Search

Despite incineration is an important emission source of toxic pollutants, such as heavy metals and polychlorinated dibenzo -p- dioxins and dibenzofurans (PCDD/Fs), it is still one of the most widely used methods for the management of municipal solid waste. The current paper summarizes the results of a 20-year follow-up study of the emissions of PCDD/Fs by a municipal solid waste incinerator (MSWI) in Sant Adrià de Besòs (Catalonia, Spain). Samples of ambient air, soils and herbage were periodically collected near the facility and the content of PCDD/Fs was analyzed. In the last (2017) survey, mean levels in soil were 3.60 ng WHO-TEQ/kg (range: 0.40-10.6), being considerably higher than the mean concentrations of PCDD/Fs in soil samples collected near other MSWIs in Catalonia. Moreover, air PCDD/F concentrations were even higher than those found in a previous (2014) survey, as they increased from 0.026 to 0.044 pg WHO-TEQ/m 3 . Ultimately, the PCDD/F exposure would be associated to a cancer risk (2.5 × 10 -6 ) for the population living in the surrounding area. Globally, this information indicates that the MSWI of Sant Adrià de Besòs could have had a negative impact on the environment and potentially on public health, being an example of a possible inappropriate management for years. The application of Best Available Techniques to minimize the emission of PCDD/Fs and other chemicals is critical.

Objective: This study aimed to describe dietary intake and important dietary sources to pollutants as well as to identify maternal socio-economic and lifestyle factors associated with high intake during pregnancy in women residing in a Mediterranean city with heavy industrial activity., Methods: Dietary intake during pregnancy of As, InAs, Cd, MeHg, Pb, PCDD/Fs, DL-PCBs, and NDL-PCBs in 701 pregnant women participating in the longitudinal ECLIPSES study was calculated based on a 45-item food-frequency questionnaire and a database of pollutants in food of the Catalan Food Safety Agency. Details on socio-economic, lifestyle, and anthropometric variables were also collected., Results: The mean dietary intake of pollutants per day and the food group that contributed the most (%) was: 286.51 μg of As (71.27% from white fish), 4.14 μg of InAs (70.16% from cereals-tubers), 6.27 μg of Cd (47.51% from seafood), 5.00 μg of MeHg (52.88% from blue fish), 3.32 μg of Pb (30.15% from cereals-tubers), 9.93 pg of PCDD/Fs (from many food categories), 18.39 pg of DL-PCBs (59.74% from blue fish) and 181.00 ng of NDL-PCBs (44.58% from blue fish). Adjusted multivariate analysis revealed that older age was associated with high As intake, higher educational level was related to low InAs, Cd, and DL-PCBs intake, and alcohol use and smoking were linked with high Pb intake., Conclusion: The dietary intake of pollutants including As and DL-PCBs among pregnant women exceeds or almost reaches the EFSA safety threshold. These findings support the urgent need for local governments to pay special attention to this situation and develop specific prevention strategies for this vulnerable group., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 The Authors. Published by Elsevier Ltd.. All rights reserved.)

Chemical industries and oil refineries are known emission sources of environmental contaminants, such as metals/metalloids, polycyclic aromatic hydrocarbons (PAHs), volatile organic compounds (VOCs) and polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), among others. Based on the toxicological potential of these pollutants, harmful health effects can be expected for the population living near these facilities. One of the largest chemical/petrochemical complexes in Europe is located in Tarragona County (Catalonia, Spain). In the last two decades, a number of investigations aimed at assessing the environmental impact of air pollutants potentially emitted by this industrial complex have been carried out. The present paper is a review of the available scientific information on the levels of air pollutants related with the activities of this chemical/petrochemical complex. Although there are currently some data on the environmental burdens of metals/metalloids, PAHs, VOCs and PCDD/Fs, there is an evident lack of specific biological monitoring studies on human health. Taking into account the amount of chemicals released to air and their toxicity, it is essential to perform an in-depth analysis of the current health status of the population living in Tarragona County., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 The Authors. Published by Elsevier B.V. All rights reserved.)

This paper was aimed at reviewing recent studies related with the impact on environment and human health of metals and PCDD/Fs near cement plants. It has been particularly focused on the impact of cement plants located in Catalonia, Spain, which have been monitored by our research for more than ten years. Environmental monitoring studies were performed under different cement plant conditions. While some of our studies examined temporal trends of the levels of the above indicated pollutants, the main goal of other surveys was to assess the impact of implementing alternative fuels in the facilities. Even one of the studies was performed before and after the cement plant temporally ceased its industrial activity. The impact of cement plants burning alternative fuels on the emissions of metals and PCDD/Fs elsewhere was also reviewed. Regarding the cement plants in Catalonia, no significant differences were found, neither in the long-term follow-up studies, nor when alternative fuels are used, nor when a cement plant temporally stopped its activity. These results are in agreement with those reported for several stack emissions of other cement plants working under different conditions. We conclude that emissions of metals and PCDD/Fs by cement plants working with the best available techniques (BAT), should not cause a significant negative impact neither on the surrounding environment, nor on the human health of the population living in the neighborhood.

In 2009, a cement plant located in Alcanar (South Catalonia, Spain) started co-processing a special kind of refuse-derived fuel (RDF) called ENERFUEL™. In April 2014 and 2017, 5 and 8 years after RDF co-processing, the concentrations of metals and metalloids (As, Cd, Co, Cr, Cu, Hg, Mn, Ni, Pb, Sb, Tl, V and Zn) and PCDD/Fs were measured in samples of soils, herbage and air collected in the vicinity of the facility. The comparison of the current concentrations with those obtained in a baseline study (2008), when fossil fuels were used solely, has shown that the environmental concentrations of metals, metalloids and PCDD/Fs were not significantly modified. The concentrations of metals, metalloids and PCDD/Fs in soil, vegetation and air of Alcanar are in the low part of the ranges found around other cement plants in Catalonia (in general, below 50th percentile). Non-carcinogenic risks due to exposure to metals, metalloids and PCDD/Fs were lower than the safety value (HQ<1). In turn, carcinogenic risks were below the 10 - 5 Spanish threshold. The present results corroborate that, from an environmental point of view, the use of wastes as alternative fuels (AF) in a cement plant, which is operating with suitable technical conditions, is a good option for waste management. It contributes towards overcoming challenges such as climate change and fossil fuel depletion, while utilizing principles of circular economy., (Copyright © 2018 Elsevier Inc. All rights reserved.)

Previously to the modernization of the municipal solid waste incinerator (MSWI) of Campdorà (Girona, Catalonia, Spain) two sampling campaigns (2015 and 2016) were conducted. In each campaign, 8 soil and 4 air samples (PM 10 and total particle phase and gas phase) were collected. The levels of As, Cd, Co, Cr, Cu, Hg, Mn, Ni, Pb, Sb, Sn, Tl and V, and PCDD/Fs were analysed at different distances and wind directions around the MSWI. Environmental levels of trace elements and PCDD/Fs were used to assess exposure and health risks (carcinogenic and non-carcinogenic) for the population living around the facility. In soils, no significant differences were observed for trace elements and PCDD/Fs between both campaigns. In air, significant higher levels of As, Cd, Co, Mn, Ni, Pb, Tl and V were detected in 2016. Regarding soil levels, only Cd (distances) and As, Cu, Mn, and Ni (wind directions) showed significant differences. No differences were noted in the concentrations of trace elements and PCDD/Fs in air levels with respect to distances and directions to the MSWI. No differences were registered in air levels (elements and PCDD/Fs) between points influenced by MSWI emissions and background point. However some differences in congener profile were noted regarding from where back-trajectories come from (HYSPLIT model results), pointing some influence of Barcelona metropolitan area. The concentrations of trace elements and PCDD/Fs were similar -or even lower- than those reported around other MSWIs in Catalonia and various countries. Non-carcinogenic risks were below the safety limit (HQ<1). In turn, carcinogenic risks due to exposure to trace elements and PCDD/Fs were in acceptable ranges, according to national and international standard regulations., (Copyright © 2018 Elsevier B.V. All rights reserved.)

In 2014, we conducted a study aimed at screening the concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), polychlorinated biphenyls (PCBs) and various trace elements in air and soil samples collected in an urban area of Sant Adrià de Besòs (Barcelona, Spain) in the vicinity of an Integrated Waste Management Facility (IWMF). It consists of a mechanical-biological treatment plant (MBT) and an old municipal solid waste incinerator (MSWI). Human health risks for the population living in the area were also assessed. The most worrying result was the high cancer risks estimated for the area (2.5×10 -6 ). In March 2017, we have carried out a new survey to check if the authorities had taken the necessary and urgent measures to reduce the environmental concentrations of PCDD/Fs -and the human health risks- until acceptable levels. Although the concentrations of PCDD/Fs in soils are currently lower (mean value: 1.66 vs. 3.6ng WHO-TEQ/kg in 2014), they are still are notably higher than those found near other MSWIs of Catalonia. In turn, the levels of PCDD/Fs in air are even higher than in 2014 (mean value: 0.044 vs. 0.026pgWHO-TEQ/m 3 in 2014), being also the highest detected in similar zones of Catalonia. The current cancer risk due to PCDD/F exposure for the residents in the neighborhood of the IWMF is 2.3×10 -6 , a worrying fact as the 10 -6 threshold continues to be exceeded., (Copyright © 2017 Elsevier B.V. All rights reserved.)

This study aimed at evaluating the potential impact of a cement plant after 4 years of the employment of alternative fuel. In June 2015, concentrations of PCDD/Fs and metals were determined in soils, vegetation and air in order to measure potential changes with respect to previous surveys before (July 2011) and after (June 2013) the employment of alternative fuel. Risks to human health were also assessed. In soils, metal levels were similar to those observed in June 2013 (p > 0.05). In comparison with July 2011, the increment was only statistically significant for As and Cd (p < 0.05). A notable increase in levels of PCDD/Fs was noted when current levels in soils (1.14 ng WHO-TEQ per kg) were compared with those observed in July 2011 (0.37 ng WHO-TEQ per kg) (p > 0.05) and June 2013 (0.41 ng WHO-TEQ per kg) (p < 0.05). This increase was mainly caused by the increase in PCDD/F levels at one sampling site, which showed the heterogeneity of PCDD/F levels in soils, possibly as a result of different point emissions over the years. On the other hand, temporal trends in levels of metals and PCDD/Fs in vegetation showed a clear decrease, which indicated that the particle fraction of these pollutants would potentially be removed from leaf surfaces by wash-off. In air, levels were similar to those found in previous surveys. The results of PCA showed that the change in fuel had not affected the environmental profiles of metals and PCDD/Fs around the cement plant. The exposure of the population living in the surroundings of the plant was measured and it was shown that diet was the major contributor for both metals and PCDD/Fs, with percentages of over 97%, the only exceptions being As and Pb, for which dietary intake accounted for 43% and 71% of the total exposure, respectively. Environmental non-cancer and cancer risks were within the limits considered as acceptable by international standards.

In May 2016, a fire occurred in one of the largest landfills in Europe (Seseña, Toledo, Spain), where 70,000-90,000tons of tires had been illegally accumulated for >15years. Because of the proximity of population nuclei and the duration of the episode (>20days), we conducted a preliminary human health risk assessment study just after the tire fire. Samples of air and soil were collected in 3 areas surrounding the landfill (El Quiñón, at only 500m, and Seseña Nuevo and Seseña Viejo, both at 4km), as well as in background sites. In addition, samples of crops (barley, wheat, cabbage and lettuce) were also obtained from local farmers. The concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs) and a number of trace elements (As, Cd, Co, Cr, Cu, Hg, Mn, Ni, Pb, Sb, Sn, Tl, and V) were analyzed in all the samples. The concentrations of all the target pollutants, excepting PAHs, were relatively similar at the different sampling zones, irrespective of the distance to the landfill. In turn, a significant increase of PAHs was noted near the tire landfill, with air levels up to 6-times higher than those found at 4km (134 vs. 19.5-22.7ng/m 3 ). Similarly, PAH concentrations in lettuce were relatively higher than those typically found in monitoring programs of food safety. Because of the increase of airborne PAHs, cancer risks due to exposure to environmental pollutants for the population living at El Quiñón, near the landfill, were between 3- and 5-times higher than those estimated for the inhabitants of Seseña. After this preliminary study, further investigations, focused only on PAHs, but more extensive in terms of number of samples, should be conducted to assure that PAHs have been progressively degraded through time., (Copyright © 2016 Elsevier Ltd. All rights reserved.)

The concentrations of PCDD/Fs, PCBs, and metals were determined in soil and air samples collected near a municipal solid waste incinerator (MSWI) located in Mataró (Catalonia, Spain), being the health risks for the population living in the vicinity of the facility subsequently assessed. We also established the temporal trends with respect to previous surveys performed in the same zone. In general terms, the highest environmental levels of the pollutants were found in the city of Mataró and were independent on the distance to the MSWI. Soil levels of metals did not show temporal variations between the current and previous campaigns. However, the concentrations of metals in air samples collected in 2011 and 2013, were lower than those found in our 2008 survey. Regarding PCDD/Fs and PCBs, no differences were noted between the levels of the current survey and those corresponding to 2008. Anyhow, the concentrations of metals, PCDD/Fs, and PCBs in soils and air did not exceed the reference values established by regulatory organizations, being also in the low range of other similar studies recently reported. Finally, the human non-carcinogenic and carcinogenic risks due to exposure to metals, PCDD/Fs, and PCBs, were, for the population living in the neighborhood of the MSWI, considered as acceptable according to international standards., (Copyright © 2015 Elsevier Ltd. All rights reserved.)

The concentrations of As, Cd, Co, Cr, Cu, Hg, Mn, Ni, Pb, Sb, Sn, Tl, V, and Zn, and the levels of polychlorinated dibenzo-p-dioxins and dibenzofurans were determined in samples of soil, vegetation, and air, collected in the vicinity of a cement plant (Catalonia, Spain), before (January 2011 and July 2011) and after (January 2012 and June 2013) alternative fuel partial substitution (fossil fuels by sewage sludge). Seven sampling points were selected at different directions and distances to the facility including two background sampling points. The results were used to assess the health risk assessment for the population living near the facility. Only few significant differences were found before and after alternative fuel partial substitution (Mn in soils and Cd in vegetation). Non-carcinogenic risks were below the safety threshold (HQ<1), while carcinogenic risks were below 10(-5), or exceeding slightly that value, always in the range considered as assumable (10(-6)-10(-4))., (Copyright © 2014 Elsevier B.V. All rights reserved.)

From 2008 to 2009, we evaluated the environmental impact of a cement plant (Montcada i Reixac, Catalonia, Spain) that is located close to densely populated areas. The potential health risks for the population living in the neighborhood were also assessed. The levels of various heavy metals and the concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) were determined in soil, vegetation, and air samples collected at different directions and distances from the facility. Three 6-monthly consecutive campaigns were performed to establish temporal and seasonal trends. Multivariate statistical techniques, such as principal component analysis, were used. Human exposure to metals and PCDD/Fs, as well as the associated carcinogenic and noncarcinogenic risks, were also calculated. Environmental pollutant concentrations, especially those found in urban sites, were noted to be slightly higher than those recently reported around other cement plants in Catalonia. A seasonal pattern was observed, with higher values recorded during the colder sampling periods. Despite this, the carcinogenic and noncarcinogenic risks derived from human exposure to metals and PCDD/Fs were within the ranges considered acceptable by international regulatory organisms.

In April 2009, a cement plant located in Sant Feliu de Llobregat (Catalonia, NE Spain) stopped its normal operations. To establish the environmental impact of the facility and the health risks for the population living in the neighbourhood, the concentrations of a number of metals and polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) were determined in soil, vegetation and air samples in three different surveys, which were carried out before and after the facility stopped the cement production. The influence of the cement plant was found to be low in comparison with other potential emission sources in the area, as no decrease in the immission concentrations was noted after the facility ceased its industrial activity. No significant differences were observed in human health risks derived from the exposure to metals and PCDD/Fs before and after the plant ceased the cement production. Risk values for the population living near the facility were similar to those found for residents living in a number of urban and suburban areas.

The results of an environmental program around the municipal solid waste incinerator (MSWI) of Mataró (Catalonia, Spain), which was designed to assess the potential impact of the facility on the close environment and the health of the population living in the vicinity, are here reported. Metals, polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) and polychlorinated biphenyls (PCBs) were analyzed in soil and air samples collected in/around the facility. In soils, Mn and Zn showed the highest metal concentrations (ranges: 136-648 mg kg(-1) and 29.6-97.8 mg kg(-1), respectively), while total concentrations of PCDD/Fs and PCBs were 0.14-0.46 ng WHO-TEQ kg(-1) and 167-3340 ng kg(-1), respectively. In air, the highest metal levels corresponded to Cu (range: 26.9-52.9 ng m(-3)) and Mn (range: 6.92-19.3 ng m(-3)), while those of PCDD/Fs and PCBs ranged 0.008-0.015 pg WHO-TEQ m(-3) and 9.20-42.1 pg m(-3), respectively. Carcinogenic and non-carcinogenic risks derived of exposure to metals, PCDD/Fs and PCBs did not exceed the threshold values. Complementarily analyzed with the results obtained in the concurrent biomonitoring study and the stack emissions, data indicate that the MSWI of Mataró does not mean significant human health risks derived of emissions of metals, PCDD/Fs and PCBs., (Copyright (c) 2010 Elsevier Ltd. All rights reserved.)

Abstract: Since 2008, sewage sludge is being used as alternative fuel in a cement plant placed in Vallcarca (Catalonia, Spain). To evaluate the temporal trend of the environmental levels of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) and a number of metals (As, Cd, Co, Cr, Cu, Hg, Mn, Ni, Pb, Sn, Tl, V, and Zn), as well as the potentially associated human health risks, samples of soil, herbage, and air were collected around the facility, after approximately one year of the permanent partial substitution of fuel. The temporal evolution of the pollutant levels was assessed by comparing the measured concentrations (2009) with those from samples collected in previous surveys (2003 and 2006) at the same sampling sites. The concentrations of PCDD/Fs in herbage and soil were 0.10 and 1.11ng I-TEQ·kg−1 dw, respectively, values very similar to those found in our previous surveys. For metals, although a clear tendency could not be observed, there were fluctuations through time. In this study, the levels of metals, which had not been analyzed in previous campaigns, were also determined in air, additionally to soil and vegetation. Airborne metal concentrations were similar to those found in other industrial areas worldwide. The human health risks for the population living around the cement plant were comparable to those obtained in previous studies, when petroleum coke was exclusively used as combustible, being in both cases tolerable according to the international standards. [ABSTRACT FROM AUTHOR]

Since 2008, the environmental levels of polychlorinated compounds near a municipal solid waste incinerator in Mataró (Catalonia, Spain) have been periodically monitored. The present study aimed at updating the data regarding the temporal changes occurred between 2015 and 2017, when air and soil samples were collected again, and the concentrations of the same chemical pollutants (i.e., polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), and polychlorinated biphenyls (PCBs)) were analysed. Furthermore, the health risks associated with their human exposure were also evaluated. The levels of all the contaminants in soil were far below the threshold established by regional and national legislations, also being lower than those observed in previous surveys. A similar trend was also noted for PCDD/Fs in air samples, while airborne PCBs were the only group of chemicals whose levels significantly increased. In any case, the global assessment of the data regarding the different pollutants and matrices indicates that there has not been a general increase in the environmental pollution around the facility. In addition, the environmental exposure to PCDD/Fs and PCBs by the population living nearby is still clearly lower than the dietary intake of these same chemical pollutants. [ABSTRACT FROM AUTHOR]