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The development of photonic integrated components for terahertz has become an active and growing research field. Despite its numerous applications, several challenges are still present in hardware design. We demonstrate an on-chip active wavelength division multiplexer (WDM) operating at THz frequencies. The WDM architecture is based on an inverse design topology optimization, which is applied in this case to the active quantum cascade heterostructure material embedded within a polymer in a planarized double metal cavity. Such an approach enables the fabrication of a strongly subwavelength device, with a normalized volume of only $V/\lambda^3 \simeq 0.5$. The WDM input is integrated with a THz quantum cascade laser frequency comb, providing three broadband output ports, ranging from 2.2 THz to 3.2 THz, with $\approx$ 330 GHz bandwidth and a maximum crosstalk of -6 dB. The three ports are outcoupled via integrated broadband patch array antennas with surface emission. Such a device can be also function as a stand-alone element, unlocking complex on-chip signal processing in the THz range

Frequency-modulated (FM) combs are produced by mode-locked lasers in which the electric field has a linearly chirped frequency and nearly constant amplitude. This regime of operation occurs naturally in certain laser systems and constitutes a valuable alternative to generate spectra with equidistant modes. Here, we use a low-noise fs-pulse comb as the local oscillator and combine dual comb heterodyne detection with time domain analysis of the multi-heterodyne signal to reveal the temporal trace of both amplitude and phase quadratures of FM comb lasers' electric field. This technique is applied to both a dense and a harmonic mid-infrared free-running quantum cascade laser frequency comb and shows direct evidence of the FM behavior together with the high degree of coherence of these sources. Our results furnish a deeper insight on the origin of the FM combs and pave the way to further improvement and optimization of these devices., Comment: 6 pages, 5 figures

In this paper, we present a method based on a modal decomposition to quantify the efficiency of photonic lanterns (PL) based free space optical (FSO) communication receivers. We fabricate a seven port PL and we evaluate numerically the free space to fiber coupling efficiency based on a reconstruction of the fields at the PL FSO multimode port. We validate the numerical approach with an experimental characterization of the PL. Then we compare the PL to a commercial multiplane light converter spatial demultiplexer. The PL shows better coupling efficiency for low order spatial modes with orders of magnitude of demultiplexer size reduction. Finally we evaluate the PL receiver with a simulation of received optical wavefront in a FSO communication

Optical injection locking of the repetition frequency of a quantum cascade laser frequency comb is demonstrated using an intensity modulated near-infrared light at 1.55 $\mu$m illuminating the front facet of the laser. Compared to the traditional electrical modulation approach, the introduced technique presents benefits from several perspectives such as the availability of mature and high bandwidth equipment in the near-infrared, circumvent the need of dedicated electronic components for the quantum cascade laser, and allows a direct link between the near and mid-infrared for amplitude to frequency modulation. We show that this stabilization scheme, used with a moderate near-infrared power of 5 mW, allows a tight lock to a radio-frequency generator with less than 1 mrad residual phase noise at 1 s integration time. We also perform a full characterization of the mechanism and evidence that the locking range follows Adler's law. A comparison with our recent characterization of the traditional method indicates that the optical approach could potentially lead to lower phase noise, which would benefit mid-infrared spectroscopy and metrological applications.

Lanthanide nanoparticles (LnNPs) feature sharp emission lines together with millisecond emission lifetimes which makes them promising luminescent probes for biosensing and bioimaging. Although LnNPs are gathering a large interest, their photoluminescence properties at the single nanoparticle level remain largely unexplored. Here, we employ fluorescence correlation spectroscopy (FCS) and photoluminescence burst analysis to investigate the photodynamics of Sm and Eu-based LnNPs with single nanoparticle sensitivity and microsecond resolution. By recording the photoluminescence intensity and the number of contributing LnNPs, we compute the photoluminescence brightness per individual nanoparticle, and estimate the actual number of emitting centers per nanoparticle. Our approach overcomes the challenges associated with ensemble-averaged techniques and provides insights into LnNP photodynamics. Moreover, we demonstrate our microscope capability to detect and analyze LnNPs at the single nanoparticle level, monitoring both photoluminescence brightness and burst duration. These findings expand our understanding of LnNPs and pave the way for their advanced biosensing applications at the single nanoparticle level.

In a laser, the control of its spectral emission depends on the physical dimensions of the optical resonator, limiting it to a set of discrete cavity modes at specific frequencies. Here, we overcome this fundamental limit by demonstrating a monolithic semiconductor laser with a continuously tunable repetition rate from 4 up to 16 GHz, by employing a microwave driving signal that induces a spatiotemporal gain modulation along the entire laser cavity, generating intracavity mode-locked pulses with a continuously tunable group velocity. At the output, frequency combs with continuously tunable mode spacings are generated in the frequency domain, and coherent pulse trains with continuously tunable repetition rates are generated in the time domain. Our results pave the way for fully tunable chip-scale lasers and frequency combs, advantageous for use in a diverse variety of fields, from fundamental studies to applications such as high-resolution and dual-comb spectroscopy., Comment: 9 pages, 5 figures

We present here a real-time analysis of diffraction images acquired at high frame-rate (925 Hz) and its application to macromolecular serial crystallography. The software uses a new signal separation algorithm, able to distinguish the amorphous (or powder diffraction) component from the diffraction signal originating from single crystals. It relies on the ability to work efficiently in azimuthal space and derives from the work performed on pyFAI, the fast azimuthal integration library. Two applications are built upon this separation algorithm: a lossy compression algorithm and a peak-picking algorithm; the performances of both is assessed by comparing data quality after reduction with XDS and CrystFEL., Comment: 43 pages, 12 figures

We demonstrate a quantum walk comb in synthetic frequency space formed by externally modulating a semiconductor optical amplifier operating in the telecommunication wavelength range in a unidirectional ring cavity. The ultrafast gain saturation dynamics of the gain medium and its operation at high current injections is responsible for the stabilization of the comb in a broad frequency modulated state. Our device produces a nearly flat broadband comb with a tunable repetition frequency reaching a bandwidth of 1.8THz at the fundamental repetition rate of 1GHz while remaining fully locked to the RF drive. Comb operation at harmonics of the repetition rate up to 14.1GHz is also demonstrated. This approach paves the way for next-generation optical frequency comb devices with potential applications in precision ranging and high-speed communications.

The need of atmospheric information with a higher spatial and temporal resolution drives the development of small satellites and satellite constellations to complement satellite flagship missions. Since optical systems are a main contributor to the satellite size, these are the prime candidate for their miniaturization. We present here a novel optical system where the complete spectrometer part of the optical system is compressed in one flat optical element. The element consists of an array of photonic crystals which is directly placed on a detector. The photonic crystals act as optical filters with a tunable spectral transmission response. From the integrated optical signals per filter and the atmosphere model, greenhouse gas concentrations are obtained using computational inversion. We present in this article the instrument concept, the manufacturing and measurement of the photonic crystals, methods for the filter array optimization, and discuss the predicted retrieval performance for the detection of methane and carbon dioxide., Comment: ICSO 2024

Laser-Wakefield Accelerators (LWFA) running at kHz repetition rates hold great potential for applications. They typically operate with low-energy, highly compressed laser pulses focused in high-pressure gas targets. Experiments have shown that the best-quality electron beams are achieved using Hydrogen gas targets. However, continuous operation with Hydrogen requires a dedicated pumping system. This work presents the design of a differential pumping system, enabling, for the first time, continuous operation of our kHz LWFA using a high-pressure Hydrogen gas jet. The system successfully maintained a pressure below 3e-4 mbar, even with a free-flowing gas jet operating at 140 bar backing pressure. Numerical fluid dynamics and optical simulations were used to guide and validate the system's design., Comment: 10 pages, 9 figures

We miniaturize a vertically-coupled in-plane whispering gallery mode cavity incorporating a quantum cascade gain medium, aiming to realize the mid-infrared counterpart to the vertical cavity surface emitting laser (VCSEL). Building on previous work with linear microcavities, we introduce a new type of quantum cascade surface emitting laser (QCSEL) by miniaturizing a buried heterostructure ring cavity. At wavelengths of 4.5 ${\mu}$m and 8 ${\mu}$m, we investigate the optical losses for decreasing ring diameters while benchmarking the device performance against linear microcavities. We achieve an equivalent mirror reflectivity of 0.95 and demonstrate lasing with ring diameters as small as 50 ${\mu}$m. Finally, we report a continuous-wave threshold power dissipation of 274mW for a 100 ${\mu}$m diameter ring QCSEL, characterized on wafer level at 20 ${^\circ}$C.

Interband Cascade Lasers (ICLs) are semiconductor lasers emitting in the mid-wave infrared (MWIR 3-6 {\mu}m) and can operate as frequency combs (FCs). These demonstrations are based on double section cavities that can reduce dispersion and/or are adapted for radio-frequency operation. Here we show that ICLs FCs at long wavelengths, where the refractive index dispersion reduces, can be realized in a single long section cavity. We show FC generation for ICLs operating at {\lambda} ~ 4.2 {\mu}m, demonstrating narrow electrical beatnotes over a large current range. We also reconstruct the ultrafast temporal response through a modified SWIFT spectroscopy setup with two fast MWIR detectors, which shows a frequency modulated response in free-running operation. Further, we show that, through active modelocking, the ICL can be forced to generate short pulses on the order of 3 ps. This temporal response is in agreement with Maxwell Bloch simulations, highlighting that these devices possess long dynamics (~100ps) and potentially makes them appropriate for the generation of large peak powers in the MWIR., Comment: 11 pages, 6 figures

A new generation of gravitational wave detectors is currently being designed with the likely use of a different laser wavelength compared to current instruments. The estimation of the optical losses for this new wavelength is particularly relevant to derive the detector sensitivity and also to anticipate the optical performances of future instruments. In this article, we measured the absorption and angle-resolved scattering of several mirror samples in order to compare optical losses at a wavelength of 1064 and 1550\ nm. In addition, we have carried out simulations of the Einstein Telescope arm cavities at 1064 and 1550\ nm taking into account losses due to surface low-spatial frequency flatness. Our results suggest that optical losses as measured at 1064\ nm are about twice as large as those at 1550\ nm as predicted with a simple model., Comment: 12 pages, 3 figures

The intensity noise of a laser source represents one of the key factors limiting the ultimate sensitivity in laser-based systems for sensing and telecommunication. For advanced applications based on interferometry, the availability of a shot-noise-limited local oscillator is even more important for the effective feasibility of high-precision measurements. This is particularly crucial in quantum optics applications based on homodyne detection schemes to measure non-classical light states, such as squeezed states. This work deeply investigates and analyzes the intensity noise features of the most widely used mid-infrared semiconductor heterostructured lasers: quantum cascade and interband cascade lasers. For this purpose, a comprehensive comparison of three different continuous-wave lasers operating at room temperature around 4.5 {\mu}m wavelength is presented. First, a thorough electro-optical characterization is given, highlighting the differences and the shared common characteristics of the tested devices. Then, a detailed intensity noise analysis is reported, identifying their different noise operations with a particular reference to shot-noise-limited operations. Finally, some perspectives towards advanced applications are discussed., Comment: 17 pages, 5 figures

Laser spectroscopy and interferometry have provided an unparalleled view into the fundamental nature of matter and the universe through ultra-precise measurements of atomic transition frequencies and gravitational waves. Optical frequency combs have expanded metrology capabilities by phase-coherently bridging radio frequency and optical domains to enable traceable high-resolution spectroscopy across bandwidths greater than hundreds of terahertz. However, quantum mechanics limits the measurement precision achievable with laser frequency combs and traditional laser sources, ultimately impacting fundamental interferometry and spectroscopy. Squeezing the distribution of quantum noise to enhance measurement precision of either the amplitude or phase quadrature of an optical field leads to significant measurement improvements with continuous wave lasers. In this work, we generate bright amplitude-squeezed frequency comb light and apply it to molecular spectroscopy using interferometry that leverages the high-speed and broad spectral coverage of the dual-comb technique. Using the Kerr effect in nonlinear optical fiber, the amplitude quadrature of a frequency comb centered at 1560 nm is squeezed by >3 dB over a 2.5 THz of bandwidth that includes 2500 comb teeth spaced by 1 GHz. Interferometry with a second coherent state frequency comb yields mode-resolved spectroscopy of hydrogen sulfide gas with a signal-to-noise ratio (SNR) nearly 3 dB beyond the shot noise limit, taking full metrological advantage of the amplitude squeezing when the electrical noise floor is considered. The quantum noise reduction leads to a two-fold quantum speedup in the determination of gas concentration, with impact for fast, broadband, and high SNR ratio measurements of multiple species in dynamic chemical environments., Comment: 31 pages, 12 figures

We present significant advances in Laser Wakefield Acceleration (LWFA) operating at a 1 kHz repetition rate, employing a sub-TW, few-femtosecond laser and a continuously flowing hydrogen gas target. We conducted the first comprehensive study assessing how the nature of the gas within the target influences accelerator performance. This work confirms and elucidates the superior performance of hydrogen in kHz LWFA. Our system generates quasi-monoenergetic electron bunches with energies up to 10 MeV, bunch charges of 2 pC, and angular divergences of 15 mrad. Notably, our novel scheme relying on differential pumping enables continuous operation at kHz repetition rates, contrasting with previous systems that operated in burst mode to achieve similar beam properties. Particle-in-cell simulations explain hydrogen's superior performances: the ionization effects in nitrogen and helium distort the laser pulse, negatively impacting accelerator performance. These effects are strongly mitigated in hydrogen plasma, thereby enhancing beam quality. This analysis represents a significant step forward in optimizing and understanding kHz LWFA. It underscores the critical role of hydrogen and the imperative need to develop hydrogen-compatible target systems capable of managing high repetition rates, as exemplified by our differential pumping system. These advances lay the groundwork for further developments in high-repetition-rate LWFA technology., Comment: 11 pages, 7 figures

Photonic emulators have facilitated the investigation of numerous solid-state phenomena and have contributed to the development of optical devices inspired by quantum mechanics. Although current photonic emulators are constrained to bosonic behavior with local interactions, the utilization of active synthetic lattices holds promise for surpassing these limitations. In this study, we propose employing the modulated ring fast-gain laser as a foundation for emulating quench dynamics within a synthetic lattice that conforms to equal density filling of its reciprocal space. To illustrate the effectiveness of this emulation platform, we subject a dispersed Wannier-Stark ladder to quenching and directly observe oscillations, enabled by the fast-gain, along with their coherent stabilization to a single Wannier stark state. These coherent dynamics stem directly from our lasers liquid state of light, a characteristic resulting from fast-gain and explained by the rapid decay of fluctuations occurring on the system's shortest timescale. Additionally, by adequately biasing the lattice through detuning the modulation from the cavity resonance, this process supports oscillatory dynamics within the synthetic space.

Development of small pixels for high resolution image sensors implies a lot of challenges. A high level of performance should be guaranteed whereas the overall size must be reduced and so the degree of freedom in design and process. One key parameter of this constant improvement is the knowledge and the control of the crosstalk between pixels. In this paper, we present an advance in crosstalk characterization method based on the design of specific color patterns and the measurement of quantum efficiency. In a first part, we describe the color patterns designed to isolate one pixel or to simulate un-patterned colored pixels. These patterns have been implemented on test-chip and characterized. The second part deals with the characterization setup for quantum efficiency. Indeed, the use of spectral measurements allows us to discriminate pixels based on the color filter placed on top of them and to probe the crosstalk as a function of the depth in silicon, thanks to the photon absorption length variation with the wavelength. In the last part, results are presented showing the impact of color filters patterning, i.e. pixels in a Bayer pattern versus un-patterned pixels. The crosstalk directions and amplitudes are also analyzed in relation to pixel layout.

In this paper we present two design generations of metasurface-based planar microlenses implemented on Front-Side Illumination SPAD pixels. This kind of microlens is an alternative to conventional reflow microlens. It offers more degrees of freedom in term of design, especially the capability to design off-axis microlens to gather light around the SPAD photodiode. The two generations of microlenses have been fabricated on STMicroelectronics SPAD and characterized. We validated the sensitivity improvement offered by extended metasurface-based microlens. We also confirmed the impact of lithography capability on metasurface performances, highlighting the

Cavity electrodynamics is emerging as a promising tool to control chemical processes and quantum material properties. In this work we develop a formalism to describe the cavity mediated energy exchange between a material and its electromagnetic environment. We show that coplanar cavities can significantly affect the heat load on the sample if the cavity resonance lies within the frequency region where free-space radiative heat dominates, typically the mid-IR at ambient temperature, while spectral filtering is necessary for having an effect with lower frequency cavities.

Efficient drug delivery is a major challenge in modern medicine and pharmaceutical research. Micrometer-scale robots have recently been proposed as a promising venue to amplify precision of drug administration. Remotely controlled microrobots sufficiently small to navigate through microvascular networks can reach any part of the human body, yet real-time tracking is crucial for providing precise guidance and verifying successful arrival at the target. In vivo deep-tissue monitoring of individual microrobots is currently hampered by the lack of sensitivity and/or spatio-temporal resolution of commonly used clinical imaging modalities. We synthesized biocompatible and biodegradable copper phosphate micro-flowers loaded with indocyanine green and iron oxide nanoparticles to enable in vivo individual detection with localization optoacoustic tomography. We demonstrate magnetic actuation and optoacoustic tracking of these decorated micro-flowers at a per-particle level. Functional super-resolution imaging achieved via tracking intravenously injected particles provides a means of identifying microvascular targets and quantifying blood flow, while the versatile carrying capacity can be further exploited for transporting multiple types of drug formulations.

The scattering of waves in a complex medium is perturbed by polarizability changes or motion of embedded targets. These perturbations could serve as perfectly non-invasive guidestars for focusing on the targets. In this Letter, we theoretically derive a fundamental difference between these two perturbation types (the change of the scattering matrix is of rank one [two] for target polarizability changes [motion]) and identify accordingly optimal strategies to perfectly focus on the target in both cases. For target motion, at least two displacements are necessary. Furthermore, for the case of dynamic complex media additionally featuring parasitic perturbers, we establish a non-invasive scheme to achieve optimal time-averaged power delivery to a perturbation-inducing target. In all cases, no assumptions about the unitarity of the system's scattering matrix or the size of the perturbation are necessary. We experimentally demonstrate all results in the microwave regime using a strongly sub-unitary lossy chaotic cavity as complex medium. Our experiments highlight that the target's "structural scattering" is irrelevant [must be negligible] in the case of target polarizability changes [motion]. We expect our results to find applications in communications, cybersecurity, bioelectronics, flow-cytometry and self-propelled nano-swimmers., Comment: 6 pages including 4 figures + 12 pages Supplemental Material

Gold nanoclusters (AuNCs) have captured significant interest for their photoluminescent properties; however, their rapid photodynamics remain elusive while probed by ensemble-averaging spectroscopy techniques. To address this challenge, we use fluorescence correlation spectroscopy (FCS) to uncover the photoluminescence dynamics of colloidal Au18(SG)14 nanoclusters. Our FCS analysis reveals the photoluminescence (PL) brightness per nanocluster, elucidating the impact of photoexcitation saturation and ligand interactions. Unlike DNA-encapsulated silver nanoclusters, the gold counterparts notably exhibit minimal blinking, with moderate amplitudes and 0.2 ms characteristic times. Our data also clearly reveal the occurrence of photon antibunching in the PL emission, showcasing the quantum nature of the PL process, with each AuNC acting as an individual quantum source. Using zero-mode waveguide nanoapertures, we achieve a 16-fold enhancement of the PL brightness of individual AuNCs. This constitutes an important enabling proof-of-concept for tailoring emission properties through nanophotonics. Overall, our study bridges the gap between ensemble-averaged techniques and single-molecule spectroscopy, offering new insights into AuNC photodynamics for biosensing and imaging applications.

Improving the resolution of fluorescence microscopy beyond the diffraction limit can be achievedby acquiring and processing multiple images of the sample under different illumination conditions.One of the simplest techniques, Random Illumination Microscopy (RIM), forms the super-resolvedimage from the variance of images obtained with random speckled illuminations. However, thevalidity of this process has not been fully theorized. In this work, we characterize mathematicallythe sample information contained in the variance of diffraction-limited speckled images as a functionof the statistical properties of the illuminations. We show that an unambiguous two-fold resolutiongain is obtained when the speckle correlation length coincides with the width of the observationpoint spread function. Last, we analyze the difference between the variance-based techniques usingrandom speckled illuminations (as in RIM) and those obtained using random fluorophore activation(as in Super-resolution Optical Fluctuation Imaging, SOFI).

In this work, we demonstrate that in a regime of strong modulation, by generating pulses of the length of the order of a few cavity lifetimes (hundreds of ps), a broadband quantum cascade laser can be driven to lase on a bandwidth (250cm-1) limited by the gain. In addition, the amplitude noise of the radiation was shown to be limited by the detector. A laser linewidth study has been performed under different operating conditions finding values spanning from 20MHz to 800MHz, indicating a trade-off between emission bandwidth, amplitude stability and coherence.

Frequency combs are powerful tools for many applications and high performances are achieved by stabilizing these lasers. For operation in the mid-infrared, quantum cascade lasers (QCL) are ideal candidates as they present numerous advantages. However, stabilized QCL-combs lack of a detailed characterization of their noise properties due to the sensitivity limits of current analyzing techniques. To overcome these challenges, we developed what we believe to be the first tightly locked dual QCL-comb system. Its use is twofold. First, phase noise analysis of the dual-comb signal shows residual phase noise below 600 mrad for all comb lines, and we characterize the comb coherence as well as the performances of the repetition frequency locking mechanism. Second, we demonstrate coherent averaging with a $7 \times 10^5$ Hz$^{1/2}$ figure-of-merit system, which is compatible with high precision spectroscopy.

This paper presents a new FDTD-based optical simulation model dedicated to describe the optical performances of CMOS image sensors taking into account diffraction effects. Following market trend and industrialization constraints, CMOS image sensors must be easily embedded into even smaller packages, which are now equipped with auto-focus and short-term coming zoom system. Due to miniaturization, the ray-tracing models used to evaluate pixels optical performances are not accurate anymore to describe the light propagation inside the sensor, because of diffraction effects. Thus we adopt a more fundamental description to take into account these diffraction effects: we chose to use Maxwell-Boltzmann based modeling to compute the propagation of light, and to use a software with an FDTD-based (Finite Difference Time Domain) engine to solve this propagation. We present in this article the complete methodology of this modeling: on one hand incoherent plane waves are propagated to approximate a product-use diffuse-like source, on the other hand we use periodic conditions to limit the size of the simulated model and both memory and computation time. After having presented the correlation of the model with measurements we will illustrate its use in the case of the optimization of a 1.75$\mu$m pixel.

In this paper, we present the results of rigorous electromagnetic broadband simulations applied to CMOS image sensors as well as experimental measurements. We firstly compare the results of 1D, 2D, and 3D broadband simulations in the visible range (380nm-720nm) of a 1.75$\mu$m CMOS image sensor, emphasizing the limitations of 1D and 2D simulations and the need of 3D modeling, particularly to rigorously simulate parameters like Quantum Efficiency. Then we illustrate broadband simulations by two proposed solutions that improve the spectral response of the sensor: an antireflective coating, and the reduction of the optical stack. We finally show that results from experimental measurements are in agreement with the simulated results.

Frequency-modulated (FM) combs form spontaneously in free-running semiconductor lasers and possess a vast potential for spectroscopic applications. Despite recent progress in obtaining a conclusive theoretical description, experimental FM combs often exhibit non-ideal traits, which prevents their widespread use. Here we explain this by providing a clear theoretical and experimental study of the impact of the higher-order dispersion on FM combs. We reveal that spectrally-dependent dispersion is detrimental for comb performance and leads to a decreased comb bandwidth and the appearance of spectral holes. These undesirable traits can be mended by applying a radio-frequency modulation of the laser bias. We show that electrical injection-locking of the laser leads to a significant increase of the comb bandwidth, a uniform-like spectral amplitudes, and the rectification of the instantaneous frequency to recover a nearly linear frequency chirp of FM combs.

Nanoantennas capable of large fluorescence enhancement with minimal absorption are crucial for future optical technologies from single-photon sources to biosensing. Efficient dielectric nanoantennas have been designed, however, evaluating their performance at the individual emitter level is challenging due to the complexity of combining high-resolution nanofabrication, spectroscopy and nanoscale positioning of the emitter. Here, we study the fluorescence enhancement in infinity-shaped gallium phosphide (GaP) nanoantennas based on a topologically optimized design. Using fluorescence correlation spectroscopy (FCS), we probe the nanoantennas enhancement factor and observed an average of 63-fold fluorescence brightness enhancement with a maximum of 93-fold for dye molecules in nanogaps between 20 nm and 50 nm. The experimentally determined fluorescence enhancement of the nanoantennas was confirmed by numerical simulations of the local density of optical states (LDOS). Furthermore, we show that beyond design optimisation of dielectric nanoantennas, increased performances can be achieved via tailoring of nanoantenna fabrication., Comment: 21 pages, 5 figures

A precise model library based on an equivalent circuit is presented and discussed. The model fully describes the light and bias behaviours of organic photodiodes realized on plastic substrates. The sub circuit modelling consists of a single SPICE LEVEL1 diode, a light power dependent series resistance, a shunt resistance. A combined light-power and voltage-controlled current source is also used to emulate the sensitivity behaviour of the photodiode. Moreover the model also permits designers to follow the technology deviations through the inclusion of worst-case corners. Finally a statistical model is included in order to allow designers run Monte Carlo simulations.

In recent years, electro-optic sampling, which is based on Pockel's effect between an electromagnetic mode and a copropagating, phase-matched ultrashort probe, has been largely used for the investigation of broadband quantum states of light, especially in the mid-infrared and terahertz frequency range. The use of two mutually delayed femtosecond pulses at near-infrared frequencies allows the measurement of quantum electromagnetic radiation in different space-time points. Their correlation allows therefore direct access to the spectral content of a broadband quantum state at terahertz frequencies after Fourier transformation. In this work, we will prove experimentally and theoretically that when using strongly focused coherent ultrashort probes, the electro-optic sampling technique can be affected by the presence of a third-order nonlinear mixing of the probes' electric field at near-infrared frequencies. Moreover, we will show that these third-order nonlinear phenomena can also influence correlation measurements of the quantum electromagnetic radiation. We will prove that the four-wave mixing of the coherent probes' electric field with their own electromagnetic vacuum at near-infrared frequencies results in the generation of a higher-order nonlinear correlation term. The latter will be characterized experimentally, proving its local nature requiring the physical overlap of the two probes. The parameters regime where higher order nonlinear correlation results predominant with respect to electro-optic correlation of terahertz radiation is provided.

Multispectral Optoacoustic Tomography (MSOT) uniquely enables spatial mapping in high resolution of oxygen saturation (SO$_2$), with potential applications in studying pathological complications and therapy efficacy. MSOT offers seamless integration with ultrasonography, by using a common ultrasound detector array. However, MSOT relies on multiple successive acquisitions of optoacoustic (OA) images at different optical wavelengths and the low frame rate of OA imaging makes the MSOT acquisition sensitive to body/respiratory motion. Moreover, estimation of SO$_2$ is highly sensitive to noise, and artefacts related to the respiratory motion of the animal were identified as the primary source of noise in MSOT.In this work, we propose a two-step image processing method for SO$_2$ estimation in deep tissues. First, to mitigate motion artefacts, we propose a method of selection of OA images acquired only during the respiratory pause of the animal, using ultrafast ultrasound images (USIs) acquired immediately after each OA acquisition (USI acquisition duration of 1.4 ms and a total delay of 7 ms). We show that gating is more effective using USIs than OA images at different optical wavelengths. Secondly, we propose a novel method which can estimate directly the SO$_2$ value of a pixel and at the same time evaluate the amount of noise present in that pixel. Hence, the method can efficiently eliminate the pixels dominated by noise from the final SO$_2$ map. Our post-processing method is shown to outperform conventional methods for SO$_2$ estimation, and the method was validated by in vivo oxygen challenge experiments.

Plasmonic optical nanoantennas offer compelling solutions for enhancing light-matter interactions at the nanoscale. However, until now, their focus has been mainly limited to the visible and near-infrared regions, overlooking the immense potential of the ultraviolet (UV) range, where molecules exhibit their strongest absorption. Here, we present the realization of UV resonant nanogap antennas constructed from paired rhodium nanocubes. Rhodium emerges as a robust alternative to aluminum, offering enhanced stability in wet environments and ensuring reliable performance in the UV range. Our results showcase the nanoantenna ability to enhance the UV autofluorescence of label-free streptavidin and hemoglobin proteins. We achieve significant enhancements of the autofluorescence brightness per protein by up to 120-fold, and reach zeptoliter detection volumes enabling UV autofluorescence correlation spectroscopy (UV-FCS) at high concentrations of several tens of micromolar. We investigate the modulation of fluorescence photokinetic rates and report excellent agreement between experimental results and numerical simulations. This work expands the applicability of plasmonic nanoantennas into the deep UV range, unlocking the investigation of label-free proteins at physiological concentrations.

Synthetic lattices in photonics enable the exploration of light states in new dimensions, transcending phenomena common only to physical space. We propose and demonstrate a Quantum Walk Laser in synthetic frequency space formed by externally modulating a ring-shaped semiconductor laser with ultrafast recovery times. In this device, the initially ballistic quantum walk does not dissipate into low supermode states of the synthetic lattice; instead, thanks to the fast-gain nonlinearity of our quantum cascade laser active material, the state stabilizes in a broad frequency comb, unlocking the full potential of the lattice. This device produces a low-noise, nearly-flat broadband comb (reaching 100 cm$^{-1}$ bandwidth), well predicted by our models. The proposed Quantum Walk Laser offers a promising platform to generate broadband, tunable and stable frequency combs., Comment: This is the author's version of the work. The definitive version was published in Science on 2023/10/27, 10.1126/science.adj3858 (10 pages, 4 figures)

A low-cost single frequency laser emitting in the mid-infrared spectral region and dissipating minimal electrical power is a key ingredient for the next generation of portable gas sensors for high-volume applications involving chemical sensing of important greenhouse and pollutant gases. We propose here a Quantum Cascade Surface Emitting Laser (QCSEL), which we implement as a short linear cavity with high reflectivity coated end-mirrors to suppress any edge emission and use a buried semiconductor diffraction grating to extract the light from the surface. By wafer-level testing we investigate the cavity length scaling, extract mirror reflectivities larger than 0.9, and achieve a pulsed threshold power dissipation of 237 mW for an emission wavelength near 7.5 $\mu$m. Finally, we demonstrate single mode emission with a side-mode suppression ratio larger than 33 dB of a 248 $\mu$m short cavity mounted with the epitaxial layer up and operated in continuous wave at 20 $^\circ$C.

We demonstrate terahertz chiral metamaterial cavities that break time-reversal symmetry by coupling the degenerate linearly polarized modes of two orthogonal sets of nano-antenna arrays using the inter-Landau level transition of a two-dimensional electron gas in a perpendicular magnetic field, realizing normalized light-matter coupling rates up to $\Omega_R/\omega_{\mathrm{cav}} = 0.78$. The deep sub-wavelength confinement and gap of the nano-antennas means that the ultra-strong coupling regime can be reached even with a very small number of carriers, making it viable to be used with a variety of 2D materials, including graphene. In addition it possesses a non-degenerate chiral ground state that can be used to study the effect of circularly polarized electromagnetic quantum fluctuations by means of weakly-perturbing magneto-transport measurements., Comment: 17 pages, 8 figures

We present a novel and straightforward approach for the spatio-spectral characterization of ultrashort pulses. This minimally intrusive method relies on placing a mask with specially arranged pinholes in the beam path before the focusing optic and retrieving the spectrally-resolved laser wavefront from the speckle pattern produced at focus. We test the efficacy of this new method by accurately retrieving chromatic aberrations, such as pulse front tilt, pulse front curvature, and higher-order aberrations introduced by a spherical lens. The simplicity and scalability of this method, combined with its compatibility with single-shot operation, make it a promising candidate to become a new standard diagnostic tool in high-intensity laser facilities., Comment: Algorithm updated: near-field intensity measurement no longer needed. Revised version extracts phase and amplitude at pinhole positions. Wavefronts nearly unchanged. Paper adjusted, typos corrected, and cosmetic figure changes made

The reconfigurability of radio environments with programmable metasurfaces is considered a key feature of next-generation wireless networks. Identifying suitable metasurface configurations for desired wireless functionalities requires a precise setting-specific understanding of the intricate impact of the metasurface configuration on the wireless channels. Yet, to date, the relevant short and long-range correlations between the meta-atoms due to proximity and reverberation are largely ignored rather than precisely captured. Here, we experimentally demonstrate that a compact model derived from first physical principles can precisely predict how wireless channels in complex scattering environments depend on the programmable-metasurface configuration. The model is calibrated using a very small random subset of all possible metasurface configurations and without knowing the setup's geometry. Our approach achieves two orders of magnitude higher precision than a deep learning-based digital-twin benchmark while involving hundred times fewer parameters. Strikingly, when only phaseless calibration data is available, our model can nonetheless retrieve the precise phase relations of the scattering matrix as well as their dependencies on the metasurface configuration. Thereby, we achieve coherent wave control (focusing or enhancing absorption) and phase-shift-keying backscatter communications without ever having measured phase information. Finally, our model is also capable of retrieving the essential properties of scattering coefficients for which no calibration data was ever provided. These unique generalization capabilities of our pure-physics model significantly alleviate the measurement complexity. Our approach is also directly relevant to dynamic metasurface antennas, microwave-based signal processors as well as emerging in situ reconfigurable nanophotonic, optical and room-acoustical systems., Comment: 23 pages, 4 figures, 4 supplementary figures

Diffusing wave spectroscopy (DWS) is a group of techniques used to measure the dynamics of a scattering medium in a non-invasive manner. DWS methods rely on detecting the speckle light field from the moving scattering media and measuring the speckle decorrelation time to quantify the scattering mediums dynamics. For DWS, the signal-to-noise (SNR) is determined by the ratio between measured decorrelation time to the standard error of the measurement. This SNR is often low in certain applications because of high noise variances and low signal intensity, especially in biological applications with restricted exposure and emission levels. To address this photon-limited signal-to-noise ratio problem, we investigated, theoretically and experimentally, the SNR of an interferometric speckle visibility spectroscopy (iSVS) compared to more traditional DWS methods. We found that iSVS can provide excellent SNR performance through its ability to overcome camera noise. We also proved iSVS system has more relaxed constraints on the reference beam properties than most other interferometric systems. For an iSVS to function properly, we simply require the reference beam to exhibit local temporal stability, while incident angle, reference phase, and intensity uniformity do not need to be constrained. This flexibility can potentially enable more unconventional iSVS implementation schemes., Comment: 14 pages, 5 figures

We formulate a multi-physics model to describe the nonlinear propagation of a femtosecond, near-infrared, tightly focused laser pulse in a transparent dielectric. The application of our model to the case of bulk sapphire shows that even under extreme excitation conditions, ionization is universally clamped at about one tenth of the electron density in the upper valence band. The earlier estimate of ~10 TPa pressure that could be attainable through the internal excitation of transparent dielectrics by tightly focused ultrafast laser beams is shown to be off by two orders of magnitude.

THz quantum cascade lasers (QCLs) based on double metal waveguides feature broadband and high-temperature devices for use in spectroscopy and sensing. However, their extreme field confinement produces poor output coupling efficiencies and divergent far-fields. Here, we present a planarized THz QCL with an inverse-designed end facet reflector coupled to a surface-emitting patch array antenna. All the components have been optimized for octave-spanning spectral bandwidths between 2-4 THz and monolithically integrated on the same photonic chip. We demonstrate this experimentally on broadband THz QCL frequency combs, with measured devices showing a seven-fold improvement in slope efficiency compared to devices with a cleaved facet. They feature peak powers of up to 13.5 mW with surface emission into a narrow beam with a divergence of (17.0{\deg}x 18.5{\deg}), while broadband fundamental and harmonic comb states spanning up to 800 GHz are observed., Comment: 6 pages, 5 figures

Mid-infrared semiconductor lasers in photonic integrated circuits are of considerable interest for a variety of industrial, environmental, and medical applications. However, photonic integration technologies in the mid-infrared lag far behind the near-infrared range. Here we present the monolithic integration of mid-infrared quantum cascade lasers with low-loss passive waveguides via butt-coupling. The passive waveguide losses are experimentally evaluated to be only 1.2 +- 0.3 dB/cm, with negligible butt-coupling losses. We demonstrate continuous-wave lasing at room temperature of these active-to-passive waveguide coupled devices. Moreover, we report a frequency comb operation paving the way toward on-chip, mid-infrared, dual-comb sensors.

We performed spin-, time- and angle-resolved extreme ultraviolet photoemission spectroscopy (STARPES) of excitons prepared by photoexcitation of inversion-symmetric 2H-WSe$_2$ with circularly polarized light. The very short probing depth of XUV photoemission permits selective measurement of photoelectrons originating from the top-most WSe$_2$ layer, allowing for direct measurement of hidden spin polarization of bright and momentum-forbidden dark excitons. Our results reveal efficient chiroptical control of bright excitons' hidden spin polarization. Following optical photoexcitation, intervalley scattering between nonequivalent K-K' valleys leads to a decay of bright excitons' hidden spin polarization. Conversely, the ultrafast formation of momentum-forbidden dark excitons acts as a local spin polarization reservoir, which could be used for spin injection in van der Waals heterostructures involving multilayer transition metal dichalcogenides.

Plasma ignition is critical in various scientific and industrial applications, demanding an efficient and robust execution mechanism. In this work, we present an innovative approach to plasma ignition by incorporating the analysis of fundamental aspects of light scattering in the complex frequency plane. For the first time, we demonstrate the high-power virtual perfect absorption (VPA) regime, a groundbreaking method for perfectly capturing light within a resonator. By carefully designing the temporal profile of the incident wave, we effectively minimize reflections during the ignition stages, thereby significantly enhancing the efficiency and resilience of the process. Through comprehensive experimental investigations, we validate the viability of this approach, establishing VPA as a powerful tool for reflectionless excitation and optimal control of plasma discharge. By addressing the limitations of conventional plasma ignition methods, this research represents a pivotal step towards transformative advancements in plasma technology, with promising implications for improving the performance and sustainability of numerous applications.

We demonstrate the use of a low power near-infrared laser illuminating the front facet of a quantum cascade laser (QCL) as an optical actuator for the coherent control of a mid-infrared frequency comb. We show that by appropriate current control of the QCL comb and intensity modulation of the near-infrared laser, a tight phase lock of a comb line to a distributed feedback laser is possible with 2 MHz of locking bandwidth and 200 mrad of residual phase noise. A characterization of the whole scheme is provided showing the limits of the electrical actuation which we bypassed using the optical actuation. Both comb degrees of freedom can be locked by performing electrical injection locking of the repetition rate in parallel. However, we show that the QCL acts as a fast near-infrared light detector such that injection locking can also be achieved through modulation of the near-infrared light. These results on the coherent control of a quantum cascade laser frequency comb are particularly interesting for coherent averaging in dual-comb spectroscopy and for mid-infrared frequency comb applications requiring high spectral purity., Comment: 9 pages, 6 figures; edited author list

Frequency-modulated (FM) combs feature flat intensity spectra with a linear frequency chirp, useful for metrology and sensing applications. Generating FM combs in semiconductor lasers generally requires a fast saturable gain, usually limited by the intrinsic gain medium properties. Here, we show how a spatial modulation of the laser gain medium can enhance the gain saturation dynamics and nonlinearities to generate self-starting FM combs. We demonstrate this with tapered planarized THz quantum cascade lasers (QCLs). While simple ridge THz QCLs typically generate combs which are a mixture of amplitude and frequency modulation, the on-chip field enhancement resulting from extreme spatial confinement leads to an ultrafast saturable gain regime, generating a pure FM comb with a flatter intensity spectrum, a clear linear frequency chirp and very intense beatnotes up to -30 dBm. The observed linear frequency chirp is reproduced using a spatially inhomogeneous mean-field theory model which confirms the crucial role of field enhancement. In addition, the modified spatial temperature distribution within the waveguide results in an improved hightemperature comb operation, up to a heat sink temperature of 115 K, with comb bandwidths of 600 GHz at 90 K. The spatial inhomogeneity also leads to dynamic switching between various harmonic states in the same device., Comment: 9 pages, 6 figures; corrected reference typos

Symmetries and tunability are of fundamental importance in wave scattering control, but symmetries are often obvious upon visual inspection which constitutes a significant vulnerability of metamaterial wave devices to reverse-engineering risks. Here, we theoretically and experimentally show that it is sufficient to have a symmetry in the reduced basis of the "primary meta-atoms" that are directly connected to the outside world; meanwhile, a suitable topology of non-local interactions between them, mediated by the internal "secondary" meta-atoms, can hide the symmetry from sight in the canonical basis. We experimentally demonstrate covert symmetry-based scattering control in a cable-network metamaterial featuring a hidden parity (P) symmetry in combination with hidden-P-symmetry-preserving and hidden-P-symmetry-breaking tuning mechanisms. First, we achieve physical-layer security in wired communications, using the domain-wise hidden P-symmetry as shared secret between the sender and the legitimate receiver. Then, within the approximation of negligible absorption, we report the first tuning of a complex scattering metamaterial without mirror symmetry to feature exceptional points (EPs) of PT-symmetric reflectionless states, as well as quasi-bound states in the continuum. Finally, we show that these results can be reproduced in metamaterials involving non-reciprocal interactions between meta-atoms, including the first observation of reflectionless EPs in a non-reciprocal system., Comment: 30 pages including 4 figures

Coherent beam combination is one promising way to overcome the power limit of one single laser. In this paper, we use a Multi-Plane Light Converter to combine 12 fibers at 1.03 micron with a phase locking setup. The overall loss measurement gives a combination efficiency in the fundamental Hermite-Gaussian mode as high as 70%. This setup can generate the fundamental and higher-order Hermite-Gaussian modes and has beam steering capabilities.

Ring quantum cascade lasers have recently gained considerable attention, showing ultrastable frequency comb and soliton operation, thus opening a way to integrated spectrometers in the midinfrared and terahertz fingerprint regions. Thanks to a self-consistent Maxwell-Bloch model, we demonstrate, in excellent agreement with the experimental data, that a small but finite coupling between the counterpropagating waves arising from distributed backscattering is essential to stabilize the soliton solution., Comment: 6 Pages, 4 figures