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The relationship between the chemical purity of one-size particles and microwave properties in ferromagnetic materials is not clearly studied. Ferromagnetic nanostructured iron powders were synthesized from iron nitrate solution using ultrasonic spray-pyrolysis and then reduced in H2 flow at 350, 400, 450, and 500 °C. A rise in the concentration of solutions of a precursor from 10 to 20 wt. % led to an increase in mean particle size. The interrelationship was studied between chemical composition and the microwave dispersion of the powders obtained. An increase in the temperature of reduction changes the chemical composition and increases the amplitude of complex microwave permeability, which was studied using solid-state physics methods (XRD, STA, SEM, and VNA). It was found that annealing at 400 °C is the optimal treatment that allows the production of iron powders, consisting of about 90% of α-Fe phase, possessing a particle surface with low roughness and porosity, and demonstrating intense microwave absorption. Annealing at a higher temperature (500 °C) causes an even higher increase in permeability but leads to the destruction of nanostructured spheres into smaller particles due to grain growth. This destruction causes an abrupt increase in permittivity and therefore significantly reduces potential applications of the product. The insight into chemical–magnetic relationships of these materials enhances the data for design applications in magnetic field sensing. [ABSTRACT FROM AUTHOR]

Hollow ferromagnetic powders of iron were obtained by means of ultrasonic spray pyrolysis. A variation in the conditions of the synthesis allows for the adjustment of the mean size of the hollow iron particles. Iron powders were obtained by this technique, starting from the aqueous solution of iron nitrate of two different concentrations: 10 and 20 wt.%. This was followed by a reduction in hydrogen. An increase in the concentration of the solution increased the mean particle size from 0.6 to 1.0 microns and widened particle size distribution, but still produced hollow particles. Larger particles appeared problematic for the reduction, although admixture of iron oxides did not decrease the microwave permeability of the material. The paraffin wax-based composites filled with obtained powders demonstrated broadband magnetic loss with a complex structure for lesser particles, and single-peak absorption for particles of 1 micron. Potential applications are 5G technology, electromagnetic compatibility designs, and magnetic field sensing. [ABSTRACT FROM AUTHOR]

Intrinsic permeability of sendust alloys is determined from the measured microwave permittivity and permeability of composites filled with either spherical or flaky sendust powders. The permittivity and permeability measurements are performed applying the coaxial reflection-transmission technique in the 0.05 to 18 GHz frequency range. The effects of the filling factor, inclusion shape, and size on composite constitutive parameters are discussed. The permeability of metal inclusion is retrieved from the measured permeability of composites using a generalized Maxwell Garnett equation that accounts for the percolation threshold. The equation parameters are found by fitting the measured dependence of composite permittivity and permeability on frequency and filling. The inclusion dimensions calculated from the found parameters agree with the results of grain-size analyses. The alloy intrinsic permeability is retrieved from inclusion permeability with the account for skinning. The fitted frequency and damping factor of ferromagnetic resonance depend on the inclusion shape. The calculated reflectivity map of the flake-filled composite shows that sendust powders are promising fillers for interference suppressors and microwave absorbers at frequencies close to 1 GHz. [ABSTRACT FROM AUTHOR]

The technique to retrieve the microwave permeability of metals from the measured constitutive parameters of composites with fine powder of these metals is developed. The technique is based on the modified Sihvola mixing rule and describes a wide range of contrasts in the component susceptibility, accounts for both the inclusion shape and the percolation threshold. These parameters are related to the Bergman-Milton shape-distribution width and to composite structure. The technique is applied to retrieve the microwave permeability of nickel. The metal permeability is calculated from the measured permittivity and permeability of paraffin-bound composites filled with nickel flakes or spheres with account for skinning in conducting inclusions. The measurements are performed using the transmission coaxial-cell in the frequency range up to 15 GHz. The effects of filling factor, inclusion shape and size on the retrieved permeability spectra are analyzed. The permeability retrieval procedure is based on parameter fitting of the selected mixing model for the measured permittivity and permeability data. The retrieved permeability is close to the data available from archived literature sources that are obtained with thick nickel wires and foils. [ABSTRACT FROM AUTHOR]

The microwave permeability of nickel is determined from constitutive parameters of paraffin–bound composites filled with nickel flakes or spheres. The metal permeability is calculated with account for skinning. The measurements of constitutive parameters are performed using the reflection–transmission coaxial-line within the frequency band of 0.001–20 GHz. The effects of filling factor, particle shape, and size on permittivity and permeability spectra are analyzed. The retrieval of inclusion permeability is based on the treatment of measured dependence of composite constitutive parameters on frequency and on volume fraction of inclusions. The retrieval procedure is based on the generalized Sihvola mixing model simplified for a single-dimension composite. The model describes the wide contrast of component susceptibility, accounts for inclusion shape and the Bergman–Milton spectral linewidth. The retrieved microwave permeability is close to the values reported for measurements with thick wires and foils. [ABSTRACT FROM AUTHOR]

Abstract: Microwave magnetic performance of thin ferromagnetic films is of interest in view of many technical problems. For measuring the microwave permeability, a shorted stripline technique is in common use. Recently, a coaxial technique has been developed for permeability measurements of films deposited onto a flexible substrate. The coaxial technique is reported to be advantageous over the conventional stripline method in wideband operating range and accuracy. In this paper, measurement results are presented which are obtained with these two techniques for Fe–N films. It is found that the magnetoelastic effect contributes greatly to the measured microwave permeability of the films. With the coaxial measurements under an external magnetic bias, this effect may be accounted for to estimate the permeability of a plane film sample. Additional information on the properties of the film can also be extracted from these data, such as estimations of average magnetic anisotropy field and of the magnetostriction constant of the film. [Copyright &y& Elsevier]