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In this work, we employ differential evolution algorithm to identify the optimal configurations of small atomic ensembles supporting quantum states with maximal radiative lifetime. We demonstrate that atoms mostly tend to assemble in quasi-regular structures with specific geometry strongly depending on the minimal interatomic distance $r_{min}$. We identified the clear underlying physics that governs the suppression of the radiative losses in particular geometries. However, we reveal that the specific configurations in small ensembles are not easily predictable based on the knowledge established for the arrays of large size. In particular, the states that inherit their properties from bound states in continuum in infinite lattices turn out to be the most subradiant in a wide range of $r_{min}$ values. We also show that for small interatomic distance the chains with modulated interatomic distances exhibit fast exponential decrease of the radiative losses with the size of the ensemble.

Cold Rydberg atoms are a promising platform for quantum technologies and combining them with optical waveguides has the potential to create robust quantum information devices. Here, we experimentally observe the excitation of cold rubidium atoms to a large range of Rydberg S and D states through interaction with the evanescent field of an optical nanofiber. We develop a theoretical model to account for experimental phenomena present such as the AC Stark shifts and the Casimir-Polder interaction. This work strengthens the knowledge of Rydberg atom interactions with optical nanofibers and is a critical step toward the implementation of all-fiber quantum networks and waveguide QED systems using highly excited atoms.