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Metal organic frameworks (MOFs) are multi-dimensional network of crystalline material held together by bonding of metal atoms and organic ligands. Owing to unique structural, chemical, and physical properties, MOFs has been used for enzyme immobilization to be employed in different catalytic process, including catalytic degradation of antibiotics. Immobilization process other than providing large surface provides enzyme with enhanced stability, catalytic activity, reusability, and selectivity. There are various approaches of enzyme immobilization over MOFs including physical adsorption, chemical bonding, diffusion and in situ encapsulation. In situ encapsulation is one the best approach that provides extra stability from unfolding and denaturation in harsh industrial conditions. Presence of antibiotic in environment is highly damaging for human in particular and ecosystem in general. Different methods such as ozonation, oxidation, chlorination and catalysis are available for degradation or removal of antibiotics from environment, however these are associated with several issues. Contrary to these, enzyme immobilized MOFs are novel system to be used in catalytic degradation of antibiotics. Enzyme@MOFs are more stable, reusable and more efficient owing to additional support of MOFs to natural enzymes in well-established process of photocatalysis for degradation of antibiotics aimed at environmental remediation. Prime focus of this review is to present catalytic degradation of antibiotics by enzyme@MOFs while outlining their synthetics approaches, characterization, and mechanism of degradation. Furthermore, this review highlights the significance of enzyme@MOFs system for antibiotics degradation in particular and environmental remediation in general. Current challenges and future perspective of research in this field are also outlined along with concluding comments. [ABSTRACT FROM AUTHOR]

Although rapid industrialization has made life easier for humans, several associated issues are emerging and harming the environment. Wastewater is regarded as one of the key problems of the 21st century due to its massive production every year and requires immediate attention from all stakeholders to protect the environment. Since the introduction of nanotechnology, bismuth-based nanomaterials have been used in variety of applications. Various techniques, such as hydrothermal, solvo-thermal and biosynthesis, have been reported for synthesizing these materials, etc. Among these, biosynthesis is eco-friendly, cost-effective, and less toxic than conventional chemical methods. The prime focuses of this review are to elaborate biosynthesis of bismuth-based nanomaterials via bio-synthetic agents such as plant, bacteria and fungi and their application in wastewater treatment as anti-pathogen/photocatalyst for pollutant degradation. Besides this, future perspectives have been presented for the upcoming research in this field, along with concluding remarks. • Outlining synthetic strategies for bismuth-based nanomaterials. • Biosynthetic route for bismuth-based nanomaterials using plants and microbes. • Sustainable removal of emerging environmental contaminants from wastewater. • Bioengineered bismuth-based nanostructured materials as environmental photocatalysts. • Current challenges and future recommendations for the upcoming research. [ABSTRACT FROM AUTHOR]