Phase change material (PCM)-enhanced building envelopes can control indoor temperatures and save energy. However, PCM needs to undergo a phase change transition from solid to liquid and back to be fully effective. Furthermore, most previous research integrated PCM with high embodied energy materials. This study aims to advance the existing research on integrating PCM into carbon-negative wall assemblies composed of hempcrete and applying temperature control strategies to improve wall systems' performance while considering the hysteresis phenomenon. Four hempcrete and hempcrete-PCM (HPCM) wall design configurations were simulated and compared under different control strategies designed to reduce energy demand while enhancing the phase change transition of the microencapsulated PCM. The HPCM wall types outperformed the hempcrete wall assembly through heating (~3–7%) and cooling (~7.8–20.7%) energy savings. HPCM walls also maintained higher wall surface temperatures during the coldest days, lower during the warmest days, and within a tighter range than hempcrete assembly, thus improving the thermal comfort. However, the results also show that the optimal performance of thermal energy storage materials requires temperature controls that facilitate their charge and discharge. Hence, applied control strategies reduced heating and cooling energy demand in the range of ~4.4–21.5% and ~14.5–55%, respectively. [ABSTRACT FROM AUTHOR]