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Atmospheric radon measurements assist in many aspects of climate and meteorological research, notably as an airmass tracer and for modelling boundary layer development, mixing heights and stability. Daughter products from radon decay are sometimes incorporated into the particle pollution measurements of commercially available beta-attenuation monitors (BAM). BAMs incorporating radon measurements are used in air quality monitoring networks and can supplement traditional radon measurements. Here we compare in-situ radon measurements from Thermo Fisher Scientific (Franklin, MA, USA) BAM instruments (Thermo Scientific 5014i, Thermo Scientific 5030 SHARP, Thermo Anderson FH62C14) at two air quality monitoring stations in New South Wales, Australia. Between systems we find strong correlations for hourly measurements (r = 0.97–0.99); daily means (r = 0.97–0.99); hour of the day (r = 0.84–0.98); and month (r = 0.82–0.98). The regression analysis for radon measurements between systems showed strong linear responses, although there are some variations in the slopes of the regressions. This implies that with correction BAM measurements can be comparable to standard measurement techniques, for example, from the Australian Nuclear Science and Technology Organisation (ANSTO) dual flow loop monitors. Our findings imply that BAM derived radon measurements are precise, although their accuracy varies. BAM radon measurements can support studies on boundary layer development or where radon is used as an atmospheric transport tracer. [ABSTRACT FROM AUTHOR]

Radon (Rn) is a radioactive, colourless, odourless, noble gas that decays rapidly. It's most stable isotope, 222Rn, has a half-life of around 3.8 days. Atmospheric radon measurements play an important role in understanding our atmospheric environments. Naturally occurring radon can be used as an atmospheric tracer for airmass tracking, to assist in modelling boundary layer development, and is important for understanding background radiation levels and personal exposure to natural radiation. The daughter products from radon decay also play an important role when measuring fine particle pollution using beta-attenuation monitors (BAM). Beta radiation from the 222Rn decay chain interferes with BAM measurements of fine particles; thus, some BAMs incorporate radon measurements into their sampling systems. BAMs are ubiquitous in air quality monitoring networks globally and present a hitherto unexplored source of dense, continuous radon measurements. In this paper, we compare in situ real world 222Rn measurements from a high quality ANSTO dual flow loop, dual filter radon detector, and the radon measurements made by a commercial BAM instrument (Thermo 5014i). We find strong correlations between systems for hourly measurements (R2 = 0.91), daily means (R2 = 0.95), hour of day (R2 = 0.72–0.94), and by month (R2 = 0.83–0.94). The BAM underestimates radon by 22–39%; however, the linear response of the BAM measurements implies that they could be corrected to reflect the ANSTO standard measurements. Regardless, the radon measurements from BAMs could be used with correction to estimate local mixed layer development. Though only a 12-month study at a single location, our results suggest that radon measurements from BAMs can complement more robust measurements from standard monitors, augment radon measurements across broad regions of the world, and provide useful information for studies using radon as a tracer, particularly for boundary layer development and airmass identification. [ABSTRACT FROM AUTHOR]

ABSTRACT Ozone and particle pollution are of concern for the Sydney basin, in particular during warm months (November to March) when pollution levels can exceed national standards. Previous studies on the relationship between synoptic circulation and air quality focused on high pollution days or aggregated air quality conditions over the region as a whole. This study provides both temporal and spatial analyses of the synoptic processes affecting warm-month ozone and particle pollution in Sydney. A warm-month synoptic catalogue was developed by applying the self-organising map method to the NCEP/NCAR geopotential height reanalysis for south-east Australia. The catalogue was linked to mesoscale meteorological features such as drainage flows and sea breezes, and subsequently to the spatial variability in air quality across the Sydney basin. The typical synoptic types commonly associated with high or low ozone and PM10 levels, as well as variations in visibility, were identified. The results suggest that, due to Sydney's subtropical coastal-basin environment, the interaction between meso- and synoptic-scale features determine local air quality conditions in the region, rather than the synoptic conditions alone. Emissions from bushfires appear to have considerable impacts on the synoptic modulation to visibility and PM10 levels, with such impacts tending to be more at a local scale. In contrast, no comparable impacts were found for ozone pollution. For ozone and visibility, the probability for an exceedance day under some synoptic types varied considerably over time, implying that there might have been a shift in the role of synoptic modulation to local air quality associated with changes in air emissions profiles. This study provides a leap in our understanding of the relationship between synoptic circulation and air quality in a coastal-basin environment. The results are useful for improving air quality forecasting in Sydney, with the methodology developed readily applicable to similar regions elsewhere. [ABSTRACT FROM AUTHOR]