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Accelerated weathering of LDPE laminates, with samples exposed to ultraviolet radiation (UVR) in air and while floating in seawater at the same temperature, was investigated in this study. The depth profiles of the concentrations of oxidation products in the two sets of samples was assessed by FTIR (Fourier Transform Infrared Spectroscopy) and suggest the oxidation on weathering to be diffusion-controlled in both air and in seawater, localizing the reaction to a thin surface layer. While the thickness of this layer is several hundred microns in air-weathered samples it is too small to be discernible by FTIR spectroscopy in sea water-weathered samples. A naturally weathered polyethylene microplastic pellet from floating ocean debris was also similarly studied by FTIR and the depth profile compared with that from accelerated weathering of LDPE laminates. Tensile properties of the LDPE weathered in air and in sea water were also compared to better understand the impact of diffusion-controlled oxidation on their mechanical integrity. How the origin of apparent retardation of the rate of weathering degradation of LDPE in seawater relative to that in air, is related diffusion-controlled oxidation due to the low concentrations of dissolved oxygen in seawater, is also discussed., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

This article explains the history, from 1600 BC to 2008, of materials that are today termed ‘plastics’. It includes production volumes and current consumption patterns of five main commodity plastics: polypropylene, polyethylene, polyvinyl chloride, polystyrene and polyethylene terephthalate. The use of additives to modify the properties of these plastics and any associated safety, in use, issues for the resulting polymeric materials are described. A comparison is made with the thermal and barrier properties of other materials to demonstrate the versatility of plastics. Societal benefits for health, safety, energy saving and material conservation are described, and the particular advantages of plastics in society are outlined. Concerns relating to littering and trends in recycling of plastics are also described. Finally, we give predictions for some of the potential applications of plastic over the next 20 years. [ABSTRACT FROM AUTHOR]

Nanocomposites based on low-density polyethylene (LDPE) with MMT clay, nanosilica, and nanoscale zinc oxide (at 5 wt.%) were prepared by melt processing and evaluated for durability using laboratory accelerated weathering. The changes in tensile properties of the nanocomposites with the duration of exposure were compared to data from natural weathering outdoors.The enhancement of degradation rates of the LDPE matrix by the presence of nanofillers in accelerated weathering is reported. [ABSTRACT FROM AUTHOR]