Search

Some marine animals form long‐lived luminescence for predation, communication, camouflage, and anti‐predation. These marine animals demonstrate soft nature, sustainable glowing, and underwater emission, which are difficult to achieve in synthetic room temperature phosphorescence (RTP) materials. Inspired by these marine animals, here the study reports RTP hydrogels that show long‐lived phosphorescence (lifetime >500 ms and afterglow >10 s) in water. Exceptional underwater mechanical properties are simultaneously achieved, including tensile strength of 5.1 MPa, tensile strain of 452%, and toughness of 19.3 MJ m−3. The key to this achievement lies in the in situ phase separation microarchitecture formed between polyacrylamide (PAM) and its partial hydrolysates, which confines the motions of polymer chains and protects vulnerable triplet excitons from quenching of water. Such a strategy shows the merits of facile fabrication without laborious synthesis. In addition, these RTP hydrogels offer repeatable photoprinting and highly stability in water, providing a versatile platform for underwater applications of RTP materials, including information encryption and camouflage of marine animals. [ABSTRACT FROM AUTHOR]

The development of tough, stretchable and long‐lived room temperature phosphorescence (RTP) materials holds great significance for manufacturing and processing photoluminescent materials, but limited techniques are available to profile their mechanics‐photophysics correlation. Here we report glassy ionogels, and their mechanical properties and photophysical properties are fused by dynamic mechanical analysis (DMA), functioning like a human brain that perceives a material instantaneously by linking sensory perception and cognition. Depending on two special temperatures presented in DMA curves, Tloss (the peak of loss modulus (E”)) and Tg (glass transition temperature), the ionogels can vary from being either tough with persistent phosphorescence, extensible with effective phosphorescence or resilience with inefficient phosphorescence. Leveraging this method, we achieve stretchable and long‐lived RTP ionogels with tensile yield strength of 53 MPa, tensile strain of 497 %, Young's modulus of 782 MPa, toughness of 111.2 MJ/m3, and lifetime of 113.05 ms. Our work provides a simple yet powerful method to reveal the mechanics‐photophysics correlation of RTP ionogels, to predict their performance without laborious synthesis and characterization, opening new avenues for applications of RTP materials, including applications in harsh conditions (257 K or 347 K), shape memory and shape reconstruction. [ABSTRACT FROM AUTHOR]