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Solid-state lithium metal batteries (LMBs) have been extensively investigated owing to their safer and higher energy density. In this work, we prepared a novel elastic solid-state polymer electrolyte based on an in situ-formed elastomer polymer matrix with ion-conductive plasticizer crystal embedded with Li6.5La3Zr1.5Ta0.5O12 (LLZTO) nanoparticles, denoted as LZT/SN-SPE. The unique structure of LZT/SN-SPE shows excellent elasticity and flexibility, good electrochemical oxidation tolerance, high ionic conductivity, and high Li+ transference number. The role of LLZTO filler in suppressing the side reactions between succinonitrile (SN) and the lithium metal anode and propelling the Li+ diffusion kinetics can be affirmed. The Li symmetric cells with LZT/SN-SPE cycled stably over 1100 h under a current density of 5 mA cm−2, and Li||LiFePO4 cells realized an excellent rate (92.40 mAh g−1 at 5 C) and long-term cycling performance (98.6% retention after 420 cycles at 1 C). Hence, it can provide a promising strategy for achieving high energy density solid-state LMBs. [ABSTRACT FROM AUTHOR]

The development of high-performance solid-polymer electrolytes (SPEs) is a key to the practical application of lithium metal batteries (LMBs). The use of two-dimensional (2D) inorganic nanofiller is an efficient way to build poly(ethylene oxide) (PEO)-based SPEs with high ionic conductivity and stability. Herein, a series of 2D oxygen vacancy-rich Co3O4-y−x (x = 1, 2 and 3) with well-defined 2D nanostructures, a high surface area and controllable oxygen vacancy contents (Co3O4-y) was synthesized via a facile self-assembly method and NaBH4 reduction. When the 2D Co3O4-y−x (x = 1, 2 and 3) nanosheets are introduced as nanofillers in PEO-based SPEs, they can interact with the PEO to form a three-dimensional (3D) PEO/Co3O4-y film with uniform Li+ distribution and vertical diffusion channels, as well as strong adsorption of NO3− from LiNO3 electrolyte salt at the defective sites. As a result, the PEO/Co3O4-y−2 film reached a high ionic conductivity of 4.9 × 10−5 S cm−1, high Li+ a transference number of 0.51 and a wide electrochemical window over 4.6 V at 80 °C. The PEO/Co3O4-y−2 film enables the Li||PEO/Co3O4-y−2||LiFePO4 cell to deliver a high reversible capacity of 117.7 mAh g−1 at 2 C and to maintain 126.7 mAh g−1 at 1 C after 250 cycles with an initial capacity retention of 87.9%. [ABSTRACT FROM AUTHOR]

Lithium metal batteries (LMBs) have been gotten attention owing to high energy density. In here, the production of PEO-xLiNO 3 solid electrolyte with LiNO 3 as the sole lithium salt is cost-effective, environmentally friendly, and convenient. The interaction of the electrolyte and the electrode can form a uniform and dense solid-electrolyte interphase (SEI) layer packing L 3 iN and LiN x O y groups, which will effectively control lithium deposition and inhibit dendrite growth. The electrolyte exhibits outstanding mechanical properties, remarkable room temperature ionic conductivity, and the ability to suppress lithium dendrite growth. When applied in symmetric Li//Li batteries, the electrolyte shows excellent cycling stability with over 5000 h of cycling at a current density of 0.1 mA cm−2. For NCM622//Li batteries after full charge, it exhibits good cycling stability with a capacity retention rate is as high as 88 % after 300 cycles. Hence, the proposed electrolyte not only enhances safety performance but also improves electrochemical properties, making it highly promising for large-scale practical applications. [ABSTRACT FROM AUTHOR]