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Ships that transport oil or derivatives on the Lower Amazon River waterway are at a considerably high risk of suffering spills, with severe environmental and socioeconomic consequences. The present study is aimed at modeling and simulating the oil dispersion and magnitude of these accidents in terms of the vulnerability of biological resources, considering two oil types most often transported by medium-sized tankers in the region (S500 and S10). The study method was as follows: (a) secondary data were collected from local species, and the coastal sensitivity index (CSI) was calculated, obtained from Brazil's Letters of Environmental Sensitivity to Oil Spill (Cartas de Sensibilidade Ambiental ao Derramamento de Óleo (SAO)); (b) ship traffic information was obtained from Brazil's Statistical Yearbook of Waterway (Anuário Estatístico Aquaviário (ANTAQ)); (c) modeling and numerical simulation of oil spills in water were performed, in order to investigate dispersion scenarios (SisBaHia); (d) three numerical scenarios of oil plume dispersion (in May and November) were integrated to assess species vulnerability in three zones of environmental interest (I, II, and III). Some species identified in zone II were considered to be the most vulnerable (fish, plankton, aquatic mammals, amphibians, aquatic invertebrates, trees, and plants), with the mammal Sotalia fluviatilis being at risk of extinction (Gervais & Deville, 1853). The simulated scenarios showed that contingency plans should have a minimum response time of 3 h and a maximum response time of 72 h to prevent the oil plumes from dispersing as far as 170 km longitudinally, depending on the zone, season, and tidal phase. Thus, a total of 62 sites of biological resources were identified in the literature recorded from 2016. Considering them, 324 species of flora and fauna were recorded, distributed in the following seven groups: (i) 49 tree and plant species, (ii) 37 amphibian species, (iii) 2 aquatic invertebrate species, (iv) 23 invertebrate species, (v) 1 aquatic mammal species, (vi) 95 fish species, and (vii) 117 planktonic species. A failure to respond to these accidents would impact immense intact aquatic areas and ecosystems, with unpredictable consequences for local biodiversity conservation., (© 2022. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Hydrodynamics play a critical role in determining the trajectory of an oil spill. Currents, stratification and mesoscale processes all contribute to how a spill behaves. Using an industry‑leading oil spill model, we compare forecasts of oil dispersion when forced with two different hydrodynamic models of the North-West European Shelf (7 km and 1.5 km horizontal resolution). This demonstrates how the trajectory of a deep water (>1000 m) release in the central Faroe-Shetland Channel is influenced by explicitly resolving mesoscale processes. The finer resolution hydrodynamic model dramatically enhances the horizontal dispersion of oil and transports pollutant further afield. This is a consequence of higher mesoscale variability. Stratification influences the depth of subsurface plume trapping and subsequently the far-field transport of oil. These results demonstrate that the choice of hydrodynamic model resolution is crucial when designing particle tracking or tracer release experiments., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Crown Copyright © 2020. Published by Elsevier Ltd. All rights reserved.)

During accidental crude oil spills and permitted discharges of produced water into the marine environment, a large fraction of naturally occurring oil components will be contained in micron-sized oil droplets. Toxicity is assumed to be associated with the dissolved fraction of oil components, however the potential contribution of oil droplets to toxicity is currently not well known. In the present work we wanted to evaluate the contribution of oil droplets to effects on normal development of Atlantic cod (Gadus morhua) through exposing embryos for 96 h to un-filtered (dispersions containing droplets) and filtered (water soluble fractions) dispersions in a flow-through system at dispersion concentrations ranging from 0.14 to 4.34 mg oil/L. After exposure, the embryos were kept in clean seawater until hatch when survival, development and morphology were assessed. The experiment was performed at two different stages of embryonic development to cover two potentially sensitive stages (gastrulation and organogenesis). Exposure of cod embryos to crude oil dispersions caused acute and delayed toxicity, including manifestation of morphological deformations in hatched larvae. Oil droplets appear to contribute to some of the observed effects including mortality, larvae condition (standard length, body surface, and yolk sac size), spinal deformations as well as alterations in craniofacial and jaw development. The timing of exposure may be essential for the development of effects as higher acute mortality was observed when embryos were exposed from the start of gastrulation (Experiment 1) than when exposed during organogenesis (Experiment 2). Even though low mortality was observed when exposed during organogenesis, concentration-dependent mortality was observed during recovery., (Copyright © 2019 Elsevier Ltd. All rights reserved.)

This study evaluated the applicability of eight types of biomarkers namely, adamantanes, diamantanes, sesquiterpanes, steranes, terpanes, TA-steranes, MA-steranes, and alkylated PAHs, to characterize chemically dispersed oil (CDO) after the 60-day weathering. The stability of diagnostic ratios of the selected biomarkers was evaluated and summarized. The results indicated that the concentrations of biomarkers with low molecular weight, such as adamantanes, diamantanes, and sesquiterpanes, in CDO were markedly affected by weathering and the associated diagnostic ratios were changed extensively. Most of the alkylated PAHs were degraded during weathering as well. These biomarkers thus were not recommended for characterizing CDO. The majority of the terpanes, steranes, TA-steranes, and MA-steranes could be used for weathered CDO fingerprinting due to the relatively stable diagnostic ratios. The findings could help to identify applicable biomarkers for fingerprinting of weathered dispersed oil.

Oil-suspended particulate matter aggregation (OSA) has been recognized by the oil spill remediation community to effectively enhance the cleansing of spilled oil in the marine environment. While studies have investigated the application of mineral fines as an effective method to facilitate oil dispersion, decision-makers still lack information on the role of mixing energy in OSA formation and its significance to oil dispersion in real spills. This work studied the effect of level and duration of mixing energy on OSA formation using the standard reference material 1,941 b and Arabian light crude oil. The results showed that dispersed small oil droplets increased with an increase of both the level and duration of mixing energy to form multi-droplet OSAs. The sizes of the dispersed droplets varied between 5 and 10 μm under different conditions studied. The maximum oil trapping efficiency increased from 23% to 33%, the oil to sediment ratio increased from 0.30 to 0.43 g oil/g sediment, and the required shaking time decreased from 2.3 to 1.1h as the shaking rate increased from 2.0 to 2.3 Hz. Based on the size measurement results, a breakage effect on the formed OSAs and sediment flocs was confirmed under high mixing energy level., (Copyright © 2013 Elsevier B.V. All rights reserved.)