. Additionally, the combination of self-powered micro- and nanorobots with some macromolecules' ability to be deformed and respond to external stimuli is an important topic. This review aims to critically assess the fundamental aspects of smart machines composed of polymers, examine recent advances in the combined systems at the micro- and nanoscale, and discuss the specific contribution of several polymer families. This review elucidates the role of smart polymers in the expanding field of intelligent micromachines.